Patents by Inventor Angella Nicholle Greenawalt

Angella Nicholle Greenawalt has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11953480
    Abstract: An embodiment provides a method for measuring peracetic acid concentration in an aqueous solution, including: combining, in a reactive solution, 4-(methylthio)aniline and at least one reactive species to produce a chromophore, wherein the at least one reactive species comprises a chromotropic acid disodium salt; placing the chromophore in an aqueous solution, wherein the aqueous solution comprises peracetic acid, wherein peracetic acid within the aqueous solution reacts with the chromophore; and measuring a concentration of peracetic acid within the aqueous solution, wherein the measuring comprises quantifying a colorimetric change of the aqueous solution caused by the peracetic acid reacting with the chromophore. Other embodiments are described and claimed.
    Type: Grant
    Filed: June 27, 2019
    Date of Patent: April 9, 2024
    Assignee: HACH COMPANY
    Inventors: Angella Nicholle Greenawalt, Darren Kent MacFarland
  • Publication number: 20230375514
    Abstract: An embodiment provides a method for measuring ozone in a sample, including: preparing a thiocarbamate-based indicator; introducing the thiocarbamate-based indicator to a sample, wherein the sample contains an amount of ozone and the introducing causes a change in fluorescence of the solution; and measuring the amount of ozone in the sample by measuring the change in intensity of the fluorescence. Other aspects are described and claimed.
    Type: Application
    Filed: May 17, 2023
    Publication date: November 23, 2023
    Inventors: Angella Nicholle Greenawalt, Amit Das
  • Publication number: 20230067125
    Abstract: An embodiment a method for measuring an amount of manganese in an aqueous sample, including: reducing, using a dechlorination reagent, wherein the dechlorination reagent comprises iron(II) and potassium iodide; oxidizing, under an alkaline condition using sodium hydroxide, Mn(II) to Mn(IV) in the aqueous sample, and chelating, using etidronic acid (HEDP), Fe(II) and Fe(III) in the aqueous sample, oxidizing an amount of 3,3?,5,5?-tetramethylbenzidine (TMB) with Mn(IV); and measuring, using a colorimetric indicator, the amount of manganese within the aqueous sample, by measuring an absorbance intensity at a wavelength of the oxidized amount of 3,3?,5,5?-tetramethylbenzidine (TMB). Other aspects are described and claimed.
    Type: Application
    Filed: May 27, 2022
    Publication date: March 2, 2023
    Inventor: Angella Nicholle Greenawalt
  • Patent number: 11567052
    Abstract: An embodiment provides a method for measuring nitrate in an aqueous sample, including: introducing an aqueous sample containing an amount of nitrate to a cation exchange resin; flowing the aqueous sample over copper metal; adding a reducing reagent to the aqueous sample; adding a colorimetric indicator to the aqueous sample; and measuring the amount of nitrate in the aqueous sample by measuring a change in intensity of the absorbance. Other aspects are described and claimed.
    Type: Grant
    Filed: October 29, 2019
    Date of Patent: January 31, 2023
    Assignee: HACH COMPANY
    Inventor: Angella Nicholle Greenawalt
  • Patent number: 11549884
    Abstract: An embodiment provides a method for measuring zinc and copper in an aqueous sample, including: reducing an aqueous sample containing an amount of zinc and an amount of copper with a reducing agent; buffering the reduced aqueous sample; chelating the amount of copper in the buffered aqueous sample with a copper(I) chelating agent; measuring the amount of copper in the aqueous sample by measuring a first change in intensity of the absorbance of the copper chelated aqueous sample; chelating the amount of zinc in the buffered aqueous sample with a zinc(II) chelating agent; and measuring the amount of zinc in the aqueous sample by measuring a second change in intensity of the absorbance of the zinc chelated aqueous sample. Other aspects are described and claimed.
    Type: Grant
    Filed: September 14, 2020
    Date of Patent: January 10, 2023
    Assignee: HACH COMPANY
    Inventors: Angella Nicholle Greenawalt, Brendan Easley Young, Melanie Ann Roth
  • Patent number: 11422093
    Abstract: An embodiment provides a method for measuring free chlorine in a solution, including: preparing a thiocarbamate-based indicator; introducing the thiocarbamate-based indicator to a solution, wherein the solution contains an amount of free chlorine and the introducing causes a change in fluorescence of the solution; and measuring the amount of free chlorine in the solution by measuring a change in intensity of the fluorescence. Other aspects are described and claimed.
    Type: Grant
    Filed: June 6, 2019
    Date of Patent: August 23, 2022
    Assignee: HACH COMPANY
    Inventors: Amit Das, Darren Kent MacFarland, Angella Nicholle Greenawalt, Daniel Gustav Mieritz
  • Publication number: 20220178892
    Abstract: An embodiment provides a method for measuring an ion component of an aqueous sample using a photoreactive species, including: generating a metal organic framework by combining, in a reactive solution, at least one organic linker and at least one metal; impregnating the metal organic framework with the photoreactive species; introducing the impregnated metal organic framework into an aqueous sample; and measuring an analyte component concentration of the aqueous sample, wherein the measuring comprises measuring a change in the aqueous sample, wherein the change is responsive to the analyte component dissolving at least one of: the at least one organic linker and the at least one metal, and releasing the photoreactive species. Other embodiments are described and claimed.
    Type: Application
    Filed: March 28, 2020
    Publication date: June 9, 2022
    Inventors: Daniel Gustav Mieritz, Angella Nicholle Greenawalt
  • Patent number: 11333645
    Abstract: An embodiment provides A method for measuring fluoride concentration in an aqueous solution, including: preparing a metal-ligand complex, wherein the metal-ligand complex comprises chromeazurol S and aluminum; placing the metal-ligand complex in a sample containing fluoride, wherein the placing generates a color change by releasing the chromeazurol S from the metal-ligand complex; and measuring, using colorimetric techniques, a concentration of fluoride within the sample, wherein the measuring comprises measuring an absorbance wavelength of a colorimetric ligand. Other embodiments are described and claimed.
    Type: Grant
    Filed: April 17, 2019
    Date of Patent: May 17, 2022
    Assignee: HACH COMPANY
    Inventor: Angella Nicholle Greenawalt
  • Publication number: 20220082493
    Abstract: An embodiment provides a method for measuring zinc and copper in an aqueous sample, including: reducing an aqueous sample containing an amount of zinc and an amount of copper with a reducing agent; buffering the reduced aqueous sample; chelating the amount of copper in the buffered aqueous sample with a copper(I) chelating agent; measuring the amount of copper in the aqueous sample by measuring a first change in intensity of the absorbance of the copper chelated aqueous sample; chelating the amount of zinc in the buffered aqueous sample with a zinc(II) chelating agent; and measuring the amount of zinc in the aqueous sample by measuring a second change in intensity of the absorbance of the zinc chelated aqueous sample. Other aspects are described and claimed.
    Type: Application
    Filed: September 14, 2020
    Publication date: March 17, 2022
    Inventors: Angella Nicholle Greenawalt, Brendan Easley Young, Melanie Ann Roth
  • Publication number: 20210372924
    Abstract: An embodiment provides a method for measuring zinc in a solution, including: preparing an indicator solution; introducing the indicator solution to a solution, wherein the solution contains an amount of zinc and the introducing causes a change in fluorescence of the solution in response to the indicator solution reacting with the zinc; and measuring the amount of zinc in the solution by measuring a change in intensity of the fluorescence. Other aspects are described and claimed.
    Type: Application
    Filed: May 26, 2020
    Publication date: December 2, 2021
    Inventor: Angella Nicholle Greenawalt
  • Publication number: 20210208119
    Abstract: An embodiment provides a method for measuring peracetic acid concentration in an aqueous solution, including: combining, in a reactive solution, 4-(methylthio)aniline and at least one reactive species to produce a chromophore, wherein the at least one reactive species comprises a chromotropic acid disodium salt; placing the chromophore in an aqueous solution, wherein the aqueous solution comprises peracetic acid, wherein peracetic acid within the aqueous solution reacts with the chromophore; and measuring a concentration of peracetic acid within the aqueous solution, wherein the measuring comprises quantifying a colorimetric change of the aqueous solution caused by the peracetic acid reacting with the chromophore. Other embodiments are described and claimed.
    Type: Application
    Filed: June 27, 2019
    Publication date: July 8, 2021
    Inventors: Angella Nicholle Greenawalt, Darren Kent MacFarland
  • Publication number: 20210123898
    Abstract: An embodiment provides a method for measuring nitrate in an aqueous sample, including: introducing an aqueous sample containing an amount of nitrate to a cation exchange resin; flowing the aqueous sample over copper metal; adding a reducing reagent to the aqueous sample; adding a colorimetric indicator to the aqueous sample; and measuring the amount of nitrate in the aqueous sample by measuring a change in intensity of the absorbance. Other aspects are described and claimed.
    Type: Application
    Filed: October 29, 2019
    Publication date: April 29, 2021
    Inventor: Angella Nicholle Greenawalt
  • Patent number: 10890574
    Abstract: An embodiment provides a method for measuring a concentration of lead(0) in an aqueous sample, including: introducing an aqueous sample to a reaction vessel; adding a copper(II) acetate material to the aqueous sample in the reaction vessel; chelating unreacted copper(II) material by introduction of an organosulfur compound to the aqueous sample in the reaction vessel; adding a colorimetric indicator to the aqueous sample in the reaction vessel; and measuring a concentration of lead(II) in the aqueous sample by measuring a colorimetric change of the aqueous sample caused by a reaction of lead(II) within the aqueous sample with the colorimetric indicator. Other aspects are described and claimed.
    Type: Grant
    Filed: November 5, 2018
    Date of Patent: January 12, 2021
    Assignee: HACH COMPANY
    Inventor: Angella Nicholle Greenawalt
  • Publication number: 20200386682
    Abstract: An embodiment provides a method for measuring free chlorine in a solution, including: preparing a thiocarbamate-based indicator; introducing the thiocarbamate-based indicator to a solution, wherein the solution contains an amount of free chlorine and the introducing causes a change in fluorescence of the solution; and measuring the amount of free chlorine in the solution by measuring a change in intensity of the fluorescence. Other aspects are described and claimed.
    Type: Application
    Filed: June 6, 2019
    Publication date: December 10, 2020
    Inventors: Amit Das, Darren Kent MacFarland, Angella Nicholle Greenawalt, Daniel Gustav Mieritz
  • Publication number: 20200333304
    Abstract: An embodiment provides A method for measuring fluoride concentration in an aqueous solution, including: preparing a metal-ligand complex, wherein the metal-ligand complex comprises chromeazurol S and aluminum; placing the metal-ligand complex in a sample containing fluoride, wherein the placing generates a color change by releasing the chromeazurol S from the metal-ligand complex; and measuring, using colorimetric techniques, a concentration of fluoride within the sample, wherein the measuring comprises measuring an absorbance wavelength of a colorimetric ligand. Other embodiments are described and claimed.
    Type: Application
    Filed: April 17, 2019
    Publication date: October 22, 2020
    Inventor: Angella Nicholle Greenawalt
  • Patent number: 10794882
    Abstract: An embodiment provides a method for measuring fluoride concentration in an aqueous solution, including: preparing a polyethylene glycol (PEG) monomethyl ether to produce an ester; reacting the ester in the presence of ammoniated tetrahydrofuran to produce an amino polyethylene glycol; placing, in a solution comprising a benzaldehyde species with a phenol functional group and a carboxylic acid functional group, a 2,3,3-trimethylindolenine derivative to produce a hemicyanine with a phenol functional group and a carboxylic acid functional group; combining, in a polar aprotic solvent, the hemicyanine with the phenol functional group and carboxylic acid functional group with a 1,1-carbonyldiimidazole (CDI) and adding the amino-PEG to produce a hemicyanine-PEG; and creating a fluoride sensitive hemicyanine species by reacting the hemicyanine-PEG that contains a phenol functional group with a SiR3 species. Other embodiments are described and claimed.
    Type: Grant
    Filed: April 12, 2018
    Date of Patent: October 6, 2020
    Assignee: HACH COMPANY
    Inventors: Darren Kent MacFarland, Angella Nicholle Greenawalt
  • Patent number: 10794883
    Abstract: An embodiment provides a method for measuring aluminum concentration in an aqueous sample, including: preparing a chromeazurol S indicator solution; placing the chromeazurol S indicator solution in a sample containing aluminum, wherein the placing causes the chromeazurol S to chelate aluminum within the sample creating a colored complex; and measuring, using colorimetric techniques, a concentration of aluminum within the sample, wherein the measuring comprises measuring an absorbance at a wavelength for the colored complex. Other embodiments are described and claimed.
    Type: Grant
    Filed: February 15, 2019
    Date of Patent: October 6, 2020
    Assignee: Hach Company
    Inventors: Melanie Ann Roth, Angella NIcholle Greenawalt
  • Publication number: 20200264145
    Abstract: An embodiment provides a method for measuring aluminum concentration in an aqueous sample, including: preparing a chromeazurol S indicator solution; placing the chromeazurol S indicator solution in a sample containing aluminum, wherein the placing causes the chromeazurol S to chelate aluminum within the sample creating a colored complex; and measuring, using colorimetric techniques, a concentration of aluminum within the sample, wherein the measuring comprises measuring an absorbance at a wavelength for the colored complex. Other embodiments are described and claimed.
    Type: Application
    Filed: February 15, 2019
    Publication date: August 20, 2020
    Inventors: Melanie Ann Roth, Angella Nicholle Greenawalt
  • Publication number: 20200141916
    Abstract: An embodiment provides a method for measuring a concentration of lead(0) in an aqueous sample, including: introducing an aqueous sample to a reaction vessel; adding a copper(II) acetate material to the aqueous sample in the reaction vessel; chelating unreacted copper(II) material by introduction of an organosulfur compound to the aqueous sample in the reaction vessel; adding a colorimetric indicator to the aqueous sample in the reaction vessel; and measuring a concentration of lead(II) in the aqueous sample by measuring a colorimetric change of the aqueous sample caused by a reaction of lead(II) within the aqueous sample with the colorimetric indicator. Other aspects are described and claimed.
    Type: Application
    Filed: November 5, 2018
    Publication date: May 7, 2020
    Inventor: Angella Nicholle Greenawalt
  • Publication number: 20190317064
    Abstract: An embodiment provides a method for measuring fluoride concentration in an aqueous solution, including: preparing a polyethylene glycol (PEG) monomethyl ether to produce an ester; reacting the ester in the presence of ammoniated tetrahydrofuran to produce an amino polyethylene glycol; placing, in a solution comprising a benzaldehyde species with a phenol functional group and a carboxylic acid functional group, a 2,3,3-trimethylindolenine derivative to produce a hemicyanine with a phenol functional group and a carboxylic acid functional group; combining, in a polar aprotic solvent, the hemicyanine with the phenol functional group and carboxylic acid functional group with a 1,1-carbonyldiimidazole (CDI) and adding the amino-PEG to produce a hemicyanine-PEG; and creating a fluoride sensitive hemicyanine species by reacting the hemicyanine-PEG that contains a phenol functional group with a SiR3 species. Other embodiments are described and claimed.
    Type: Application
    Filed: April 12, 2018
    Publication date: October 17, 2019
    Inventors: Darren Kent MacFarland, Angella Nicholle Greenawalt