Abstract: Functionalized polymer matrix and/or reinforcement materials that are capable of a thermoreversible Diels-Alder reaction are useful for making composite materials. Also disclosed is a composite material which includes one or both of functionalized reinforcement materials and functionalized polymer matrix materials, as well as a method for repairing a composite material including the step of thermally treating the composite material at a temperature sufficient to react a functionality on one of the reinforcement material and the polymer matrix material with another functionality via a Diels-Alder reaction. A method of making a composite material including functionalizing one or both of a reinforcing material and a polymer matrix material with a first reactive group, providing a second reactive group capable of undergoing a Diels-Alder reaction with the first reactive group and reacting the first and second reactive groups to form a composite material, is also described.

Abstract: A self-healing coating for reinforcing steel embedded in concrete includes emulsion derived microcapsules having a healing agent and adapted for dispersion through a liquid coating medium for application on a structural steel surface to form a coating for corrosion prevention. The microcapsule particles are dispersed in the coating medium for being disposed on the surface and are configured to rupture and release the healing agent onto the surface in response to a compromise of the coating, such as being dropped or dragged on a construction site. The self-healing agent, such as Tung oil, complements the protective properties of the coating medium by flowing into regions where the coating medium has been scraped off, flaked off, or otherwise undergone compromise. Alternatively, post-installation corrosive influences, such as rust and oxidation, can also cause rupture of the particles to abate corrosion in the concrete-encased steel members.

Abstract: Functionalized polymer matrix and/or reinforcement materials that are capable of a thermoreversible Diels-Alder reaction are useful for making composite materials. Also disclosed is a composite material which includes one or both of functionalized reinforcement materials and functionalized polymer matrix materials, as well as a method for repairing a composite material including the step of thermally treating the composite material at a temperature sufficient to react a functionality on one of the reinforcement material and the polymer matrix material with another functionality via a Diels-Alder reaction. A method of making a composite material including functionalizing one or both of a reinforcing material and a polymer matrix material with a first reactive group, providing a second reactive group capable of undergoing a Diels-Alder reaction with the first reactive group and reacting the first and second reactive groups to form a composite material, is also described.