Abstract: The present disclosure relates to a lithium ion-conducting glass ceramic which comprises a residual glass phase that is also ion-conducting, a process for the production thereof as well as its use in a battery. The glass ceramic according to the present disclosure comprises a main crystal phase which is isostructural to the NaSICon crystal phase, wherein the composition can be described with the following formula: Li1+x?yMy5+Mx3+M2?x?y4+(PO4)3?, wherein x is greater than 0 and at most 1, as well as greater than y. Y may take values of between 0 and 1. Here, the following boundary condition has to be fulfilled: (1+x?y)>1. Here, M represents a cation with the valence of +3, +4 or +5. M3+ is selected from Al, Y, Sc or B, wherein at least Al as trivalent cation is present. Independently thereof, M4+ is selected from Ti, Si or Zr, wherein at least Ti as tetravalent cation is present. Independently thereof, M5+ is selected from Nb or Ta.

Abstract: A method for producing a conductive composite material for a battery such as a solid-state battery includes providing an ion-conducting electrolyte matrix that can be plasticized and that includes an ion-conducting first substance a base substance that can be plasticized and/or a polyelectrolyte; providing a second ion-conducting substance in the form of ion-conducting particles; introducing the ion-conducting particles into the electrolyte matrix to produce a mixture consisting of the ion-conducting particles and the electrolyte matrix; and homogenizing the mixture.

Abstract: A method for producing a cavity in a substrate composed of hard brittle material is provided. A laser beam of an ultrashort pulse laser is directed a side surface of the substrate and is concentrated by a focusing optical unit to form an elongated focus in the substrate. Incident energy of the laser beam produces a filament-shaped flaw in a volume of the substrate. The filament-shaped flaw extends into the volume to a predetermined depth and does not pass through the substrate. To produce the filament-shaped flaw, the ultrashort pulse laser radiates in a pulse or a pulse packet having at least two successive laser pulses. After at least two filament-shaped flaws are introduced, the substrate is exposed to an etching medium which removes material of the substrate and widens the at least two filament-shaped flaws to form filaments. At least two filaments are connected to form a cavity.

Abstract: A method for producing a cavity in a substrate composed of hard brittle material is provided. A laser beam of an ultrashort pulse laser is directed a side surface of the substrate and is concentrated by a focusing optical unit to form an elongated focus in the substrate. Incident energy of the laser beam produces a filament-shaped flaw in a volume of the substrate. The filament-shaped flaw extends into the volume to a predetermined depth and does not pass through the substrate. To produce the filament-shaped flaw, the ultrashort pulse laser radiates in a pulse or a pulse packet having at least two successive laser pulses. After at least two filament-shaped flaws are introduced, the substrate is exposed to an etching medium which removes material of the substrate and widens the at least two filament-shaped flaws to form filaments. At least two filaments are connected to form a cavity.

Abstract: A lithium-ion-conducting composite material and process of producing are provided. The composite material includes at least one polymer and lithium-ion-conducting particles. The particles have a sphericity ? of at least 0.7. The composite material includes at least 20 vol % of the particles for a polydispersity index PI of the particle size distribution of <0.7 or are present in at least 30 vol % of the composite material for the polydispersity index in a range from 0.7 to <1.2, or are present in at least 40 vol % of the composite material for the polydispersity index of >1.2.

Abstract: A powder with particulates of a lithium ion-conducting material has a conductivity of at least 10?5 S/cm. The powder has an inorganic carbon content (Total Inorganic Carbon Content (TIC)) of less than 0.4 wt % and/or an organic carbon content (Total Organic Carbon Content (TOC)) of less than 0.1 wt %. The particulates have a d50 particle size in a range from 0.05 ?m to 10 ?m. The particulates have a particle size distribution log (d90/d10) of less than 4.

Abstract: A lithium-ion-conducting composite material and process of producing are provided. The composite material includes at least one polymer and lithium-ion-conducting particles. The particles have a sphericity ? of at least 0.7. The composite material includes at least 20 vol % of the particles for a polydispersity index PI of the particle size distribution of <0.7 or are present in at least 30 vol % of the composite material for the polydispersity index in a range from 0.7 to <1.2, or are present in at least 40 vol % of the composite material for the polydispersity index of >1.2.

Abstract: The present disclosure relates to a lithium ion conductive material, preferably a lithium ion conductive glass ceramic, the material including a garnet-type crystalline phase content and an amorphous phase content. The material has a sintering temperature of 1000° C. or lower, preferably 950° C. or lower and an ion conductivity of at least 1*10?5 S/cm, preferably at least 2*10?5 S/cm, preferably at least 5*10?5 S/cm, preferably at least 1*10?4 S/cm, and the amorphous phase content includes boron and/or a composition including boron.

Abstract: A lithium-ion-conducting composite material is provided that includes at least one polymer and lithium-ion-conducting particles. The interfacial resistance for the lithium-ion conductivity between the polymer and the particles is reduced as a result of a surface modification of the particles and therefore the lithium-ion conductivity is greater than for a comparable composite material wherein the interfacial resistance between the polymer and the particles is not reduced.

Abstract: An additive for electrochemical energy storages is disclosed, wherein the additive contains at least one silicon- and alkaline earth metal-containing compound V1 which in contact with a fluorine-containing compound V2 in the energy storage forms at least one compound V3 selected from the group consisting of silicon- and fluorine-containing, lithium-free compounds V3a, alkaline earth metal- and fluorine-containing, lithium-free compounds V3b, silicon-, alkaline earth metal- and fluorine-containing, lithium-free compounds V3c and combinations thereof. Also disclosed is an electrochemical energy storage containing the additive.

Abstract: The present disclosure relates to a method for producing a solid electrolyte comprising lithium-ion conductive glass-ceramics. The method includes the steps of: providing at least one lithium ion conductor having a ceramic phase content and amorphous phase content; providing a powder of said at least one lithium ion conductor, the powder having a polydispersity index between 0.5 and 1.5, more preferably between 0.8 and 1.3, and most preferably between 0.85 and 1.15; and at least one of a) incorporating the powder into a polymer electrolyte or a polyelectrolyte and b) forming an element using the powder.

Abstract: A sintering aid mixture for sintering solid-state ion conductors, electrode materials, or the like for solid-state batteries is provided. The mixture includes at least one sol-gel precursor and/or at least one sol-gel direct precursor produced from at least one sol-gel precursor.

Abstract: The present disclosure relates to a lithium ion-conducting glass ceramic which comprises a residual glass phase that is also ion-conducting, a process for the production thereof as well as its use in a battery. The glass ceramic according to the present disclosure comprises a main crystal phase which is isostructural to the NaSICon crystal phase, wherein the composition can be described with the following formula: Li1+x?yMy5+Mx3+M2?x?y4+(PO4)3, wherein x is greater than 0 and at most 1, as well as greater than y. Y may take values of between 0 and 1. Here, the following boundary condition has to be fulfilled: (1+x?y)>1. Here, M represents a cation with the valence of +3, +4 or +5. M3+ is selected from Al, Y, Sc or B, wherein at least Al as trivalent cation is present. Independently thereof, M4+ is selected from Ti, Si or Zr, wherein at least Ti as tetravalent cation is present. Independently thereof, M5+ is selected from Nb, Ta or La.

Abstract: A plate-like glass element includes a pair of opposite side faces and an opening having a transverse dimension of at least 200 ?m. The opening is delimited by an edge. The edge has a plurality of rounded, substantially hemispherical depressions that adjoin one another. The plurality of rounded, substantially hemispherical depressions having abutting concave roundings which form ridges.

Abstract: A method includes: providing a plate-like glass element having side faces and an ultrashort pulse laser having a laser beam; directing the laser beam onto one of the side faces; concentrating the laser beam by focusing optics to form an elongated focus in the glass element; producing a filament-shaped flaw in a volume of the glass element by a radiated-in energy of the laser beam, a longitudinal direction of which runs transverse to one of the side faces, and the ultrashort pulse laser radiates in a pulse or a pulse packet having at least two successive laser pulses to produce the filament-shaped flaw; widening the filament-shaped flaw to form a channel by exposing the glass element to an etching including an etching medium which removes glass at a rate of less than 8 ?m per hour; and introducing rounded, hemispherical depressions in a wall of the channel by the etching.

Abstract: The disclosure relates to a method for producing a solid-state lithium ion conductor material in which the use of water and/or steam is a medium when the obtained intermediate product is cooled or quenched and, if needed, comminution of the intermediate product and/or carrying out of a cooling process with the production of a powder in one comminution step or in a plurality of comminution steps leads or lead to especially advantageous production products. The subject of the disclosure is also the solid-state lithium ion conductor material that has an ion conductivity of at least 10?5 S/cm at room temperature as well as a water content of <1.0 wt %. The disclosure further relates to the use of the solid-state lithium ion conductor material in the form of a powder in batteries or rechargeable batteries, preferably lithium batteries or rechargeable lithium batteries, in particular, separators, cathodes, anodes, or solid-state electrolytes.

Abstract: The disclosure relates to an aluminum-doped lithium ion conductor based on a garnet structure comprising lanthanum, in particular an aluminum-doped lithium lanthanum zirconate (LLZO), in which the latter is co-doped with at least one trivalent M3+ ion on the lanthanum site, and in which the trivalent M3+ ion has an ionic radius that is smaller than that of La3+, and a higher lithium content is present in comparison to a stoichiometric garnet structure, with the provision that if M3+ is yttrium, a further trivalent M3+ ion, which is different than Y3+ and has an ionic radius that is smaller than that of La3+, is co-doped on the lanthanum site. A co-doping strategy is carried out, in which a doping on the lanthanum site with ions of the same valence, but smaller diameter brings about the change in the lattice geometry to the cubic modification. This leads to a stabilization of the cubic crystal modification that is present also with superstoichiometric quantities of lithium.

Abstract: The present disclosure relates to a lithium ion-conducting glass ceramic which comprises a residual glass phase that is also ion-conducting, a process for the production thereof as well as its use in a battery. The glass ceramic according to the present disclosure comprises a main crystal phase which is isostructural to the NaSICon crystal phase, wherein the composition can be described with the following formula: Li1+x?yMy5+Mx3+M2?x?y4+(PO4)3, wherein x is greater than 0 and at most 1, as well as greater than y. Y may take values of between 0 and 1. Here, the following boundary condition has to be fulfilled: (1+x?y)>1. Here, M represents a cation with the valence of +3, +4 or +5. M3+ is selected from Al, Y, Sc or B, wherein at least Al as trivalent cation is present. Independently thereof, M4+ is selected from Ti, Si or Zr, wherein at least Ti as tetravalent cation is present. Independently thereof, M5+ is selected from Nb, Ta or La.

Abstract: A plate-like glass element including a pair of opposite side faces and at least one channel introduced into the glass of the glass element. The at least one channel joins the side faces and opens into the side faces. The at least one channel has a rounded wall and a transverse dimension of less than 100 ?m. The at least one channel extends in a longitudinal direction that runs transverse to the side faces. The rounded wall of the at least one channel has a plurality of rounded, substantially hemispherical depressions.

Abstract: A feed-through component for a conductor feed-through which passes through a part of a housing, for example a battery housing, is embedded in a glass or glass ceramic material and has at least one conductor, for example an essentially pin-shaped conductor, and a head part. The surface, in particular the cross-sectional surface, of the head part is greater than the surface, in particular the cross-sectional surface, of the conductor, for example of the essentially pin-shaped conductor. The head part is embodied such that is can be joined to an electrode-connecting component, for example an electrode-connecting part, which may be made of copper, a copper alloy CuSiC, an aluminum alloy AlSiC or aluminum, with a mechanically stable and non-detachable connection.