Abstract: The present invention generally relates to premix compositions having low to zero VOCs according to EPA test methods which are thermally stable, free from HAP's, alkylphenol free, dispersible in cold water and can be formulated into acid or alkaline systems. The premix of the present invention formulates into a rapid degreasing formulation when combined with typical additives used in detergent formulations. The premix composition of the invention comprises at least one nonionic surfactant, at least one cationic surfactant, an effective amount a polyhydric alcohol, and optionally water. The formulations of the present invention can be used in the preparation of aqueous or semi-aqueous detergents formulations for household, institutional and industrial applications with low or zero VOCs.