Abstract: The present invention relates to nonferrous metallurgy, in particular to the process equipment for electrolytic production of primary aluminum, namely to methods for lining cathode assemblies of reduction cells. A method for lining a cathode of a reduction cell for production of aluminum includes filling a cathode device shell with a thermal insulation layer and leveling said layer; filling, leveling and compacting a refractory layer; installing bottom and side blocks followed by sealing joints therebetween with a cold ramming paste. Prior to filling a shell bottom with the thermal insulation layer, a layer of fine carbonized particles is formed. The inventive method for lining a cathode assembly of a reduction cell for production of primary aluminum allows to reduce the cost of lining materials and energy consumption for reduction cell operation by means of improved heat resistance of a base and to increase the service life of reduction cells.