Abstract: The present invention provides a zirconium-based metal-organic framework material and a preparation method therefor and the use thereof, and an adsorption separation device and method. The zirconium-based metal-organic framework material has a chemical structural formula of [C18H6O16Zr3]n, and comprises zirconium and an organic ligand forming a coordination bond with zirconium, wherein the organic ligand is diphenylethyne-3,3?,5,5?-tetracarboxylic acid. The molecular structure of the zirconium-based metal-organic framework material of the present invention is a three-position network structure having a one-dimensional channel; and in the present invention, the size of the one-dimensional channel is accurately controlled by changing the aspect ratio of the organic ligand, such that the zirconium-based metal-organic framework material efficiently separates a hexane isomer by means of a kinetic effect.

Abstract: Provided is a method and device for viscosity-reducing and upgrading of low-grade heavy oil. The method comprises: (a) performing visbreaking reaction on low-grade heavy oil raw material and controlling the content of toluene insolubles in the produced oil; (b) mixing the produced oil in step (a) with hydrogen in a gas-liquid mixer to obtain a hydrogen-oil mixture in liquid state, or mixing the produced oil in step (a) with hydrogen to obtain hydrogen-oil mixture in gas-liquid state; in the presence of a hydrogenation catalyst, performing hydrogenation reaction on the hydrogen-oil mixture in liquid state or the hydrogen-oil mixture in gas-liquid state in the reactor, and obtaining a viscosity-reduced and upgraded oil after the reaction. It is viscosity-reducing and upgrading method by combining thermal visbreaking and fixed-bed hydrogenation, which can solve the problems of high viscosity, high density and poor stability of low-grade heavy oil products in the prior art.

Abstract: The present invention relates to a selective hydrogenation catalyst for an unsaturated compound. The supported catalyst contains at least one Group VIB non-noble metal oxide and at least one Group VIII non-noble metal oxide deposited on a carrier; and the catalyst has an optimized acid distribution on the surface of the catalyst, and more preferably has an optimized Group VIII/VIB metal ratio and a Group VIII non-noble metal density per unit of catalyst surface area. Using the catalyst of the present invention can have the following advantages: the weight increase of light sulphides in an unsaturated compound or a mixture containing unsaturated compounds, the hydrogenation of a polyunsaturated compound, the isomerization of a monounsaturated compound, high operation flexibility and a significant improvement in the effects of a hydrogenation treatment.

Abstract: The present invention relates to a selective hydrogenation catalyst for an unsaturated compound. The supported catalyst contains at least one Group VIB non-noble metal oxide and at least one Group VIII non-noble metal oxide deposited on a carrier; and the catalyst has an optimized acid distribution on the surface of the catalyst, and more preferably has an optimized Group VIII/VIB metal ratio and a Group VIII non-noble metal density per unit of catalyst surface area. Using the catalyst of the present invention can have the following advantages: the weight increase of light sulphides in an unsaturated compound or a mixture containing unsaturated compounds, the hydrogenation of a polyunsaturated compound, the isomerization of a monounsaturated compound, high operation flexibility and a significant improvement in the effects of a hydrogenation treatment.

Abstract: An apparatus and a method that increase the concentration of recycled hydrogen in the hydrogenation unit are disclosed having a hydration separation unit included between the high-pressure separator and hydrocracking reactor. A part of the recycled hydrogen contacts with the water-in-oil microemulsion to form hydrates from which the light hydrocarbon components are removed. The gas flow entering into the hydration separation unit is present in amount of 20%˜100% of the total gas flow coming from the high-pressure separator; the water-in-oil microemulsion, in which the volume ratio of oil and water is 1:1 to 5:1 may increase hydrogen partial pressure in the reactor and thus upgrade the performance of hydrogenation.

Abstract: An apparatus and a method that increase the concentration of recycled hydrogen in the hydrogenation unit are disclosed having a hydration separation unit included between the high-pressure separator and hydrocracking reactor. A part of the recycled hydrogen contacts with the water-in-oil microemulsion to form hydrates from which the light hydrocarbon components are removed. The gas flow entering into the hydration separation unit is present in amount of 20%˜100% of the total gas flow coming from the high-pressure separator; the water-in-oil microemulsion, in which the volume ratio of oil and water is 1:1 to 5:1 may increase hydrogen partial pressure in the reactor and thus upgrade the performance of hydrogenation.

Abstract: The present invention relates to a catalytic cracking process and a device used in the process in particular, the present invention provides a catalytic cracking process, which comprises which comprises: 1) catalytic cracking a feedstock in the first riser for less than about 1.5 second and sending the resultant stream into the first separating device,; 2) catalytic cracking the recycle oil obtained from the first separating device in the second riser for less than about 1.

Abstract: This application provides processes for recovering hydrogen, ethylene and ethane from dry gas or separating ethylene cracked gas from dry gas of refinery plants, wherein a hydrating separation may be combined with for example a freezing or absorbing separation so as to separate a multiple gas mixture.

Abstract: The present invention relates to a catalytic cracking process and a device used in the process in particular, the present invention provides a catalytic cracking process, which comprises which comprises:

Abstract: The invention relates to a new and improved heavy oil hydrocracking process using a multimetallic liquid catalyst in a slurry-bed reactor, particularly an improvement of lightweight treatment of heavy oil in the petroleum processing technology. According to the present invention, a slurry-bed hydrocracking reactor and a highly dispersed multimetallic liquid catalyst are mainly applied during the process. A fixed-bed hydrotreating reactor is also used on line to enhance lightweight oil yield from heavy oil under normal pressure.

Abstract: A multi-stage loop reactor, employed in various gas-liquid or gas-liquid-solid chemical reaction systems, which comprises a reactor body, draft tube(s) inside the reactor body, and a gas distributor at the bottom of draft tube. The draft tube can include one or more sections. The multi-stage loop reactor of the present invention has a higher mass transfer rate because the different phases are well mixed throughout the reactor, and the gas bubbles are distributed evenly everywhere. The reactor of this invention can be extensively applied in various gas-liquid or gas-liquid-solid reaction processes including the oxidization process, hydrogenation process, hydrocracking process, coal liquification process, fermentation process, hydrocarbon processing process, and biological treatment of waste water, etc.

Abstract: The invention relates to a new and improved heavy oil hydrocracking process using a multimetallic liquid catalyst in a slurry-bed reactor, particularly an improvement of lightweight treatment of heavy oil in the petroleum processing technology. According to the present invention, a slurry-bed hydrocracking reactor and a highly dispersed multimetallic liquid catalyst are mainly applied during the process. A fixed-bed hydrotreating reactor is also used on line to enhance lightweight oil yield from heavy oil under normal pressure.

Abstract: This invention relates to a new two-stage riser catalytic cracking process, particularly to an improvement of the conventional riser reactor and reaction-regeneration system by application of a two-stage riser reactor to fulfill the aims of the concatenation of oil-vapor, catalyst in relays as result in shortening reaction time and increasing average performance of the catalyst.