Patents by Inventor Angelo Vaccari
Angelo Vaccari has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10464049Abstract: A process to synthesize a catalyst performing Water-Gas shift reaction at a temperature more than 300° C. using a precursor having general formula [(Cu, Zn)1-x (Al, M)x (OH)2]x+ (An?x/n).kH2O with M=Al, La, Ga or In, A=CO3, 0.33<x<0.5, 1<n<3.Type: GrantFiled: June 2, 2017Date of Patent: November 5, 2019Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, Alma Mater Studiorum Universita de BolognaInventors: Raphaël Faure, Giuseppe Fornasari, Daniel Gary, Carlo Lucarelli, Nicola Schiaroli, Angelo Vaccari
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Publication number: 20170348675Abstract: A process to synthesize a catalyst performing Water-Gas shift reaction at a temperature more than 300° C. using a precursor having general formula [(Cu, Zn)1?x (Al, M)x (OH)2]x+ (An?x/n).kH2O with M=Al, La, Ga or In, A=CO3, 0.33<x<0.5, 1<n<3.Type: ApplicationFiled: June 2, 2017Publication date: December 7, 2017Inventors: Raphaël FAURE, Giuseppe FORNASARI, Daniel GARY, Carlo LUCARELLI, Nicola SCHIAROLI, Angelo VACCARI
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Patent number: 9604201Abstract: Process for treating a catalytic reactor comprising a catalyst bed that includes the successive steps of passivating the catalytic reactor leading to the production of an oxidation layer at the surface of the active sites of the catalyst bed, opening the reactor, and skimming at least one portion of the catalyst bed.Type: GrantFiled: March 5, 2014Date of Patent: March 28, 2017Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges ClaudeInventors: Daniel Gary, Raphael Faure, Olivier Debellemaniere, Angelo Vaccari, Giuseppe Brenna
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Publication number: 20160023194Abstract: Process for treating a catalytic reactor comprising a catalyst bed that includes the successive steps of passivating the catalytic reactor leading to the production of an oxidation layer at the surface of the active sites of the catalyst bed, opening the reactor, and skimming at least one portion of the catalyst bed.Type: ApplicationFiled: March 5, 2014Publication date: January 28, 2016Applicant: L'AIR LIQUIDE, SOCIETE ANONYME POUR I'ETUDE ET I'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Daniel GARY, Raphael FAURE, Olivier DEBELLEMANIERE, Angelo VACCARI, Giuseppe BRENNA
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Publication number: 20140336041Abstract: [RhxMgyAlw(OH)2](3x+2y+3w?2)+(A2?)(3x+2y+3w?2)/2,k H2) (I) Hydrotalcite-like compound of the formula (I): catalyst synthesis process involving such a compound, and the use of this catalyst for hydrocarbons reforming and for ethanol reforming.Type: ApplicationFiled: November 14, 2012Publication date: November 13, 2014Inventors: Francesco Basile, Angelo Vaccari, Giuseppe Fornasari, Irene Bersani, Pascal Del-Gallo, Daniel Gary
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Publication number: 20140309102Abstract: A hydrotalcite-type compound of the formula (I): [CuxZnyAlw(OH)2](2x+2y+3w?2)+(A2?)(2x+2y+3w?2)/n,kH2O??(I) wherein (A2?) represents either a carbonate anion or a silicate anion, x>0, y>0, w>0, (x+y)=(1?w), 1<[(x+y)/w]<5, and 1/99?x/y?1/1; a synthesis process for its preparation; a catalyst obtained by its calcination and the subsequent reduction of the calcined product.Type: ApplicationFiled: November 14, 2012Publication date: October 16, 2014Inventors: Francesco Basile, Guiseppe Brenna, Raphael Faure, Guiseppe Fornasari, Daniel Gary, Angelo Vaccari
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Publication number: 20120149548Abstract: Process for the preparation of a catalytic specie consisting essentially of a metallic support, which is coated with a ceramic active phase layer, mainly compound of the general formula (I): [RhxNiyMglAlm(OH)2]z+(An?z/n) kH2O.Type: ApplicationFiled: December 13, 2011Publication date: June 14, 2012Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Daniel Gary, Pascal Del-Gallo, Francesco Basile, Angelo Vaccari, Giuseppe Fornasari, Valentina Rosetti, Erika Scavetta, Domenica Tonelli
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Patent number: 8105973Abstract: Chemical combination (C) between an active solid phase which is covalently bound to the surface of an inert solid phase, characterized in that said solid active phase essentially consists in a solid solution of a mixture of at least a magnesium oxide type phase compound and at least a magnesium silicate type phase compound in which Al, and Rh and/or Ni cations are soluted and characterized in that said inert solid phase is either a compound represented by the general formula (I): AlaNibRhcMgdSieOf??(I) wherein a, b, c, d, and e are integers which are greater than or equal to 0, f is an integer greater than 0, the sum a+b+c+d?0, and wherein (3a+2b+3c+2d+4e)/2=f, or a mixture of compounds represented by the said general formula (I), provided that at least one of the Si, Al, Mg, Rh or Ni elements, which is present in the solid active phase, is also present in the solid inert phase. Use of a catalyst in chemical reactions involving the conversion of hydrocarbonaceous feedstocks.Type: GrantFiled: November 18, 2010Date of Patent: January 31, 2012Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploiation des Procedes Georges ClaudeInventors: Francesco Basile, Pascal Del Gallo, Giuseppe Fornasari, Daniel Gary, Valentina Rosetti, Angelo Vaccari
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Patent number: 8092716Abstract: Process for the preparation of a catalytic specie consisting essentially of a metallic support, which is coated with a ceramic active phase layer, mainly compound of the general formula (I): [RhxNiyMglAlm(OH)2]z+(An?z/n)kH2O,??(I) wherein An? is mainly a silicate or a polysilicate anion; 0?x?0.3; 0?y?0.9; 0?l?0.9; 0?m?0.5; 0?k?10; x+y>0; 0.5?y+l?0.9; x+y+l+m=1; and z is the total electrical charge of the cationic element or a compound of the general formula (II): [AzA?1-z][B1-x-yNixRhy]O3-???(II) wherein A and A? are different and are selected from the Lanthanide or the Actinide families or from the group IIa of the Mendeleev's periodical table of elements; B is selected from the transition metal groups of columns IIIb, IVb, Vb, VIb, VIIb, Ib and IIb and group VIIIb of the Mendeleev's periodical table of elements; 0?x?0.7, 0?y?0.5, 0?x+y?0.Type: GrantFiled: January 10, 2007Date of Patent: January 10, 2012Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Daniel Gary, Pascal Del-Gallo, Francesco Basile, Angelo Vaccari, Giuseppe Fornasari, Valentina Rosetti, Erika Scavetta, Domenica Tonelli
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Publication number: 20110118112Abstract: Chemical combination (C) between an active solid phase which is covalently bound to the surface of an inert solid phase, characterized in that said solid active phase essentially consists in a solid solution of a mixture of at least a magnesium oxide type phase compound and at least a magnesium silicate type phase compound in which Al, and Rh and/or Ni cations are soluted and characterized in that said inert solid phase is either a compound represented by the general formula (I): AlaNibRhcMgdSieOf??(I) wherein a, b, c, d, and e are integers which are greater than or equal to 0, f is an integer greater than 0, the sum a+b+c+d?0, and wherein (3a+2b+3c+2d+4e)/2=f, or a mixture of compounds represented by the said general formula (I), provided that at least one of the Si, Al, Mg, Rh or Ni elements, which is present in the solid active phase, is also present in the solid inert phase. Use of a catalyst in chemical reactions involving the conversion of hydrocarbonaceous feedstocks.Type: ApplicationFiled: November 18, 2010Publication date: May 19, 2011Inventors: Francesco Basile, Pascal Del Gallo, Giuseppe Fornasari, Daniel Gary, Valentina Rosetti, Angelo Vaccari
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Publication number: 20110017953Abstract: Process for the preparation of a catalytic specie consisting essentially of a metallic support, which is coated with a ceramic active phase layer, mainly compound of the general formula (I): [RhxNiyMglAlm(OH)2]z+(An?z/n)kH2O,??(I) wherein An? is mainly a silicate or a polysilicate anion; 0?x?0.3; 0?y?0.9; 0?l?0.9; 0?m?0.5; 0?k?10; x+y>0; 0.5?y+l?0.9; x+y+l+m=1; and z is the total electrical charge of the cationic element or a compound of the general formula (II): [AzA?1-z][B1-x-yNixRhy]O3-???(II) wherein A and A? are different and are selected from the Lanthanide or the Actinide families or from the group IIa of the Mendeleev's periodical table of elements; B is selected from the transition metal groups of columns IIIb, IVb, Vb, VIb, VIIb, Ib and IIb and group VIIIb of the Mendeleev's periodical table of elements; 0?x?0.7, 0?y?0.5, 0?x+y?0.Type: ApplicationFiled: January 10, 2007Publication date: January 27, 2011Inventors: Daniel Gary, Pascal Del-Gallo, Francesco Basile, Angelo Vaccari, Giuseppe Fornasari, Valentina Rosetti, Erika Scavetta, Domenica Tonelli
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Patent number: 7329691Abstract: A composition and method for a Catalytic Partial Oxidation (CPO) of methane to synthesis gas. The catalyst allows the process to proceed at low residence time providing a long time thermal stability. The perovskite structure [AzA?1-z][B1-x-yNix Rhy] O3-? of the catalyst is obtained using mainly La, Sr, as A and A? cation sites (A, A?: actinide and/or lanthanide, elements and/or elements from Group I and II) and mainly Fe, Ni, as B cation sites (B: transition metal element and/or element from Group III to V).Type: GrantFiled: November 13, 2003Date of Patent: February 12, 2008Assignee: L'Air Liquid, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Francesco Basile, Giuseppe Fornasari, Angelo Vaccari, Pascal Del Gallo, Daniel Gary
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Publication number: 20060148640Abstract: The present invention relates to the use of a silicon-based porous catalytic system for oligomerizing light olefins, the porous silicon-based catalytic system having an average pore diameter of between about 1 nm and about 5 nm and an acidity level of between about 150 ?mol/g and about 650 ?mol/g, and prepared from at least one hydrolysable silicon-based compound, or other source of silicon, and at least one non-ionic surface active agent. The invention also relates to a process for oligomerizing light olefins using the silicon-based porous catalytic system, and to certain silicon-based porous catalytic systems.Type: ApplicationFiled: October 15, 2003Publication date: July 6, 2006Inventors: Jacques Roziere, Deborah Jones, Melanie Jacquin, Stefano Rossini, Roberto Catani, Angelo Vaccari, Maurizio Lenarda, Antonio Jimenez-Lopez, Jose-Manuel Trejo-Menayo, Enrique Rodriguez-Castellon, Pedro Mairelles-Torres
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Publication number: 20050181930Abstract: A process of preparation of silicon-based multifunctional catalytic systems synthesised together with one or more surface active agents is described. Also described is a multifunctional silicon-based porous catalytic system including at least one porous catalytic support structurally including silica and at least one other metal or non-metal oxide chosen from aluminium, zirconium, and boron. The catalytic support is synthesised together with one or more surface active agents, and at least one or more catalyst chosen from among metallic elements of groups 6-10 of the periodic table of the elements. The catalytic systems are useful in hydrogenation and/or decyclisation reactions of (poly)aromatic compounds, especially for improving the quality of diesel fuels and increasing their cetane number.Type: ApplicationFiled: January 31, 2003Publication date: August 18, 2005Inventors: Jacques Roziere, Deborah Jones, Melanie Jacquin, Antonio Jimenez-Lopez, Enrique Rodriguez-Castellon, Pedro Maireles-Torres, Jose-Manuel Trejo-Menayo, Angelo Vaccari, Maurizio Lenarda, Guido Busca
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Publication number: 20050156622Abstract: A semiconductor test device for acquiring a multiplexed clock signal from LSI output data and using the clock to test the LSI. The device includes a time interpolator 30 and registers 41a to 41n connected in series. The time interpolator has flip-flops 31a to 31n connected in parallel for inputting output data from an LSI 1 to be measured, a delay circuit 32 for successively inputting strobes delayed at a constant timing interval to the flip-flops 31 and outputting time-series level data, and an encoder 34 for inputting the time-series level data output from the flip-flops 31 and encoding it into position data indicating an edge timing. The registers 41a to 41n successively store position data from the encoder 34 and output them at a predetermined timing. The device further includes a digital filter for outputting the position data output from the registers 41 as a recovery clock.Type: ApplicationFiled: April 21, 2003Publication date: July 21, 2005Inventors: Jacques Roziere, Deborah Jones, Melanie Jacquin, Antonio Jimenez-Lopez, Enrique Rodriguez-Castellon, Pedro Maireles-Torres, Jose-Manuel Trejo-Menayo, Angelo Vaccari, Maurizio Lenarda, Guido Busca
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Publication number: 20040127351Abstract: The present patent deals with new catalysts for the Catalytic Partial Oxidation (CPO) of methane to synthesis gas (hydrogen and carbon monoxide), a gas mixture widely employed in industry. The discovered perovskite catalysts allows to carried out the process at low residence time obtaining a long time stability in the reaction conditions notwithstanding the high temperature reached in the reactor. The fundamental component of the catalyst is the perovskite structure [AzA′1-z][B1-x-yNixRhy]O3-&dgr; obtained using mainly La, Sr, as A and A′ cation sites (A, A′: actinide and/or lanthanide, elements and/or elements from Group I and II) and mainly Fe, Ni, as B cation sites (B: transition metal element and/or element from Group III to V). The active phases Ni and/or Rh are inserted in the perovskite structure during the preparation and are reduced in situ or before the catalytic tests.Type: ApplicationFiled: November 13, 2003Publication date: July 1, 2004Inventors: Francesco Basile, Giuseppe Fornasari, Angelo Vaccari, Pascal Del Gallo, Daniel Gary
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Patent number: 5698713Abstract: Disclosed is a process for the production of gamma-butyrolactone from maleic anhydride or succinic anhydride by hydrogenation in the presence of a catalyst composition comprising the mixed oxides of copper, zinc and zirconium.Type: GrantFiled: February 20, 1997Date of Patent: December 16, 1997Assignee: Lonza S.P.A.Inventors: Rosa Lancia, Angelo Vaccari, Carlo Fumagalli, Erich Armbruster