Abstract: The present invention provides a photolatent Ti-chelate catalyst formulation, comprising (i) at least one compound of the formula (I) wherein R1 is C1-C20alkyl or C2-C20alkyl which is interrupted by one or more non-consecutive O-atoms; Y is formula (II) or optionally substituted phenyl; Y1 is formula (III) or optionally substituted phenyl; Y2 is formula (IV) or optionally substituted phenyl; Y3 is formula (V) or optionally substituted phenyl; R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are hydrogen, halogen, optionally substituted C1-C20alkyl, or R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are optionally substituted C6-C14aryl, provided that only one of R2, R3, R4 is hydrogen and only one of R5, R6, R7 is hydrogen and only one of R8, R9, R10 is hydrogen and only one of R11, R12, R13 is hydrogen; and (ii) at least one chelate ligand compound of the formula IIa, IIb or IIc, wherein Y? is formula (VI) or formula (VII); Y?1 is formula (VI

Abstract: Compounds of the formula (I) (I), wherein X is O, S, a direct bond or CR16R17; Y is O or S; R1, R2, R3, R4, R5, R6, R7 and R8 for example are hydrogen, halogen, C1-C4alkyl, or a group of formula (II) or (III) (II) (III) provided that either (i) one of R1, R2, R3, R4, R5, R6, R7 or R8 is a group of formula (II) or (III); or (ii) one of R1, R2, R3 or R4 is a group of formula (II) or (III) and one of R5, R6, R7 or R8 is a group of formula (II) or (III); R9 and R10 independently of each other are C1-C4alkyl or together with the C atom to which they are attached form a 5-membered, 6-membered or 7-membered carbocyclic ring; R11 is hydrogen, C1-C4alkyl, C5-C7cycloalkyl, 2-tetrahydropyranyl or Si(C1-C4alkyl)3; R12 and R13 for example are C1-C4alkyl, C2-C12alkenyl, phenyl-C1-C4alkyl, phenyl-C1-C4alkyl which is substituted by C1-C4alkyl, R14 and R15 independently of each other are C1-C4alkyl, C5-C7cycloalkyl, or together with the N atom to which they are attached form a 5-membered, 6-membered or 7-membered ring, which

Abstract: A titanium-oxo-chelate catalyst formulation, comprising: (i) at least one compound of the formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11 and R12 independently of each other are for example hydrogen, halogen, C1-C20alkyl, C6-C14aryl which is unsubstituted or substituted; or R1, R2 and R3 and/or R4, R5 and R6 and/or R7, R8 and R9 and/or R10, R11 and R12 together with the C-atom to which they are attached each form a C6-C14aryl group which is unsubstituted or substituted; or R1 and R2 and/or R4 and R5 and/or R7 and R8 and/or R10 and R11 together with the C-atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate ligand compound of the formula (IIa), (IIb) or (IIc), wherein R1, R2, R3, R4, R5 and R6 are defined as above for formula (I), is suitable as a photolatent catalyst formulation for polymerizing compounds, which are capable to crosslink in the presence of a Lewis acid.

Abstract: A titanium-oxo-chelate catalyst formulation, comprising: (i) at least one compound of the formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11 and R12 independently of each other are for example hydrogen, halogen, C1-C20alkyl, C6-C14aryl which is unsubstituted or substituted; or R1, R2 and R3 and/or R4, R5 and R6 and/or R7, R8 and R9 and/or R10, R11 and R12 together with the C-atom to which they are attached each form a C6-C14aryl group which is unsubstituted or substituted; or R1 and R2 and/or R4 and R5 and/or R7 and R8 and/or R10 and R11 together with the C-atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate ligand compound of the formula (IIa), (IIb) or (IIc), wherein R1, R2, R3, R4, R5 and R6 are defined as above for formula (I), is suitable as photolatent catalyst formulation for polymerizing compounds, which are capable to crosslink in the presence of a Lewis acid.

Abstract: Compounds of the formula (I) (I), wherein X is O, S, a direct bond or CR16R17; Y is O or S; R1, R2, R3, R4, R5, R6, R7 and R8 for example are hydrogen, halogen, C1-C4alkyl, or a group of formula (II) or (III) (II) (III) provided that either (i) one of R1, R2, R3, R4, R5, R6, R7 or R8 is a group of formula (II) or (III); or (ii) one of R1, R2, R3 Or R4 is a group of formula (II) or (III) and one of R5, R6, R7 or R8 is a group of formula (II) or (III); R9 and R10 independently of each other are C1-C4alkyl or together with the C atom to which they are attached form a 5-membered, 6-membered or 7-membered carbocyclic ring; R11 is hydrogen, C1-C4alkyl, C5-C7cycloalkyl, 2-tetrahydropyranyl or Si(C1-C4alkyl)3; R12 and R13 for example are C1-C4alkyl, C2-C2alkenyl, phenyl-C1-C4alkyl, phenyl-C1-C4alkyl which is substituted by C1-C4alkyl, R14 and R15 independently of each other are C1-C4alkyl, C5-C7cycloalkyl, or together with the N atom to which they are attached form a 5-membered, 6-membered or 7-membered ring, which m

Abstract: Described is a method and an apparatus for producing cured coating films on a substrate surface. Specifically, a portable spraygun may be used to initiate radiation cure without the operative having to be protected from radiation. The spraygun comprises a supply channel for a radiation-curable coating composition, a needle, a reserve for the radiation-curable coating composition, and, optionally, a supply channel for a gas.

Abstract: Iminoxytriazine compounds of the formula I wherein n is 1 or 2; R1 and R2 independently of each other are hydrogen, NH2, NHR5, NR5R6, COR5, COOR5, CONH2, CONHR5, CONR5R6, CN, SR5, OR5, C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl, wherein said C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl is unsubstituted or substituted by one or more radicals selected from the group consisting of C1-C12alkyl, C3-C12-cycloalkyl, phenyl, halogen and C1-C12 alkoxy, or R1 and R2 together with the C atom to which they are linked form a 4 to 12 membered carbocyclic or heterocyclic saturated or unsaturated ring which is unsubstituted or substituted by one or more radicals selected from the group consisting of C1-C12alkyl, C3-C12-cycloalkyl, phenyl, halogen and C1-C12 alkoxy; R3 is F, Cl, OH, OR5, SH, SR5, NH2, NHR5, NR5R6 or R1R2C?N—O—; wherein R1 and R2 in all groups R1R2C?N—O— in the compound of the formula I are identical or different; if n is 1, R4 is F, Cl, OH, OR5, SH, SR5, NH2, NHR5, NR5R6 or R1R2C

Abstract: Iminoxytriazine compounds of the formula I wherein n is 1 or 2; R1 and R2 independently of each other are hydrogen, NH2, NHR5, NR5R6, COR5, COOR5, CONH2, CONHR5, CONR5R6, CN, SR5, OR5, C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl, wherein said C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl is unsubstituted or substituted by one or more radicals selected from the group consisting of C1-C12alkyl, C3-C12-cycloalkyl, phenyl, halogen and C1-C12 alkoxy, or R1 and R2 together with the C atom to which they are linked form a 4 to 12 membered carbocyclic or heterocyclic saturated or unsaturated ring which is unsubstituted or substituted by one or more radicals selected from the group consisting of C1-C12alkyl, C3-C12-cycloalkyl, phenyl, halogen and C1-C12 alkoxy; R3 is F, Cl, OH, OR5, SH, SR5, NH2, NHR5, NR5R6 or R1R2C?N—O—; wherein R1 and R2 in all groups R1R2C?N—O— in the compound of the formula I are identical or different; if n is 1, R4 is F, Cl, OH, OR5, SH, SR5, NH2, NHR5, NR5R6 or R1R2C

Abstract: The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds. The O-Imino-isoureas compounds are compounds of the formula (I) wherein and salts thereof.

Abstract: The invention relates to the use of triazenes of formula (I) wherein Q is a direct bond or a bivalent radical —(CR8R9)—, Z1 is —O—, —NR10—, —CH2—, —(CR11R12)— or —C(?O)— and R1 to R12 are optionally substituted hydrocarbon residues, as precursors for radicals useful in reactions triggered by free radicals, such as polymerization of unsaturated monomers and degradation of polyolefins. Most of the triazenes of formula (I) are novel and claimed, too, as well as the preparation of triazenes of formula (I) and polymerizable compositions comprising them.

Abstract: The present invention provides photolatent Ti-chelate catalyst compounds of formula (I), wherein R1 is for example C6-C14 aryl which is substituted by one or more R?2, R?3 or R?4; or the two R1 together are unsubstituted linear or branched C1-C12alkylene; R2, R3, R4, R?2, R?3, and R?4 independently of each other are for example hydrogen, halogen or linear or branched C1-C20alkyl; R5, R6 and R7 independently of each other are hydrogen, linear or branched C1-C20alkyl, C6-C14aryl, Br or Cl, provided that not more than one of R5, R6 and R7 is hydrogen; as well as formulations comprising said compounds and defined 1,3-diketones.

Abstract: The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds.

Abstract: The invention relates to novel O-dialkylamino-isoureas and polymerizable compositions comprising these O-dialkylamino-isoureas of compounds of the general formula (I). The invention further relates to the use of O-dialkylamino-isoureas as polymerization initiators, especially to prepare coatings or for controlled degradation of polyolefins.

Abstract: The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds.

Abstract: A titanium-oxo-chelate catalyst formulation, comprising: (i) at least one compound of the formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11 and R12 independently of each other are for example hydrogen, halogen, C1-C20alkyl, C6-C14aryl which is unsubstituted or substituted; or R1, R2 and R3 and/or R4, R5 and R6 and/or R7, R8 and R9 and/or R10, R11 and R12 together with the C-atom to which they are attached each form a C6-C14aryl group which is unsubstituted or substituted; or R1 and R2 and/or R4 and R5 and/or R7 and R8 and/or R10 and R11 together with the C-atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate ligand compound of the formula (IIa), (IIb) or (IIc), wherein R1, R2, R3, R4, R5 and R6 are defined as above for formula (I), is suitable as photolatent catalyst formulation for polymerizing compounds, which are capable to crosslink in the presence of a Lewis acid.

Abstract: The present invention relates to a method and an apparatus for producing cured coating films on a substrate surface.

Abstract: The present invention provides organometallic latent catalyst compounds, which are suitable as catalysts in polyaddition or polycondensation reactions which are catalysed by a Lewis acid type catalyst, in particular for the crosslinking of a blocked or unblocked isocyanate or isothiocyanate component with a polyol or polythiolto form a polyurethane (PU).

Abstract: The present invention provides photolatent Ti-chelate catalyst compounds of formula (I), wherein R1 is for example C6-C14 aryl which is substituted by one or more R?2, R?3 or R?4; or the two R1 together are unsubstituted linear or branched C1-C12alkylene; R2, R3, R4, R?2, R?3, and R?4 independently of each other are for example hydrogen, halogen or linear or branched C1-C20 alkyl; R5, R6 and R7 independently of each other are hydrogen, linear or branched C1-C20 alkyl, C6-C14 aryl, Br or Cl, provided that not more than one of R5, R6 and R7 is hydrogen; as well as formulations comprising said compounds and defined 1,3-diketones.

Abstract: The present invention provides a photolatent Ti-chelate catalyst formulation, comprising (i) at least one compound of the formula (I) wherein R1 is C1-C20alkyl or C2-C20alkyl which is interrupted by one or more non-consecutive O-atoms; Y is formula (II) or optionally substituted phenyl; Y1 is formula (III) or optionally substituted phenyl; Y2 is formula (IV) or optionally substituted phenyl; Y3 is formula (V) or optionally substituted phenyl; R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are hydrogen, halogen, optionally substituted C1-C20alkyl, or R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are optionally substituted C6-C14aryl, provided that only one of R2, R3, R4 is hydrogen and only one of R5, R6, R7 is hydrogen and only one of R8, R9, R10 is hydrogen and only one of R11, R12, R13 is hydrogen; and (ii) at least one chelate ligand compound of the formula IIa, IIb or IIc, wherein Y? is formula (VI) or formula (VII); Y?1 is formula (VI

Abstract: The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds.