Patents by Inventor Antero Ahvenainen

Antero Ahvenainen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5684097
    Abstract: A process for producing polyethylene compositions in the presence of a catalytic system of ethylene polymerizing catalyst and cocatalyst in a multistage continuous reaction sequence consisting of successive liquid phase and gas phase polymerizations is disclosed. In the first step of the process, ethylene and optionally hydrogen and comonomer are polymerized in a first loop reactor in a low boiling hydrocarbon medium in the presence of ethylene polymerizing catalyst and cocatalyst. The reaction mixture is then removed and then transferred to a second loop reactor where polymerization is continued by addiing ethylene, hydrogen and optionally inert hydrocarbon, comonomers and cocatalysts. Thereafter, the reaction mixture is removed from the second loop reactor along with an essential part of the reaction medium and transferred to a gas phase reactor where polymerizing is continued in the presence of added ethylene and optionally hydrogen, comonomers and cocatalysts to form an end product.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 4, 1997
    Assignee: Borealis Polymers OY
    Inventors: Ari Palmroos, Ali Harlin, Antero Ahvenainen, Jouni Takakarhu, Aimo Sahila
  • Patent number: 5391654
    Abstract: The invention relates to a method for homo- or copolymerizing ethene in the presence of a Ziegler-Natta or other catalyst and a possible comonomer and hydrogen for preparing a homo- or copolymer of ethene in particle form in propane. In accordance with the invention, the polymerization is performed in a loop reactor under such supercritical conditions where the temperature is higher than the critical temperature of the mixture formed by ethene, propane and a possible hydrogen and a comonomer, but lower than the melting temperature of the ethene polymer forming in the polymerization, and the pressure is higher than the critical pressure of said mixture.
    Type: Grant
    Filed: May 25, 1993
    Date of Patent: February 21, 1995
    Assignee: Neste OY
    Inventors: Antero Ahvenainen, Kari Sarantila, Henrik Andtsjo
  • Patent number: 5326835
    Abstract: The invention concerns a multi-stage process for producing polyethylene having a bimodal and/or broad molecular weight distribution in the presence of an ethylene polymerizing catalyst system in a multistep reaction sequence, in which the first reaction step is a liquid phase polymerization step and the second reaction step is formed by one or more gas-phase polymerization steps. According to the process of the invention in the first reaction step ethylene is polymerized in a loop reactor (10) in an inert low-boiling hydrocarbon medium the residence time being at least 10 minutes, reaction mixture is discharged from the loop reactor (10) and at least a substantial part of the inert hydrocarbon mixture is separated and the polymer is transferred into one or more gas-phase reactors (30), where the polymerization is completed in the presence of ethylene and optionally hydrogen and a comonomer.
    Type: Grant
    Filed: August 20, 1992
    Date of Patent: July 5, 1994
    Assignee: Neste OY
    Inventors: Antero Ahvenainen, Kari Sarantila, Henrik Andtsjo, Jouni Takakarhu, Ari Palmroos
  • Patent number: 5179180
    Abstract: The polymerization of certain alpha-olefins in a gas phase involves the problem of agglomeration of the product into particles disadvantageous from the viewpoint of its handling. In the present invention this problem has been solved by means of a new type of process for the homo- or copolymerization of alpha-olefins. In the process the catalyst system is pretreated by contacting and reacting a transition-metal compound which is solid or on a solid carrier with an organoaluminum compound, and possibly an electron donor, in a liquid medium, and by drying the thus formed reaction product to produce a solid catalyst system. The thus pretreated solid and active catalyst system is then fed together with an alpha-olefin in the gaseous state into a gas-phase reactor, and polymerization is carried out by contacting them with each other.
    Type: Grant
    Filed: October 30, 1989
    Date of Patent: January 12, 1993
    Assignee: Berggren OY AB
    Inventors: Antero Ahvenainen, Hannu Salminen, Jari Tervonen, Tarja Soderberg