Abstract: The present disclosure provides metalloporphyrin and metallochlorin compounds (e.g., compounds of Formula (II) and (III)), which are useful in the preparation of optical devices (e.g., contact lenses, intraocular lenses, implantable contact lenses) that protect retinal pigment epithelium by the selective blocking of blue light. Also provided are precursor porphyrin and chlorin compounds (e.g., compounds of Formula (I)), and compositions and optical devices incorporating the compounds of the disclosure. Also provided are methods of selecting appropriate metalloporphyrin and metallochlorin compounds for incorporation into optical devices wherein the devices mitigate damage to retinal epithelial cells while balancing changes to luminous transmission, discomfort glare, color distortion, and disruption of circadian rhythms.

Abstract: A system is provided comprising an optical filter. The optical filter comprises a Cu-porphyrin dye compound. The transmission spectrum of the system has an average transmission across the wavelength range of 460 nm-700 nm of at least 60%. The transmission spectrum of the system has an average transmission across the wavelength range 400 nm-460 nm that is less than 75%.

Abstract: A system is provided comprising an optical filter. The optical filter comprises a Cu-porphyrin dye compound. The transmission spectrum of the system has an average transmission across the wavelength range of 460 nm-700 nm of at least 60%. The transmission spectrum of the system has an average transmission across the wavelength range 400 nm-460 nm that is less than 75%.

Abstract: A system is provided that selectively blocks blue light in addition to having low overall transmittance values. The average value of the transmission spectrum of the system across the wavelength range 400 nm-470 nm is between 0% and 30% and the average value of the transmission spectrum across the wavelength range 470 nm-700 nm is between 0% and 70%. The transmission spectrum of the system has a first local minimum in transmission between 400 nm-470 nm.

Abstract: A system is provided comprising an optical filter. The optical filter comprises a Cu-porphyrin dye compound. The transmission spectrum of the system has an average transmission across the wavelength range of 460 nm-700 nm of at least 60%. The transmission spectrum of the system has an average transmission across the wavelength range 400 nm-460 nm that is less than 75%.

Abstract: A system is provided comprising an optical filter. The optical filter comprises a Cu-porphyrin dye compound. The transmission spectrum of the system has an average transmission across the wavelength range of 460 nm-700 nm of at least 80%. The transmission spectrum of the system has an average transmission across the wavelength range 400 nm-460 nm that is less than 75%.

Abstract: An improved dual-filter lens for protective eyewear that combines a first filter for blocking essentially 100% of UV light, and second filter for filtering blue light. The first filter may comprise a multi-layered dielectric mirror layer 14 or Rugate filter 50, and the second filter may comprise dye-impregnated lens layer(s) 16, 18 or Rugate filter 50. The first filter blocks essentially 100% of UV light, while the second filter establishes an increasing transmission profile that cuts on sharply at approximately 415 nm, and establishes an increasing transmission profile between approximately 415 nm to about 475 nm. The cut-on slope rises approximately 0.15% in transmissivity for every nanometer of increasing wavelength change, with a maximum filtering effect within the 440-465 nm range. These dual filters provide a balanced light transmission profile that reduces harmful tight transmission and prevents macular degeneration, cataracts and other ocular injuries, while still preserving visual acuity.

Abstract: A system is provided that selectively blocks blue light in addition to having low overall transmittance values. The average value of the transmission spectrum of the system across the wavelength range 400 nm-470 nm is between 0% and 30% and the average value of the transmission spectrum across the wavelength range 470 nm-700 nm is between 0% and 70%. The transmission spectrum of the system has a first local minimum in transmission between 400 nm-470 nm.

Abstract: A system is provided comprising an optical filter. The optical filter comprises a Cu-porphyrin dye compound. The transmission spectrum of the system has an average transmission across the wavelength range of 460 nm-700 nm of at least 80%. The transmission spectrum of the system has an average transmission across the wavelength range 400 nm-460 nm that is less than 75%.

Abstract: Disclosed herein is a method that comprises providing a solution containing a dye or a dye mixture, ultrasonicating the solution to reduce the average size of aggregates of the dye or dye mixture contained in the solution, and incorporating the dye or the dye mixture in the optical path of a device that transmits light.

Abstract: An improved lens with Rugate filter specifically designed to be worn in prescription and non-prescription glasses, contact lenses, intraocular lenses and sunglasses, and to provide protection against macular degeneration by reducing harmful visible blue light transmission and ocular photochemical damage. The lens at least includes a single lens layer with a Rugate filter deposited thereon to selectively block visible blue light. Other layers may be added including a polarizing layer, dielectric layer and/or color tint in a lens sandwich configuration, to additionally give a high degree of UVA and UVB protection, color contrast, and glare reduction. The Rugate filter is a stop band which yields an exceptional light transmission profile under all light conditions, thereby maximizing protection as well as clarity of vision.

Abstract: An improved dual-filter lens for protective eyewear that combines a first filter for blocking essentially 100% of UV light, and second filter for filtering blue light. The first filter may comprise a multi-layered dielectric mirror layer 14 or Rugate filter 50, and the second filter may comprise dye-impregnated lens layer(s) 16, 18 or Rugate filter 50. The first filter blocks essentially 100% of UV light, while the second filter establishes an increasing transmission profile that cuts on sharply at approximately 415 nm, and establishes an increasing transmission profile between approximately 415 nm to about 475 nm. The cut-on slope rises approximately 0.15% in transmissivity for every nanometer of increasing wavelength change, with a maximum filtering effect within the 440-465 nm range. These dual filters provide a balanced light transmission profile that reduces harmful tight transmission and prevents macular degeneration, cataracts and other ocular injuries, while still preserving visual acuity.

Abstract: An improved dual-filter lens for protective eyewear that combines a first filter for blocking essentially 100% of UV light, and second filter for filtering blue light. The first filter may comprise a multi-layered dielectric mirror layer 14 or Rugate filter 50, and the second filter may comprise dye-impregnated lens layer(s) 16, 18 or Rugate filter 50. The first filter blocks essentially 100% of UV light, while the second filter establishes an increasing transmission profile that cuts on sharply at approximately 415 nm, and establishes an increasing transmission profile between approximately 415 nm to about 475 nm. The cut-on slope rises approximately 0.15% in transmissivity for every nanometer of increasing wavelength change, with a maximum filtering effect within the 440-465 nm range. These dual filters provide a balanced light transmission profile that reduces harmful light transmission and prevents macular degeneration, cataracts and other ocular injuries, while still preserving visual acuity.

Abstract: An improved lens with Rugate filter specifically designed to be worn in prescription and non-prescription glasses, contact lenses, intraocular lenses and sunglasses, and to provide protection against macular degeneration by reducing harmful visible blue light transmission and ocular photochemical damage. The lens at least includes a single lens layer with a Rugate filter deposited thereon to selectively block visible blue light. Other layers may be added including a polarizing layer, dielectric layer and/or color tint in a lens sandwich configuration, to additionally give a high degree of UVA and UVB protection, color contrast, and glare reduction. The Rugate filter is a stop band which yields an exceptional light transmission profile under all light conditions, thereby maximizing protection as well as clarity of vision.

Abstract: Embodiments of the present invention relate to an ophthalmic system that performs effective blue blocking for an ophthalmic lens while at the same time providing a cosmetically attractive product, normal or acceptable color perception for a user, and a high level of transmitted light for good visual acuity.

Abstract: An improved boot for use in ice and snow conditions that combines a flared snowshoe-like secondary sole with integral and selectively deployable crampons. The expanded secondary sole extends approximately ¼? or more down from the primary sole of the boot and includes retractable crampons attached to the expanded sole to increase traction in snow or ice. The expanded sole functions to increase the surface area of the “footprint”, thereby reducing the overall depth of the footprint and making traversing in soft conditions (snow, mud, sand) less fatiguing to the wearer. The crampons may pivot outward from inside pockets in the secondary sole or, alternatively, may slide outward in a stiletto-fashion and/or unfold. The crampons may be individually deployable or simultaneously deployable by a central release button.

Abstract: An improved dual-filter lens for protective eyewear that combines a first filter for blocking essentially 100% of UV light, and second filter for filtering blue light. The first filter may comprise a multi-layered dielectric mirror layer 14 or Rugate filter 50, and the second filter may comprise dye-impregnated lens layer(s) 16, 18 or Rugate filter 50. The first filter blocks essentially 100% of UV light, while the second filter establishes an increasing transmission profile that cuts on sharply at approximately 415 nm, and establishes an increasing transmission profile between approximately 415 nm to about 475 nm. The cut-on slope rises approximately 0.15% in transmissivity for every nanometer of increasing wavelength change, with a maximum filtering effect within the 440-465 nm range. These dual filters provide a balanced light transmission profile that reduces harmful light transmission and prevents macular degeneration, cataracts and other ocular injuries, while still preserving visual acuity.

Abstract: A film suitable for use in an ophthalmic system is provided. The film may selectively inhibit blue light within the wavelength range of 400 nm to 460 nm to reduce phototoxic light to the eye while maintaining photopic vision, and may be color balanced to allow for the system into which the film is incorporated to be perceived as colorless to a viewer observing and/or using the system. The system may have a photopic and scotopic luminous transmission of 85% or more and a phototoxicity ratio of less than 80%. When used in an ophthalmic system or other system disposed between an observer's eye and a light source, the film may reduce the flux of blue light to the internal structures of the eye while reducing or minimizing dilation of the pupil.

Abstract: An ophthalmic system is provided. The system includes an ophthalmic material doped with a dye that absorbs light in a wavelength range and a layer that corrects a color imbalance caused by absorption of light by the dye. The dye can absorb light in a harmful spectral region, such as a narrow blue region. The color balancing layer may allow a user to have a color neutral view when using the system.

Abstract: Embodiments of the present invention relate to an ophthalmic system that performs effective blue blocking for an ophthalmic lens while at the same time providing a cosmetically attractive product, normal or acceptable color perception for a user, and a high level of transmitted light for good visual acuity.