Patents by Inventor Angelo Vaccari

Angelo Vaccari has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10464049
    Abstract: A process to synthesize a catalyst performing Water-Gas shift reaction at a temperature more than 300° C. using a precursor having general formula [(Cu, Zn)1-x (Al, M)x (OH)2]x+ (An?x/n).kH2O with M=Al, La, Ga or In, A=CO3, 0.33<x<0.5, 1<n<3.
    Type: Grant
    Filed: June 2, 2017
    Date of Patent: November 5, 2019
    Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, Alma Mater Studiorum Universita de Bologna
    Inventors: Raphaël Faure, Giuseppe Fornasari, Daniel Gary, Carlo Lucarelli, Nicola Schiaroli, Angelo Vaccari
  • Publication number: 20170348675
    Abstract: A process to synthesize a catalyst performing Water-Gas shift reaction at a temperature more than 300° C. using a precursor having general formula [(Cu, Zn)1?x (Al, M)x (OH)2]x+ (An?x/n).kH2O with M=Al, La, Ga or In, A=CO3, 0.33<x<0.5, 1<n<3.
    Type: Application
    Filed: June 2, 2017
    Publication date: December 7, 2017
    Inventors: Raphaël FAURE, Giuseppe FORNASARI, Daniel GARY, Carlo LUCARELLI, Nicola SCHIAROLI, Angelo VACCARI
  • Patent number: 9604201
    Abstract: Process for treating a catalytic reactor comprising a catalyst bed that includes the successive steps of passivating the catalytic reactor leading to the production of an oxidation layer at the surface of the active sites of the catalyst bed, opening the reactor, and skimming at least one portion of the catalyst bed.
    Type: Grant
    Filed: March 5, 2014
    Date of Patent: March 28, 2017
    Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Daniel Gary, Raphael Faure, Olivier Debellemaniere, Angelo Vaccari, Giuseppe Brenna
  • Publication number: 20160023194
    Abstract: Process for treating a catalytic reactor comprising a catalyst bed that includes the successive steps of passivating the catalytic reactor leading to the production of an oxidation layer at the surface of the active sites of the catalyst bed, opening the reactor, and skimming at least one portion of the catalyst bed.
    Type: Application
    Filed: March 5, 2014
    Publication date: January 28, 2016
    Applicant: L'AIR LIQUIDE, SOCIETE ANONYME POUR I'ETUDE ET I'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Daniel GARY, Raphael FAURE, Olivier DEBELLEMANIERE, Angelo VACCARI, Giuseppe BRENNA
  • Publication number: 20140336041
    Abstract: [RhxMgyAlw(OH)2](3x+2y+3w?2)+(A2?)(3x+2y+3w?2)/2,k H2) (I) Hydrotalcite-like compound of the formula (I): catalyst synthesis process involving such a compound, and the use of this catalyst for hydrocarbons reforming and for ethanol reforming.
    Type: Application
    Filed: November 14, 2012
    Publication date: November 13, 2014
    Inventors: Francesco Basile, Angelo Vaccari, Giuseppe Fornasari, Irene Bersani, Pascal Del-Gallo, Daniel Gary
  • Publication number: 20140309102
    Abstract: A hydrotalcite-type compound of the formula (I): [CuxZnyAlw(OH)2](2x+2y+3w?2)+(A2?)(2x+2y+3w?2)/n,kH2O??(I) wherein (A2?) represents either a carbonate anion or a silicate anion, x>0, y>0, w>0, (x+y)=(1?w), 1<[(x+y)/w]<5, and 1/99?x/y?1/1; a synthesis process for its preparation; a catalyst obtained by its calcination and the subsequent reduction of the calcined product.
    Type: Application
    Filed: November 14, 2012
    Publication date: October 16, 2014
    Inventors: Francesco Basile, Guiseppe Brenna, Raphael Faure, Guiseppe Fornasari, Daniel Gary, Angelo Vaccari
  • Publication number: 20120149548
    Abstract: Process for the preparation of a catalytic specie consisting essentially of a metallic support, which is coated with a ceramic active phase layer, mainly compound of the general formula (I): [RhxNiyMglAlm(OH)2]z+(An?z/n) kH2O.
    Type: Application
    Filed: December 13, 2011
    Publication date: June 14, 2012
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Daniel Gary, Pascal Del-Gallo, Francesco Basile, Angelo Vaccari, Giuseppe Fornasari, Valentina Rosetti, Erika Scavetta, Domenica Tonelli
  • Patent number: 8105973
    Abstract: Chemical combination (C) between an active solid phase which is covalently bound to the surface of an inert solid phase, characterized in that said solid active phase essentially consists in a solid solution of a mixture of at least a magnesium oxide type phase compound and at least a magnesium silicate type phase compound in which Al, and Rh and/or Ni cations are soluted and characterized in that said inert solid phase is either a compound represented by the general formula (I): AlaNibRhcMgdSieOf??(I) wherein a, b, c, d, and e are integers which are greater than or equal to 0, f is an integer greater than 0, the sum a+b+c+d?0, and wherein (3a+2b+3c+2d+4e)/2=f, or a mixture of compounds represented by the said general formula (I), provided that at least one of the Si, Al, Mg, Rh or Ni elements, which is present in the solid active phase, is also present in the solid inert phase. Use of a catalyst in chemical reactions involving the conversion of hydrocarbonaceous feedstocks.
    Type: Grant
    Filed: November 18, 2010
    Date of Patent: January 31, 2012
    Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploiation des Procedes Georges Claude
    Inventors: Francesco Basile, Pascal Del Gallo, Giuseppe Fornasari, Daniel Gary, Valentina Rosetti, Angelo Vaccari
  • Patent number: 8092716
    Abstract: Process for the preparation of a catalytic specie consisting essentially of a metallic support, which is coated with a ceramic active phase layer, mainly compound of the general formula (I): [RhxNiyMglAlm(OH)2]z+(An?z/n)kH2O,??(I) wherein An? is mainly a silicate or a polysilicate anion; 0?x?0.3; 0?y?0.9; 0?l?0.9; 0?m?0.5; 0?k?10; x+y>0; 0.5?y+l?0.9; x+y+l+m=1; and z is the total electrical charge of the cationic element or a compound of the general formula (II): [AzA?1-z][B1-x-yNixRhy]O3-???(II) wherein A and A? are different and are selected from the Lanthanide or the Actinide families or from the group IIa of the Mendeleev's periodical table of elements; B is selected from the transition metal groups of columns IIIb, IVb, Vb, VIb, VIIb, Ib and IIb and group VIIIb of the Mendeleev's periodical table of elements; 0?x?0.7, 0?y?0.5, 0?x+y?0.
    Type: Grant
    Filed: January 10, 2007
    Date of Patent: January 10, 2012
    Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Daniel Gary, Pascal Del-Gallo, Francesco Basile, Angelo Vaccari, Giuseppe Fornasari, Valentina Rosetti, Erika Scavetta, Domenica Tonelli
  • Publication number: 20110118112
    Abstract: Chemical combination (C) between an active solid phase which is covalently bound to the surface of an inert solid phase, characterized in that said solid active phase essentially consists in a solid solution of a mixture of at least a magnesium oxide type phase compound and at least a magnesium silicate type phase compound in which Al, and Rh and/or Ni cations are soluted and characterized in that said inert solid phase is either a compound represented by the general formula (I): AlaNibRhcMgdSieOf??(I) wherein a, b, c, d, and e are integers which are greater than or equal to 0, f is an integer greater than 0, the sum a+b+c+d?0, and wherein (3a+2b+3c+2d+4e)/2=f, or a mixture of compounds represented by the said general formula (I), provided that at least one of the Si, Al, Mg, Rh or Ni elements, which is present in the solid active phase, is also present in the solid inert phase. Use of a catalyst in chemical reactions involving the conversion of hydrocarbonaceous feedstocks.
    Type: Application
    Filed: November 18, 2010
    Publication date: May 19, 2011
    Inventors: Francesco Basile, Pascal Del Gallo, Giuseppe Fornasari, Daniel Gary, Valentina Rosetti, Angelo Vaccari
  • Publication number: 20110017953
    Abstract: Process for the preparation of a catalytic specie consisting essentially of a metallic support, which is coated with a ceramic active phase layer, mainly compound of the general formula (I): [RhxNiyMglAlm(OH)2]z+(An?z/n)kH2O,??(I) wherein An? is mainly a silicate or a polysilicate anion; 0?x?0.3; 0?y?0.9; 0?l?0.9; 0?m?0.5; 0?k?10; x+y>0; 0.5?y+l?0.9; x+y+l+m=1; and z is the total electrical charge of the cationic element or a compound of the general formula (II): [AzA?1-z][B1-x-yNixRhy]O3-???(II) wherein A and A? are different and are selected from the Lanthanide or the Actinide families or from the group IIa of the Mendeleev's periodical table of elements; B is selected from the transition metal groups of columns IIIb, IVb, Vb, VIb, VIIb, Ib and IIb and group VIIIb of the Mendeleev's periodical table of elements; 0?x?0.7, 0?y?0.5, 0?x+y?0.
    Type: Application
    Filed: January 10, 2007
    Publication date: January 27, 2011
    Inventors: Daniel Gary, Pascal Del-Gallo, Francesco Basile, Angelo Vaccari, Giuseppe Fornasari, Valentina Rosetti, Erika Scavetta, Domenica Tonelli
  • Patent number: 7329691
    Abstract: A composition and method for a Catalytic Partial Oxidation (CPO) of methane to synthesis gas. The catalyst allows the process to proceed at low residence time providing a long time thermal stability. The perovskite structure [AzA?1-z][B1-x-yNix Rhy] O3-? of the catalyst is obtained using mainly La, Sr, as A and A? cation sites (A, A?: actinide and/or lanthanide, elements and/or elements from Group I and II) and mainly Fe, Ni, as B cation sites (B: transition metal element and/or element from Group III to V).
    Type: Grant
    Filed: November 13, 2003
    Date of Patent: February 12, 2008
    Assignee: L'Air Liquid, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Francesco Basile, Giuseppe Fornasari, Angelo Vaccari, Pascal Del Gallo, Daniel Gary
  • Publication number: 20060148640
    Abstract: The present invention relates to the use of a silicon-based porous catalytic system for oligomerizing light olefins, the porous silicon-based catalytic system having an average pore diameter of between about 1 nm and about 5 nm and an acidity level of between about 150 ?mol/g and about 650 ?mol/g, and prepared from at least one hydrolysable silicon-based compound, or other source of silicon, and at least one non-ionic surface active agent. The invention also relates to a process for oligomerizing light olefins using the silicon-based porous catalytic system, and to certain silicon-based porous catalytic systems.
    Type: Application
    Filed: October 15, 2003
    Publication date: July 6, 2006
    Inventors: Jacques Roziere, Deborah Jones, Melanie Jacquin, Stefano Rossini, Roberto Catani, Angelo Vaccari, Maurizio Lenarda, Antonio Jimenez-Lopez, Jose-Manuel Trejo-Menayo, Enrique Rodriguez-Castellon, Pedro Mairelles-Torres
  • Publication number: 20050181930
    Abstract: A process of preparation of silicon-based multifunctional catalytic systems synthesised together with one or more surface active agents is described. Also described is a multifunctional silicon-based porous catalytic system including at least one porous catalytic support structurally including silica and at least one other metal or non-metal oxide chosen from aluminium, zirconium, and boron. The catalytic support is synthesised together with one or more surface active agents, and at least one or more catalyst chosen from among metallic elements of groups 6-10 of the periodic table of the elements. The catalytic systems are useful in hydrogenation and/or decyclisation reactions of (poly)aromatic compounds, especially for improving the quality of diesel fuels and increasing their cetane number.
    Type: Application
    Filed: January 31, 2003
    Publication date: August 18, 2005
    Inventors: Jacques Roziere, Deborah Jones, Melanie Jacquin, Antonio Jimenez-Lopez, Enrique Rodriguez-Castellon, Pedro Maireles-Torres, Jose-Manuel Trejo-Menayo, Angelo Vaccari, Maurizio Lenarda, Guido Busca
  • Publication number: 20050156622
    Abstract: A semiconductor test device for acquiring a multiplexed clock signal from LSI output data and using the clock to test the LSI. The device includes a time interpolator 30 and registers 41a to 41n connected in series. The time interpolator has flip-flops 31a to 31n connected in parallel for inputting output data from an LSI 1 to be measured, a delay circuit 32 for successively inputting strobes delayed at a constant timing interval to the flip-flops 31 and outputting time-series level data, and an encoder 34 for inputting the time-series level data output from the flip-flops 31 and encoding it into position data indicating an edge timing. The registers 41a to 41n successively store position data from the encoder 34 and output them at a predetermined timing. The device further includes a digital filter for outputting the position data output from the registers 41 as a recovery clock.
    Type: Application
    Filed: April 21, 2003
    Publication date: July 21, 2005
    Inventors: Jacques Roziere, Deborah Jones, Melanie Jacquin, Antonio Jimenez-Lopez, Enrique Rodriguez-Castellon, Pedro Maireles-Torres, Jose-Manuel Trejo-Menayo, Angelo Vaccari, Maurizio Lenarda, Guido Busca
  • Publication number: 20040127351
    Abstract: The present patent deals with new catalysts for the Catalytic Partial Oxidation (CPO) of methane to synthesis gas (hydrogen and carbon monoxide), a gas mixture widely employed in industry. The discovered perovskite catalysts allows to carried out the process at low residence time obtaining a long time stability in the reaction conditions notwithstanding the high temperature reached in the reactor. The fundamental component of the catalyst is the perovskite structure [AzA′1-z][B1-x-yNixRhy]O3-&dgr; obtained using mainly La, Sr, as A and A′ cation sites (A, A′: actinide and/or lanthanide, elements and/or elements from Group I and II) and mainly Fe, Ni, as B cation sites (B: transition metal element and/or element from Group III to V). The active phases Ni and/or Rh are inserted in the perovskite structure during the preparation and are reduced in situ or before the catalytic tests.
    Type: Application
    Filed: November 13, 2003
    Publication date: July 1, 2004
    Inventors: Francesco Basile, Giuseppe Fornasari, Angelo Vaccari, Pascal Del Gallo, Daniel Gary
  • Patent number: 5698713
    Abstract: Disclosed is a process for the production of gamma-butyrolactone from maleic anhydride or succinic anhydride by hydrogenation in the presence of a catalyst composition comprising the mixed oxides of copper, zinc and zirconium.
    Type: Grant
    Filed: February 20, 1997
    Date of Patent: December 16, 1997
    Assignee: Lonza S.P.A.
    Inventors: Rosa Lancia, Angelo Vaccari, Carlo Fumagalli, Erich Armbruster