Abstract: The present invention relates to a catalytic process for the continuous production of carbon monoxide-free hydrogen from methane or methane-rich hydrocarbons using a solid catalyst comprising at least one group VIII metal in two parallel catalytic reactors.

Abstract: The present invention relates to a catalytic process for the continuous production of carbon monoxide-free hydrogen from methane or methane-rich hydrocarbons using a solid catalyst comprising at least one group VIII metal in two parallel catalytic reactors.

Abstract: A process for the continuous production of hydrogen from methane and/or natural gas and/or methane-rich hydrocarbons and steam at low temperature, using a solid catalyst comprising group VIII metal oxide(s) in two parallel reactors, comprising reducing the solid catalyst in both the reactors by contacting the catalyst with a gaseous feed comprising a reducing agent, contacting a first gaseous feed comprising methane and/or natural gas and/or methane rich hydrocarbons, simultaneously contacting a second gaseous feed comprising steam called Feed-B with the solid catalyst reduced in step-i in a second reactor. while regularly switching over the two feeds, Feed-A arid Feed-B, between the two parallel reactors to obtain a mixed product stream comprising hydrogen from the two reactors.

Abstract: A process for catalytic conversion of methane or natural gas to syngas using a supported catalyst containing oxides of nickel and cobalt with of without noble metals. Efficiency of the catalytic process is increased by simultaneously carrying out an exothermic oxidation reaction and an endothermic steam and carbon dioxide reforming reaction over the supported catalyst. The catalyst is prepared by depositing oxides of nickel and cobalt, with or without noble metals, on a sintered low surface area porous inert support. Surface of the support is precoated with an oxide of Be, Mg, Ca or a mixture thereof so that a protective layer of alkaline earth oxide is formed between the oxides of nickel and cobalt and the support, and hence, direct chemical interactions between the oxides of nickel and cobalt and reactive components of the support, which leads to formation of catalytically inactive binary oxide phases, are avoided.

Abstract: A process for the production of propylene and ethylene by non-catalytic oxidative conversion of propane by allowing the endothermic hydrocarbon cracking reaction to occur simultaneously with the exothermic hydrocarbons oxidative conversion reactions in an empty tubular reactor is disclosed. The process comprises mixing of oxygen and propane at ambient temperatures, mixing of sulfur compound with steam, admixing the mixture of steam and sulfur compound and the mixture of oxygen and propane and preheating the resulting admixture, passing said mixture through an empty tubular reactor, cooling and separating the components of effluent product gases by known methods and recycling the unconverted reactants, if required.

Abstract: An improved process for the production of ethylene by non-catalytic oxidative cracking of ethane or ethane rich C.sub.2 -C.sub.4 paraffins with high conversion, selectivity and productivity, operating in a most energy efficient and safe manner requiring little or no external energy, in an empty tubular reactor, wherein the exothermic oxidative conversion of ethane or ethane rich C.sub.2 -C.sub.4 paraffins is coupled with the endothermic hydrocarbon cracking reactions by carrying out both the exothermic and endothermic reactions simultaneously in the reactor so that the heat produced in the exothermic reactions is used instantly in the endothermic reactions and thereby making the overall process mildly exothermic, near thermo-neutral or mildly endothermic, which comprises passing a preheated gaseous feed comprising of ethane or ethane rich C.sub.2 -C.sub.4 paraffins, oxygen and steam through an empty tubular reactor operated at the effective temperature, pressure, space velocity and hydrocarbon/O.sub.

Abstract: A supported catalyst is prepared by depositing oxides of nickel and cobalt, with or without noble metals, on a sintered low surface area porous inert support, surface of which is precoated with an oxide of Be, Mg, Ca or a mixture thereof so that a protective layer of the alkaline earth oxide is formed between the oxides of nickel and cobalt, with or without noble metal, and the support and hence direct chemical interactions between the oxides of the group VIII transition metals and the reactive components of support, which leads to the formation of catalytically inactive binary oxide phases are avoided.