Abstract: Described herein is coated article comprising: (a) a substrate comprising a ceramic, a glass, or a glass ceramic, wherein the substrate comprises a surface, the surface comprising a continuous upper portion and a plurality of lower portions, wherein each lower portion is connected to the upper portion by at least one sidewall; and (b) a first layer comprising a material capable of physical vapor deposition, wherein the first layer is disposed on the continuous upper portion and at least a portion of each sidewall and wherein at least a portion of each lower portion is free of the first layer. Methods of making such coated articles are described herein, wherein the substrate is coating via angular physical vapor deposition.

Abstract: An article is provided that includes a substrate, a silicon containing layer on the substrate, and a layer including metallic Pt on the silicon containing layer. The silicon containing layer is a diamond-like glass layer. Optionally, the substrate is a porous membrane. In some cases, the silicon containing layer is a continuous layer.

Abstract: An article including a substrate; a silicon containing layer on the substrate; and a layer comprising metallic Pt on the silicon containing layer.