Abstract: Present invention relates to sp2 carbon nanogranules with iron incorporated in it from heavy petroleum residue of a refinery and thereby utilizing the materials for improved synthesis of light olefins (C2-C4) from syngas in a single step Fischer Tropsch synthesis to lower olefins, (FTO). The efficient iron incorporated carbon nanogranules derived from low value heavy petroleum residue are very attractive as catalytic system for direct synthesis of light olefin (C2-C4) from syngas at CO conversion up to 30%.

Abstract: Present invention relates to sp2 carbon nanogranules with iron incorporated in it from heavy petroleum residue of a refinery and thereby utilizing the materials for improved synthesis of light olefins (C2-C4) from syngas in a single step Fischer Tropsch synthesis to lower olefins, (FTO). The efficient iron incorporated carbon nanogranules derived from low value heavy petroleum residue are very attractive as catalytic system for direct synthesis of light olefin (C2-C4) from syngas at CO conversion up to 30%.

Abstract: Disclosed are sp2 carbon nanogranules with iron incorporated from heavy petroleum residue of a refinery. The nanogranules may be used for improved synthesis of light olefins (C2-C4) from syngas in a single step Fischer Tropsch synthesis to lower olefins, (FTO). The efficient iron incorporated carbon nanogranules derived from low value heavy petroleum residue are very attractive as a catalytic system for direct synthesis of light olefin (C2-C4) from syngas at CO conversion up to 30%.

Abstract: The present invention provides a Ni—Zr oxide catalyst and a process for the preparation of the catalyst. The invention further provides use of the catalyst for the production of synthesis gas (a mixture of CO and H2) by Tri-reforming of methane. The process provides a direct single step selective vapor phase partial oxidation of methane to synthesis gas over Ni—ZrO2 catalyst between temperature range of 600° C. to 800° C. at atmospheric pressure. The process provides a methane conversion of 1-99% with H2 to CO mole ratio of 1.6 to 2.2.

Abstract: The present invention provides a catalyst and a process for the selective oxidation of carbon monoxide (CO) to produce carbon dioxide gas (CO2). The process provides a process which selectively oxidizes CO to CO2 in presence of excess hydrogen. The process provides a selective oxidation of CO to CO2 gas over Cu/CeO2 catalyst between temperature range 40° C. to 90° C. at atmospheric pressure in presence of excess H2, H2O and CO2. The process provides a CO conversion up to 100% without deactivation till 100 h.

Abstract: Disclosed are sp2 carbon nanogranules with iron incorporated from heavy petroleum residue of a refinery. The nanogranules may be used for improved synthesis of light olefins (C2-C4) from syngas in a single step Fischer Tropsch synthesis to lower olefins, (FTO). The efficient iron incorporated carbon nanogranules derived from low value heavy petroleum residue are very attractive as a catalytic system for direct synthesis of light olefin (C2-C4) from syngas at CO conversion up to 30%.

Abstract: The present invention provides a process and catalyst for the production of synthesis gas (a mixture of CO and H2) by reforming of methane with carbon dioxide. The process provides a direct single step selective vapor phase dry reforming of methane with carbon dioxide to produce synthesis gas over Ni—MgO—ZnO catalyst between temperature range of 600° C. to 800° C. at 1 atmospheric pressure. The process provides a methane conversion of 5-95% with H2 to CO mole ratio of 0.83-1.2.

Abstract: The present invention provides a process and catalyst for the autothermal and dry reforming of methane to produce syngas. The process provides a direct single step gas phase reforming of methane or natural gas to syngas over Ni—Pt supported nanocrystalline ZrO2. The process provides methane conversion of 54-99% with H2/CO ratio of 1.14 to 1.42 (mol %) in the temperature range of 250 to 750 800° C. at atmospheric pressure.

Abstract: The present invention provides a catalyst and a process for the selective oxidation of carbon monoxide (CO) to produce carbon dioxide gas (CO2). The process provides a process which selectively oxidizes CO to CO2 in presence of excess hydrogen. The process provides a selective oxidation of CO to CO2 gas over Cu/CeO2 catalyst between temperature range 40° C. to 90° C. at atmospheric pressure in presence of excess H2, H2O and CO2. The process provides a CO conversion up to 100% without deactivation till 100 h.

Abstract: The present invention provides a Ni nano-cluster supported on MgO—CeO2—ZrO2 catalyst and processes the production of the catalyst. Further, the present invention discloses use of Ni nano-cluster supported on MgO—CeO2—ZrO2 catalyst for the synthesis gas (a mixture of CO and H2) by tri-reforming of methane. The process provides a direct single step selective vapor phase tri-reforming of methane to synthesis gas over NiO—MgO—CeO2—ZrO2 oxide catalyst between temperature range of 600° C. to 800° C. at atmospheric pressure. The process provides a methane conversion of 1-99% with H2 to CO mole ratio of 1.6 to 2.3.

Abstract: The present invention provides a process and catalyst system for the production of synthesis gas (a mixture of CO and H2) from greenhouse gases like methane and carbon di oxide. The process provide a single step selective reforming of methane with carbon dioxide to produce synthesis gas over Ce—Ni—MgAl2O4 catalyst prepared by using combination of two methods evaporation induced self-assembly and organic matrix combustion method. These suitably combined methods generate a unique catalyst system with very fine Ni nano clusters evenly dispersed in high surface area support. The process provides both Methane and carbon di oxide conversion more than 90% without any noticeable deactivation till 100 hours between temperature range of 500-800° C. at atmospheric pressure.

Abstract: The present invention provides a process and catalyst for the autothermal and dry reforming of methane to produce syngas. The process provides a direct single step gas phase reforming of methane or natural gas to syngas over Ni—Pt supported nanocrystalline ZrO2. The process provides methane conversion of 54-99% with H2/CO ratio of 1.14 to 1.42 (mol %) in the temperature range of 250 to 750 800° C. at atmospheric pressure.

Abstract: The present invention provides an improved process for the preparation of phosphorous containing mesoporous alumina catalyst for selective dehydration of methanol to dimethyl ether. The process provides a single step selective vapor phase dehydration of methanol to produce dimethyl ether over phosphorous containing mesoporous alumina (P/Al2O3) catalyst at a temperature in the range of 150-350° C. The process provides methanol conversion of 45-100% with a selectivity of the DME up to 100%.

Abstract: The present invention provides a Ni nano-cluster supported on MgO—CeO2—ZrO2 catalyst and processes the production of the catalyst. Further, the present invention discloses use of Ni nano-cluster supported on MgO—CeO2—ZrO2 catalyst for the synthesis gas (a mixture of CO and H2) by tri-reforming of methane. The process provides a direct single step selective vapor phase tri-reforming of methane to synthesis gas over NiO—MgO—CeO2—ZrO2 oxide catalyst between temperature range of 600° C. to 800° C. at atmospheric pressure. The process provides a methane conversion of 1-99% with H2 to CO mole ratio of 1.6 to 2.3.

Abstract: The present invention provides a Ni—Zr oxide catalyst and a process for the preparation of the catalyst. The invention further provides use of the catalyst for the production of synthesis gas (a mixture of CO and H2) by Tri-reforming of methane. The process provides a direct single step selective vapor phase partial oxidation of methane to synthesis gas over Ni—ZrO2 catalyst between temperature range of 600° C. to 800° C. at atmospheric pressure. The process provides a methane conversion of 1-99% with H2 to CO mole ratio of 1.6 to 2.2.

Abstract: The present invention provides a process and catalyst for the production of synthesis gas (a mixture of CO and H2) by reforming of methane with carbon dioxide. The process provides a direct single step selective vapor phase dry reforming of methane with carbon dioxide to produce synthesis gas over Ni—MgO—ZnO catalyst between temperature range of 600° C. to 800° C. at 1 atmospheric pressure. The process provides a methane conversion of 5-95% with H2 to CO mole ratio of 0.83-1.2.

Abstract: The present invention provides a process and catalyst system for the production of synthesis gas (a mixture of CO and H2) from greenhouse gases like methane and carbon di oxide. The process provide a single step selective reforming of methane with carbon dioxide to produce synthesis gas over Ce—Ni—MgAl2O4 catalyst prepared by using combination of two methods evaporation induced self-assembly and organic matrix combustion method. These suitably combined methods generate a unique catalyst system with very fine Ni nano clusters evenly dispersed in high surface area support. The process provides both Methane and carbon di oxide conversion more than 90% without any noticeable deactivation till 100 hours between temperature range of 500-800° C. at atmospheric pressure.

Abstract: The present invention provides an improved process for the preparation of phosphorous containing mesoporous alumina catalyst for selective dehydration of methanol to dimethyl ether. The process provides a single step selective vapour phase dehydration of methanol to produce dimethyl ether over phosphorous containing mesoporous alumina (P/Al2O3) catalyst at a temperature in the range of 150-350° C. The process provides methanol conversion of 45-100% with a selectivity of the DME up to 100%.