Patents by Inventor Anthony Nicholas Speca
Anthony Nicholas Speca has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7494626Abstract: A polymerization process is provided. For example, a polymerization process is described, including providing a catalyst slurry having a metallocene catalyst and a first oil, providing a transport medium including a second oil and combining the transport medium and the catalyst slurry to form a catalyst mixture. The process may further include introducing the catalyst mixture to a polymerization reactor and contacting olefin monomers with the catalyst mixture to polymerize the olefin monomers and form polyolefins.Type: GrantFiled: July 18, 2006Date of Patent: February 24, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Lawrence Carl Smith, James Charles Vizzini, Ted Alexander Powell, Terry John Burkhardt, Anthony Nicholas Speca, Shiaw Tzuu Ju
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Patent number: 7232868Abstract: A polymerization process is provided. For example, a polymerization process is described, including providing a catalyst slurry having a metallocene catalyst and a first oil, providing a transport medium including a second oil and combining the transport medium and the catalyst slurry to form a catalyst mixture. The process may further include introducing the catalyst mixture to a polymerization reactor and contacting olefin monomers with the catalyst mixture to polymerize the olefin monomers and form polyolefins.Type: GrantFiled: September 22, 2003Date of Patent: June 19, 2007Assignee: Exxon/Mobil Chemical Patents Inc.Inventors: Lawrence Carl Smith, James Charles Vizzini, Ted Alexander Powell, Terry John Burkhardt, Anthony Nicholas Speca, Shiaw Tzuu Ju
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Patent number: 7026040Abstract: This invention relates generally to films made from crystalline polypropylene polymers. Specifically, this invention relates to films comprising crystalline polypropylene polymer compositions containing both propylene homopolymers and propylene copolymers. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymers and copolymers using propylene with a small amount of comonomer, preferably ethylene. The resulting polymers are excellent for use in the production of biaxially oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional polypropylene polymers.Type: GrantFiled: August 31, 2004Date of Patent: April 11, 2006Assignee: Exxon Mobil Chemical Patents Inc.Inventors: Aspy Keki Mehta, Michael Chia-Chao Chen, Chon-Yie Lin, James John Mcalpin, Anthony Nicholas Speca, Kelly Tormaschy
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Patent number: 6806316Abstract: This invention relates generally to crystalline polypropylene polymers and methods for their production. Specifically, this invention relates to crystalline polypropylene polymer compositions comprising both propylene homopolymers and propylene copolymers. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymers and copolymers using propylene with a small amount of comonomer, preferably ethylene. The resulting polymers are excellent for use in the production of biaxially oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional polypropylene polymers.Type: GrantFiled: November 25, 2002Date of Patent: October 19, 2004Assignee: ExxonMobil Chemical Patents Inc.Inventors: Aspy Keki Mehta, Michael Chia-Chao Chen, Chon-Yie Lin, James John McAlpin, Anthony Nicholas Speca, Kelly Tormaschy
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Publication number: 20040097667Abstract: A polymerization process is provided. For example, a polymerization process is described, including providing a catalyst slurry having a metallocene catalyst and a first oil, providing a transport medium including a second oil and combining the transport medium and the catalyst slurry to form a catalyst mixture. The process may further include introducing the catalyst mixture to a polymerization reactor and contacting olefin monomers with the catalyst mixture to polymerize the olefin monomers and form polyolefins.Type: ApplicationFiled: September 22, 2003Publication date: May 20, 2004Inventors: Lawrence Carl Smith, James Charles Vizzini, Ted Alexander Powell, Terry John Burkhardt, Anthony Nicholas Speca, Shiaw Tzuu Ju
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Publication number: 20030153689Abstract: This invention relates generally to crystalline polypropylene polymers and methods for their production. Specifically, this invention relates to crystalline polypropylene polymer compositions comprising both propylene homopolymers and propylene copolymers. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymers and copolymers using propylene with a small amount of comonomer, preferably ethylene. The resulting polymers are excellent for use in the production of biaxially oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional polypropylene polymers.Type: ApplicationFiled: November 25, 2002Publication date: August 14, 2003Inventors: Aspy Keki Mehta, Michael Chia-Chao Chen, Chon-Yie Lin, James John McAlpin, Anthony Nicholas Speca, Kelly Tormaschy
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Patent number: 6140432Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported metallocene catalyst which when utilized in a polymerization process substantially reduces reactor fouling and sheeting in a gas or slurry polymerization process.Type: GrantFiled: July 13, 1995Date of Patent: October 31, 2000Assignee: Exxon Chemical Patents Inc.Inventors: Agapios Kyriacos Agapiou, Chi-I Kuo, Michael Elroy Muhle, Anthony Nicholas Speca
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Patent number: 6124230Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported bulky ligand transition metal catalyst which when utilized in a polymerization process substantially reduces the reactor fouling and sheeting in a gas, slurry or liquid pool polymerization process.Type: GrantFiled: July 13, 1995Date of Patent: September 26, 2000Assignee: Exxon Chemical Patents, Inc.Inventors: Anthony Nicholas Speca, Jeffrey Lawrence Brinen
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Patent number: 6117955Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported metallocene catalyst which when utilized in a polymerization process substantially reduces reactor fouling and sheeting in a gas or slurry polymerization process.Type: GrantFiled: July 30, 1996Date of Patent: September 12, 2000Assignee: Exxon Chemical Patents IncInventors: Agapios Kyriacos Agapiou, Chi-I Kuo, Michael Elroy Muhle, Anthony Nicholas Speca
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Patent number: 6114479Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported bulky ligand transition metal catalyst which when utilized in a polymerication process substantially reduces the reactor fouling and sheeting in a gas, slurry or liquid pool polymerization process.Type: GrantFiled: July 30, 1996Date of Patent: September 5, 2000Assignee: Exxon Chemical Patents Inc.Inventors: Anthony Nicholas Speca, Jeffrey Lawrence Brinen
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Patent number: 6087291Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst system of the invention provides for a metallocene catalyst and alumoxane activator supported on a porous support using a total volume of catalyst solution that is less than that of which a slurry is formed. The metallocene and alumoxane aer mixed in solution, then the solution is added to a porous support in a volume between the total pore volume of the support and the volume at which a slurry forms. The solvent is then removed, leaving an activated supported metallocene.Type: GrantFiled: October 24, 1997Date of Patent: July 11, 2000Assignee: Exxon Chemical Patents, Inc.Inventors: Anthony Nicholas Speca, Jeffrey Lawrence Brinen, George Alan Vaughan, Patrick Brant, Terry John Burkhardt
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Patent number: 6013594Abstract: This invention relates to catalyst supports made by spray drying an emulsion polymerized latex and the novel supported catalysts utilizing these supports. This invention further relates to a method for forming supported catalysts by spray drying a latex of microparticles containing catalyst or catalyst components. The polymizerable monomers used in the latex are e.g. styrenes, vinyl benzenes, vinyl cyclohexane and vinyl cyclohexene and can form homo- or copolymers which may be crosslinked. The catalysts supported include metallocenes as well as Ziegler-Natta catalysts. Processes of polymerizing olefins using such catalysts are also described.Type: GrantFiled: April 29, 1998Date of Patent: January 11, 2000Assignee: Exxon Chemical Patents, Inc.Inventors: Henry Wu-Hsian Yang, Anthony Nicholas Speca
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Patent number: 5863853Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst system of the invention provides for a supported bulky ligand transition metal catalyst system which when utilized in a polymerization process substantially reduces the reactor fouling and sheeting particularly in a gas phase polymerization process.Type: GrantFiled: February 24, 1997Date of Patent: January 26, 1999Assignee: Exxon Chemical Patents, Inc.Inventors: George Alan Vaughan, Anthony Nicholas Speca, Patrick Brant, Jo Ann Marie Canich
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Patent number: 5721184Abstract: Catalyst systems and methods for supporting catalysts and their components, particularly metallocene catalyst components, are provided. The method involves techniques for evenly distributing a small volume of catalyst component over and among a porous support material. Such even distribution is thought to result in reduced fouling.Type: GrantFiled: August 27, 1996Date of Patent: February 24, 1998Assignees: Hoechst, Exxon Chemical Patents Inc.Inventors: Jeffrey Lawrence Brinen, Anthony Nicholas Speca, Kelly Tormaschy, Kathryn Ann Russell
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Patent number: 5688734Abstract: The invention relates to a supported, prepolymerized metallocene catalyst system as well as its production and use in olefin polymerization. The method for producing the prepolymerized catalyst system involves prepolymerizing a metallocene catalyst system containing a volume of solution that is the equivalent of or less than the total pore volume of the supported catalyst system.Type: GrantFiled: September 19, 1996Date of Patent: November 18, 1997Assignees: Exxon Chemical Patents Inc., Hoechst AktiengesellschaftInventors: Anthony Nicholas Speca, Kelly Tormaschy
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Patent number: 5665665Abstract: Catalyst systems and methods for supporting catalysts and their components, particularly metallocene catalyst components, are provided. The method involves teqhniques for evenly distributing a small volume of catalyst component over and among a porous support material. Such even distribution is thought to result in reduced fouling.Type: GrantFiled: November 17, 1995Date of Patent: September 9, 1997Assignees: Exxon Chemical Patents, Inc., HoechstInventors: Jeffrey Lawrence Brinen, Anthony Nicholas Speca, Kelly Tormaschy, Kathryn Ann Russell