Abstract: Lignocellulosic biomass materials are fractionated by dissolving at least a portion of the lignocellulosic material in an ionic liquid and separating the resulting mixture into a cellulose-enriched fraction and/or a lignin-enriched fraction. The cellulose-enriched fraction contains about 10 percentage points more glucose than the weight percent glucose contained in the original lignocellulosic biomass material. In certain embodiments, the lignin-enriched fraction includes a lignin content that is 5 percentage points greater than the weight percent lignin present in the original lignocellulosic material. The techniques used to isolate the cellulose-enriched fractions and/or the lignin-enriched fractions from the ionic liquid mixture do not employ environmentally unfriendly solvents.

Abstract: Lignocellulosic biomass materials are fractionated by dissolving at least a portion of the lignocellulosic material in an ionic liquid and separating the resulting mixture into a cellulose-enriched fraction and/or a lignin-enriched fraction. The cellulose-enriched fraction contains about 10 percentage points more glucose than the weight percent glucose contained in the original lignocellulosic biomass material. In certain embodiments, the lignin-enriched fraction includes a lignin content that is 5 percentage points greater than the weight percent lignin present in the original lignocellulosic material. The techniques used to isolate the cellulose-enriched fractions and/or the lignin-enriched fractions from the ionic liquid mixture do not employ environmentally unfriendly solvents.

Abstract: The disclosure includes lignin mixed esters comprising first ester groups and second ester groups wherein the number of carbon atoms in the first ester group differs from the number of carbon atoms in the second ester group by 3 or more and processes of making the same. The unique thermal glass transition temperature properties of such lignin mixed esters are described.