Abstract: The present disclosure relates to a chromium-free coating composition including at least one binder and at least one iron(III)-tris(N,N-dithiocarbamate) complex, where the binder includes at least one synthetic resin and at least one crosslinker. The present disclosure also relates to the use of such a coating composition for the protection against corrosion of metallic substrates, a process for at least partially coating a metallic substrate with such a priming coat, a substrate at least partially coated therewith and an article or a component made of such a substrate.