Abstract: Processes for converting one or more C1-C5 alcohols to one or more C2-C5 olefins at a time on stream that is greater than a time on stream of a comparable process are provided. In one exemplary aspect, the process can be a single stage process for the direct conversion of C1-C5 alcohols to olefinic mixtures (e.g., C2-C5) carried out in a reactor using one or more catalysts, where an amount of water within the input stream is reduced and/or pressure within the reactor is increased at different time periods when an amount of an olefin present in the output stream is equal to or less than a target amount. Systems for carrying out these processes are also provided.

Abstract: Processes for converting one or more bio-oil(s) with or without co-feeding C1-C5 alcohols and/or water to one or more C2-C5 olefins and/or one or more aromatics are provided. In one exemplary aspect, the process can be a single stage process for the direct conversion of bio-oil(s) to olefinic (e.g., C2-C5) and aromatic (e.g., BTEX) mixtures carried out in a reactor using one or more catalysts that include a zeolite doped with one or more dopants and a doped or undoped alumina catalyst. Systems for carrying out these processes are also provided.

Abstract: Processes for converting one or more C1-C5 linear or branched alcohols to one or more C2-C5 olefins are provided. In one exemplary embodiment, the process can be a single stage process for the direct conversion of C1-C5 alcohols to olefinic mixtures (e.g., C2-C5) carried out in a reactor using a catalyst that includes zeolite doped with boron and phosphor. Systems for carrying out these processes are also provided.

Abstract: Disclosed are systems, methods, and compositions for producing renewable alcohols, conversion of C1-C5 alcohols to a mixture of C2-C7 olefins to generate stream for recycle to the alcohol conversion step to create or separate oligomerization conversion to generate a predominantly C4+ stream, oligomerizing stream into fuel range olefins to create a stream, separating stream into fractions appropriate for use as gasoline, jet, and diesel fuels. The disclosure also provides systems, methods, and compositions of bio-based ethanol that can be converted to ethylene and subsequently to mixtures of C3-C8 olefins in a single-step.

Abstract: Processes for converting one or more C2-C7 linear or branched olefins to one or more C8-C24 hydrocarbons are provided.

Abstract: Processes for converting one or more C1-C5 linear or branched alcohols to one or more C2-C5 olefins are provided. In one exemplary embodiment, the process can be a single stage process for the direct conversion of C1-C5 alcohols to olefinic mixtures (e.g., C2-C5) carried out in a reactor using a catalyst that includes zeolite doped with boron and phosphor. Systems for carrying out these processes are also provided.

Abstract: Various processes for preparing aldaric acids, aldonic acids, uronic acids, and/or lactone(s) thereof are described. For example, processes for preparing a C5-C6 aldaric acid and/or lactone(s) thereof by the catalytic oxidation of a C5-C6 aldonic acid and/or lactone(s) thereof and/or a C5-C6 aldose are described.

Abstract: Processes for converting one or more C1-C5 linear or branched alcohols to one or more C2-C5 olefins are provided. In one exemplary embodiment, the process can be a single stage process for the direct conversion of C1-C5 alcohols to olefinic mixtures (e.g., C2-C5) carried out in a reactor using a catalyst that includes zeolite doped with boron and phosphor. Systems for carrying out these processes are also provided.

Abstract: Processes for producing two or more different C2-C6 linear or branched olefins are disclosed herein. In one exemplary implementation, the process can include contacting a first feed stream that includes ?-valerolactone with one or more first catalysts in a first reactor to form a mixture. The mixture includes two or more different C2-C6 linear or branched olefins at a yield of at least 60%, and the one or more first catalysts include a doped zeolite. Processes for converting levulinic acid to ?-valerolactone are also disclosed herein.

Abstract: Processes for oxidative pretreatment of carbohydrate dehydration products are disclosed, which relate to the discovery that functional groups of humins, such as those that result in, or lead to, color formation (e.g., aldehyde groups and/or groups having conjugated double bonds) may be more readily converted by oxidation (in some cases “bleached”) than FDCA-forming furanics. This selective oxidation of humins may use milder oxidation conditions and/or a different reaction system, compared to respective conditions and systems used for oxidation of furan ring-containing compounds. Oxidative pretreatment can beneficially promote the selective oxidation of humin functional groups over FDCA-forming furanics, with the overall result of modifying humins in a manner that can provide a number of improvements.

Abstract: A shear ram system includes an upper block coupled to a first arm, the upper block positioned to transition from a first location outside a bore to a second location within the bore, the upper block including an upper blade having a cutout formed at a radially outward end, the cutout having a cutout profile. The shear ram system also includes a lower block coupled to a second arm, the lower block positioned to transition from the first location outside the bore to the second location within the bore, the lower block including a gap control arm including a wear insert arranged axially higher than a lower blade, the gap control arm having an arm profile that substantially conforms to the cutout profile. The wear insert of the gap control arm is configured to engage the cutout when the upper block and the lower block are moved to the second location.

Abstract: Processes for the oxidation of carbohydrate dehydration products, such as furanics that can be oxidized to the bio-based monomer 2,5-furandicarboxylic acid (FDCA), are disclosed, according to which certain co-feeds, having been discovered to impart a beneficial reaction stabilizing effect, are oxidized together with the carbohydrate dehydration products. This can advantageously counteract, in whole or in part, detrimental effects of humin impurities present in oxidation feed, with such impurities having been generated as byproducts of the upstream dehydrating step. An important co-feed is para-xylene that can be co-oxidized to form the petroleum-based monomer terephthalic acid (TPA), such that co-processing can beneficially yield two valuable monomers, while improving performance, particularly in terms of reaction stability, over comparable processes in which only the first monomer is produced.

Abstract: The technology disclosed in this patent document for optical devices for modulating light using nonlinear optical materials exhibiting electro-optical effects. Suitable nonlinear optical materials can be formed over a silicon-based semiconductor substrate via a silicon processing compatible process. In one application, such a device can be implemented for steering light based on a unique two-dimensional array of phased optical modulators using integrated photonic chip fabrication technologies to provide high performance and small footprint device packaging. The phased optical modulators can be phase shifting elements, each of which can be configured as a vertical-cavity surface-emitting phase shifter (VCSEP) to provide effective phase changes via both the control of the optical refractive index of the nonlinear optical material and the metal-dielectric surface plasmon effect.

Abstract: Processes for converting one or more C1-C5 linear or branched alcohols to one or more C2-C5 olefins are provided. In one exemplary embodiment, the process can be a single stage process for the direct conversion of C1-C5 alcohols to olefinic mixtures (e.g., C2-C5) carried out in a reactor using a catalyst that includes zeolite doped with boron and phosphor. Systems for carrying out these processes are also provided.

Abstract: Various processes for preparing aldaric acids, aldonic acids, uronic acids, and/or lactone(s) thereof are described. For example, processes for preparing a C5-C6 aldaric acid and/or lactone(s) thereof by the catalytic oxidation of a C5-C6 aldonic acid and/or lactone(s) thereof and/or a C5-C6 aldose are described.

Abstract: A shear ram system includes an upper block coupled to a first arm, the upper block positioned to transition from a first location outside a bore to a second location within the bore, the upper block including an upper blade having a cutout formed at a radially outward end, the cutout having a cutout profile. The shear ram system also includes a lower block coupled to a second arm, the lower block positioned to transition from the first location outside the bore to the second location within the bore, the lower block including a gap control arm including a wear insert arranged axially higher than a lower blade, the gap control arm having an arm profile that substantially conforms to the cutout profile. The wear insert of the gap control arm is configured to engage the cutout when the upper block and the lower block are moved to the second location.

Abstract: A shear ram system includes an upper block positioned to transition from a first location outside a bore to a second location within the bore, the upper block including a blade control arm having a first contact surface. The shear ram system includes a lower block positioned to transition from the first location outside the bore to the second location within the bore, the lower block including a second contact surface proximate the first contact surface. The shear ram system includes a progressive gap between the first contact surface and the second contact surface larger at a first end than at a second end such that a first gap distance at the first end is greater than a second gap distance the second end.

Abstract: A system is disclosed as including a seal for sealing an area between a hanger and a housing of a wellhead. The seal is provided with at least a notch that defines at least a movable portion such as a wing or a lip. An e-ring is provided for a first energizing of the seal. The movable portion enables pressurized fluid from beneath the seal to cause the movable portion to protrude further against a mating side in the wellhead and the hanger for a second energizing of the seal. This type of seal maintains or improves the sealing of the wellhead in high pressure applications. Methods applied to the above seal are also disclosed.

Abstract: Embodiments include an energizing ring for setting a downhole seal includes a body having a varied cross-section along at least a portion of an axial length. The energizing ring also includes a plurality of peaks forming at least a portion of the varied cross-section having a first diameter. The energizing ring also includes a plurality of valleys forming at least a portion of the varied cross-section having a second diameter, the first diameter being larger than the second diameter, and respective valleys of the plurality of valleys being arranged proximate respective peaks of the plurality of peaks.

Abstract: A system is disclosed as including an enclosed space within a seal for sealing an area between a hanger and a housing of a wellhead. The enclosed space traverses a first section of the seal, a middle section of the seal, and an opening at a second section of the seal. A port is provided as accessible from the housing. A tool positions the seal within the hanger and the housing so that the port is able to access the enclosed space from the housing to the hanger. A pressure applicator applies fluid into the port at a pressure, which is monitored to determine integrity of the seal. In a monitoring mode, a pressure is monitored at the port. A change in the pressure from an ambient pressure at the port may indicate an on-going issue with the seal. Methods applied to the system are also disclosed.