Abstract: A product may include a storage vessel that may define a first port opening into the storage vessel, and that may define a second port opening into the storage vessel. A first fill conduit may be connected to the storage vessel at the first port. A second fill conduit may be connected to the storage vessel at the second port. A control mechanism may be connected with the first and second fill conduits. A supply conduit may be connected to the control mechanism. The control mechanism may provide a flow path from the supply conduit to at least one of the first or second fill conduits to fill the storage vessel.

Abstract: Systems and methods of providing a self-healing UV-protective polymer coating include a polymer matrix formed by initiating polymerization of a UV-absorbing-matrix precursor and a UV initiator and a self-healing portion disposed within the polymer matrix. The polymer matrix includes a plurality of active sites therein. The self-healing portion includes a self-healing precursor that is flowable and a self-healing initiator. The self-healing initiator is configured to polymerize the self-healing precursor using a cationic ring opening process.

Abstract: Systems and methods of providing an electrolyte membrane for metal batteries are described. According to aspects of the disclosure, a battery cell includes an anode, a cathode, and an electrolyte membrane therebetween. The electrolyte membrane is formed from a mixture including a matrix precursor portion and an electrolyte portion. In some aspects, the membrane is polymerized after being applied to the battery component.

Abstract: Systems and methods of providing an electrolyte membrane for metal batteries are described. According to aspects of the disclosure, a method includes preparing a mixture including an electrolyte portion and a matrix precursor portion, forming an electrolyte membrane by initiating polymerization of the gel-forming precursor and the gel-forming initiator to thereby form a polymer matrix, and disposing the electrolyte membrane between an anode and a cathode. The matrix precursor portion includes a gel-forming precursor and a gel-forming initiator. The electrolyte portion is disposed substantially throughout the polymer matrix.

Abstract: A hybrid separator for an electrochemical cell is provided, along with methods of making the hybrid separator. The hybrid separator includes a first metal-organic framework comprising copper and having a plurality of first pores and a second distinct metal-organic framework comprising indium or zinc and having a plurality of second pores. The hybrid separator is capable of adsorbing one or more lithium salts in at least one of the plurality of first pores or the plurality of second pores so as to be ionically conductive. The hybrid separator may have a conductivity greater than or equal to about 0.1 mS/cm to less than or equal to about 1 mS/cm and is substantially free of any polymeric binder.

Abstract: Systems and methods of providing self-healing gel-type electrolyte composites for metal batteries are disclosed. According to aspects of the disclosure, a method includes preparing a ternary mixture including an electrolyte portion, a matrix precursor portion, and a self-healing portion, forming a self-healing gel-electrolyte membrane by initiating polymerization of the gel-forming precursor and the gel-forming initiator to thereby form a polymer matrix, and disposing the self-healing gel-electrolyte membrane between an anode and a cathode. The self-healing portion includes a self-healing precursor that is flowable and a self-healing initiator. The matrix precursor portion includes a gel-forming precursor and a gel-forming initiator. The electrolyte portion and the self-healing portion are disposed substantially throughout the polymer matrix and the polymer matrix includes a plurality of gel-forming active sites.

Abstract: A lithium-based battery separator includes a porous polymer membrane having opposed surfaces. A porous carbon coating is formed on one of the opposed surfaces of the porous polymer membrane. Polycations are incorporated in the porous carbon coating, in the porous polymer membrane, or in both the porous carbon coating and the porous polymer membrane.

Abstract: In an example of a method, a halogenide-hydrocarbon, an aprotic hydrocarbon solvent, and a reductant are combined to initiate a reaction that forms intermediate particles having a microporous framework. The intermediate particles are subjected to a heat treatment at a heat treatment temperature ranging from about 300° C. to less than 1500° C. for a heat treatment time period ranging from about 20 minutes to about 10 hours to form a precursor to microporous carbon.

Abstract: A thermal management system for a natural gas tank includes a container, and a cooling mechanism operatively positioned to selectively cool the container. A method for minimizing a loss of natural gas storage during refueling is also disclosed herein. In an example of the method, a cooling mechanism, which is operatively positioned to selectively cool a container of a natural gas storage tank, is initiated prior to a refueling event. This cools the container to a predetermined temperature.

Abstract: A bi-fuel vehicle has an Internal Combustion Engine (ICE) to provide motive power to the vehicle by combustion of a liquid fuel and gas-phase fuel. The vehicle has a dual fuel tank including a liquid fuel tank to receive liquid fuel, contain the liquid fuel, and supply the liquid fuel for combustion in the ICE. The vehicle has a pressurizable gas-phase fuel tank defined by a wall. A gas-phase fuel is permeable through the wall. The pressurizable gas-phase fuel tank is to receive the gas-phase fuel, contain the gas-phase fuel, and supply the gas-phase fuel for combustion in the ICE. A shell envelops the pressurizable gas-phase fuel tank and defines an interior space of the liquid fuel tank. The wall is in fluid communication with the interior space. The interior space is to receive the permeated gas-phase fuel.

Abstract: In certain aspects, electrolytic deposition and electroless displacement deposition methods are provided to form bimetallic structures that may be used as a bipolar current collector in a battery or a substrate for forming graphene sheets. In other aspects, bipolar current collectors for lithium-ion based electrochemical cells are provided. The bimetallic current collector may have an aluminum-containing surface and a continuous copper coating. In other aspects, a flexible substrate may be coated with one or more conductive materials, like nickel, copper, graphene, aluminum, alloys, and combinations thereof. The flexible substrate is folded to form a bipolar current collector. New stack assemblies for lithium-ion based batteries incorporating such bipolar current collectors are also provided that can have cells with a tab-free and/or weld-free design.

Abstract: A product may include a storage vessel that may define a first port opening into the storage vessel, and that may define a second port opening into the storage vessel. A first fill conduit may be connected to the storage vessel at the first port. A second fill conduit may be connected to the storage vessel at the second port. A control mechanism may be connected with the first and second fill conduits. A supply conduit may be connected to the control mechanism. The control mechanism may provide a flow path from the supply conduit to at least one of the first or second fill conduits to fill the storage vessel.

Abstract: A vehicle includes a vehicle platform and a natural gas fueled engine attached to the vehicle platform. The engine provides tractive power to at least one drive wheel. The vehicle includes an enclosure, attachable to the vehicle platform, to contain an array of natural gas storage vessels. The array of natural gas storage vessels is disposed completely within the enclosure. Each storage vessel of the array of natural gas storage vessels is in fluid communication with a single outlet port for selectively extracting the natural gas from the array of natural gas storage vessels. Each storage vessel of the array of natural gas storage vessels is in fluid communication with a single natural gas fill port.

Abstract: A vehicle includes a vehicle platform and a natural gas fueled engine attached to the vehicle platform. The engine provides tractive power to at least one drive wheel. The vehicle includes an enclosure, attachable to the vehicle platform, to contain an array of natural gas storage vessels. The array of natural gas storage vessels is disposed completely within the enclosure. Each storage vessel of the array of natural gas storage vessels is in fluid communication with a single outlet port for selectively extracting the natural gas from the array of natural gas storage vessels. Each storage vessel of the array of natural gas storage vessels is in fluid communication with a single natural gas fill port.

Abstract: A natural gas fueled vehicle, includes a natural gas fueled Internal Combustion Engine (ICE) to provide motive power to the vehicle. A pressurizable tank is disposed on the vehicle to contain a natural gas. A natural gas adsorbent is disposed in the tank. A fuel supply tube is to convey the natural gas to the ICE. A scroll compressor is on the vehicle to receive the natural gas from the tank and to deliver a first mixture of compressed natural gas and an oil to a gas and oil separator. The gas and oil separator is to receive the first mixture of the compressed natural gas and the oil from the scroll compressor and to separate the oil from the compressed natural gas and to deliver the compressed natural gas to the fuel supply tube substantially free from the oil.

Abstract: A composite pressure vessel includes a liner to contain a pressurized fluid and a composite layer formed on at least a portion of an exterior surface of liner. The composite layer includes a third generation advanced high strength steel filament reinforcement embedded in a polymer matrix.

Abstract: A bi-fuel vehicle includes an Internal Combustion Engine (ICE) to power the vehicle by combustion of liquid and gas-phase fuels. The vehicle has a dual fuel tank including a pressurizable gas-phase fuel compartment defined by a wall that is permeable by a gas-phase fuel. The gas-phase fuel compartment receives and contains the gas-phase fuel, and supplies the gas-phase fuel for combustion in the ICE. The dual fuel tank includes a liquid fuel compartment to receive and contain liquid fuel, and supply the liquid fuel for combustion in the ICE. A shell envelops the gas-phase fuel compartment, and defines the liquid fuel compartment. An interstitial space between the wall and the shell is in one-way fluid communication with the liquid fuel compartment. The interstitial space receives the permeated gas-phase fuel and channels the permeated gas-phase fuel to the liquid fuel compartment. The dual fuel tank has a vapor recovery system.

Abstract: An adsorption storage tank for a natural gas includes a pressurizable tank disposed on a vehicle to contain the natural gas. A natural gas adsorbent is disposed in the tank. The natural gas is a mixture of constituents having a constituent statistical distribution of molecule lengths and kinetic diameters. The adsorbent has a pore size statistical distribution of pore sizes to adsorb and desorb the mixture of constituents.

Abstract: A method of storing and using natural gas (NG) in a vehicle includes selecting a vehicle having an NG tank for fueling an engine of the vehicle. The tank service pressure rating is 3600 psi (pounds per square inch) and an NG adsorbent is in the tank. A first quantity of NG is transferred into the tank from a first source having a first source pressure less than 725 psi. The adsorbent adsorbs a portion of the NG. After transferring the first quantity of NG, the engine is operated until NG is desorbed and consumed by the engine. NG is transferred into the tank from a second source to fill the tank to a second tank pressure of about 3600 psi. The adsorbent adsorbs some of the NG. After transferring the second quantity of the NG, the engine is operated until NG is desorbed and consumed by the engine.

Abstract: A method of operating a vehicle powertrain includes determining a selected powertrain operational mode. A demand fraction is determined. An internal combustion engine (ICE) is to output a maximum power when a gaseous fuel is conveyed to an injector of the ICE at a source pressure greater than a cutoff pressure. The source pressure in a container in fluid connection with the injector is determined. The gaseous fuel is received at the source pressure by the injector to inject the gaseous fuel into the ICE for combustion in response to the source pressure, demand fraction, or selected powertrain operation mode meeting a first set of criteria. The injector is prevented from injecting the gaseous fuel into the ICE and the powertrain is driven from an alternative power source in response to the source pressure, demand fraction, or selected powertrain operation mode meeting a second set of criteria.