Abstract: A desilicated crystalline material having an MFI (ZSM-5) framework type, a molar silica to alumina ratio (SAR) of 15 or more, and mean crystal size of about 200 nm or less, is disclosed. The disclosed crystalline material has a mesopore volume of at least 0.40 cm3/g and a micropore volume of at least 0.10 cm3/g. A method of preparing a desilicated crystalline material is also disclosed. The method comprises mixing a starting ZSM-5 material having a mean crystal size of 200 nm or less in a base solution, collecting the solids by filtration or other separation methods, drying, and optionally calcining the solids.

Abstract: An ethylbenzene dealkylation catalyst composition comprising a ZSM-5 type zeolite as a carrier component, wherein said zeolite has been synthesized from an aqueous reaction mixture comprising one or more alumina sources, one or more silica sources, one or more alkali sources, and one or more primary and/or secondary amines and wherein the ZSM-5 type zeolite has a number average crystallite size in the range of from 1 to 10 ?m and a molar silica-to-alumina ratio (SAR) in the range of from 30 to 70; a method for reducing xylene losses in an ethylbenzene dealkylation process, said method comprising conducting the ethylbenzene dealklylation process in the presence of the afore-mentioned catalyst composition; and a process for the dealkylation of ethylbenzene, which process comprises contacting, in the presence of hydrogen, a feedstock which comprises ethylbenzene with said catalyst composition.

Abstract: A microporous crystalline material having a molar silica to alumina ratio (SAR) ranging from 10 to 15 and a fraction of Al in the zeolite framework of 0.63 or greater is disclosed. A method of selective catalytic reduction of nitrogen oxides in exhaust gas that comprises contacting exhaust gases, typically in the presence of ammonia, urea, an ammonia generating compound, or a hydrocarbon compound, with an article comprising the disclosed microporous crystalline is also disclosed. Further, a method of making the disclosed microporous crystalline material is disclosed.

Abstract: An as-synthesized microporous material having a CHA structure and containing at least one organic structure directing agent that has the following general structure of the quaternary ammonium cation is disclosed: A microporous crystalline material made from the as-synthesized material is also disclosed. A method of making microporous crystalline material using one or more organic structure directing agents is also disclosed. A method of selective catalytic reduction of nitrogen oxides in exhaust gas that comprises contacting exhaust gases, typically in the presence of ammonia, urea, an ammonia generating compound, or a hydrocarbon compound, with an article comprising the disclosed microporous crystalline is also disclosed.

Abstract: An as-synthesized microporous material having a CHA structure and containing at least one organic structure directing agent that has the following general structure of the quaternary ammonium cation is disclosed: A microporous crystalline material made from the as-synthesized material is also disclosed. A method of making microporous crystalline material using one or more organic structure directing agents is also disclosed. A method of selective catalytic reduction of nitrogen oxides in exhaust gas that comprises contacting exhaust gases, typically in the presence of ammonia, urea, an ammonia generating compound, or a hydrocarbon compound, with an article comprising the disclosed microporous crystalline is also disclosed.

Abstract: A microporous crystalline material having a molar silica to alumina ratio (SAR) ranging from 10 to 15 and a fraction of Al in the zeolite framework of 0.63 or greater is disclosed. A method of selective catalytic reduction of nitrogen oxides in exhaust gas that comprises contacting exhaust gases, typically in the presence of ammonia, urea, an ammonia generating compound, or a hydrocarbon compound, with an article comprising the disclosed microporous crystalline is also disclosed. Further, a method of making the disclosed microporous crystalline material is disclosed.

Abstract: Alkylaromatic conversion catalyst which comprises a) a carrier which comprises of from 20 to 70 wt % of a refractory oxide binder, of from 30 to 80 wt % of ZSM-5 having a mesopore volume of from 0.1 to 1.0 ml/g, a crystallite size of from 3 to 100 nm and a silica to alumina molar ratio in the range of from 20 to 200, all percentages being on the basis of total catalyst; b) an amount of from 0.001 to 5 wt % of one or more metals chosen from the group consisting of Groups 6, 9 and 10; and c) optionally a metal chosen from Group 14 in an amount up to 0.5 wt %, on the basis of total catalyst, and a process for the preparation of such catalyst.

Abstract: There is disclosed a highly crystalline, small crystal, ferrierite zeolite prepared from a gel containing a source of silica, alumina, alkali metal and a combination of two templating agents. The resulting material includes ferrierite crystals having a particle size of about or less than about 200 nm. The desired crystal size can be achieved by using a specific composition of the gel. The purity of the material and the crystal size was determined by using X-ray powder diffraction and scanning electron microscopy. The material has excellent surface area and micropore volume as determined by nitrogen adsorption.

Abstract: A one step synthesis of nanocrystalline zeolites ZSM-5 and Na? from a single template system in high yield has been discovered. The size of individual nanocrystals, as well as mesopore surface area and pore volume can be controlled by adjusting the pH of the reaction mixture, as well as the hydrothermal treatment temperature and duration. The mesopore volume and size distribution show a dependence on particle size such that smaller particles lead to higher mesopore volumes and narrower pore size distributions.

Abstract: There is disclosed a highly crystalline, small crystal, ferrierite zeolite prepared from a gel containing a source of silica, alumina, alkali metal and a combination of two templating agents. The resulting material includes ferrierite crystals having a particle size of about or less than about 200 nm. The desired crystal size can be achieved by using a specific composition of the gel. The purity of the material and the crystal size was determined by using X-ray powder diffraction and scanning electron microscopy. The material has excellent surface area and micropore volume as determined by nitrogen adsorption.

Abstract: The present invention is directing to a method for making a germanosilicate SSZ-75 molecular sieve using a tetramethylene-1,4-bis-(N-methylpyrrolidinium) dication as a structure directing agent.

Abstract: The present invention relates to new germanosilicate SSZ-75 molecular sieve, and methods for synthesizing germanosilicate SSZ-75.

Abstract: The present invention is directing to a method for making a germanosilicate SSZ-75 molecular sieve using a tetramethylene-1,4-bis-(N-methylpyrrolidinium) dication as a structure directing agent.

Abstract: The present invention relates to new germanosilicate SSZ-75 molecular sieve, and methods for synthesizing germanosilicate SSZ-75.

Abstract: A one step synthesis of nanocrystalline zeolites ZSM-5 and Na? from a single template system in high yield has been discovered. The size of individual nanocrystals, as well as mesopore surface area and pore volume can be controlled by adjusting the pH of the reaction mixture, as well as the hydrothermal treatment temperature and duration. The mesopore volume and size distribution show a dependence on particle size such that smaller particles lead to higher mesopore volumes and narrower pore size distributions.