Abstract: Compounds containing a substituted or unsubstituted allyl group directly bound to a chiral carbon atom are prepared enantioselectively. Starting reactants are either chiral or achiral, and may or may not contain an attached allyloxycarbonyl group as a substituent. Chiral ligands are employed, along with transition metal catalysts. The methods of the invention are effective in providing enantioconvergent allylation of chiral molecules.

Abstract: This system for generating message transformation and validation software uses interface definition documents as inputs. An interface definition consists of an internally consistent set of message definitions, data dictionary entries, transformation rules, and validation rules. A user-friendly graphical user interface provides the requirements engineer or other user with the ability to specify these documents. This graphical user interface is a structured table and rules editor that allows the requirements engineer to enter and validate interface definitions to ensure that the definitions meet certain predetermined requirements. The generation system takes the interface definition documents as input and generates various software artifacts to transform and validate messages. W3C XML schemas are generated from an interface definition for assistance with code development, for use as standards-compliant interface definition that can be reused and composed with other schemas, and for validating messages.