Patents by Inventor Antonio Clareti Pereira
Antonio Clareti Pereira has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9663842Abstract: It is described a method for recovering rare earth elements from low grade ores including a first metal selected group containing at least one of iron and aluminum and a second metal selected from the group consisting of at least of the rare earth elements (lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, yttrium and scandium), the method comprising the steps of: (i) contacting the ore with sulfuric acid to obtain sulfates of the first group of metals, (ii) subjecting the mixture to high temperatures in order to convert the first group of sulfates into phosphates or other stable species and the second group into sulfates, (iii) adding water to the cool mixture, selectively dissolving the rare earth elements and (iv) subjecting the rare earth solution to a purification process.Type: GrantFiled: May 3, 2013Date of Patent: May 30, 2017Assignee: VALE S.A.Inventors: Tiago Valentim Berni, Antonio Clareti Pereira, Flávia Dutra Mendes, João Alberto Lessa Tude
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Patent number: 9169534Abstract: A method of recovering base metals from sulphide ores and concentrates includes mixing the base metals ore with ferric salts, heating the mixture, adding water to form a pulp, and stirring and filtering the pulp.Type: GrantFiled: July 23, 2013Date of Patent: October 27, 2015Assignee: VALE S.A.Inventors: Tiago Valentim Berni, Antonio Clareti Pereira, Felipe Hilario Guimarães
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Patent number: 8961649Abstract: A method for recovering base metal values from oxide ore is provided by the present disclosure. The ore includes a first metal selected from the group consisting at least one of iron and aluminum and a second metal selected from the group consisting of at least one of nickel, cobalt and copper. The method includes the steps of: contacting the oxide ore with hydrogen chloride gas to obtain chlorides of the first and second metals and subjecting at least the first and second metals to pyrohydrolysis at a predetermined temperature to decompose the chlorides of the first metal into oxides. The method also includes the step of mixing the oxides of the first metal and the chlorides of the second metal in an aqueous solution to dissolve the chlorides of the second metal and recovering the dissolved ions of the second metal from the aqueous solution.Type: GrantFiled: August 26, 2008Date of Patent: February 24, 2015Assignee: Vale Canada LimitedInventors: Antonio Clareti Pereira, Flavia Dutra Mendes, Tiago Valentim Berni, Ahmed Vahed
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Patent number: 8802042Abstract: A method for recovering base metal values from oxide ore is provided, where the ore includes a first group metal selected from nickel, cobalt and copper. The method includes reducing ore particle size to suit the latter unit operation, favoring contact for the metal elements, contacting the ore with ferric or ferrous chloride, hydrated or anhydrous, to produce a mix of ore and iron (II or III) chloride subjecting the mixture of the ore and ferric or ferrous chloride to enough energy to decompose the chlorides into hydrochloric acid and a iron oxides from the second group, forming their respective chlorides, selectively dissolve the produced base metal chlorides, leaving the metal as oxides and in the solid state, and recovering the dissolved base metal values from aqueous solution.Type: GrantFiled: July 14, 2010Date of Patent: August 12, 2014Assignee: Vale S.A.Inventors: Antonio Clareti Pereira, Tiago Valentim Berni
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Patent number: 8747795Abstract: Aspects of the present invention refers to a process for production of nickel carbonate including preparing a magnesium salt solution, contacting the solution with a stream of gaseous CO2, keeping pH between 4 and 10 and temperature between 0 and 100° C., during up to 5 hours to produce a first mixture, contacting the first mixture with a nickel sulphate solution to produce a second mixture, performing a separation of liquid and solid portions of the second mixture, and feeding the magnesium salt solution with the liquid portion. This process recycles the reagent used for producing nickel carbonate and yields a final product that is easy to handle and transport.Type: GrantFiled: March 26, 2012Date of Patent: June 10, 2014Assignee: Vale S.A.Inventors: Tiago Valentim Berni, Antonio Clareti Pereira, Felipe Hilario Guimar{hacek over (a)}es
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Publication number: 20140020510Abstract: The present invention discloses a new recovery of base metals from sulphide ores and concentrates, which comprises mixing the base metal's ore with ferric salts, heating the said mixture; adding water to form a pulp, stirring and filtering the pulp.Type: ApplicationFiled: July 23, 2013Publication date: January 23, 2014Applicant: VALE S/AInventors: Tiago Valentim BERNI, Antonio Clareti PEREIRA, Felipe Hilario GUIMARÃES
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Patent number: 8628739Abstract: The present invention refers to a direct purification process of a nickel laterite leaching effluent including adjusting a pH of a leaching solution, employing an ion exchange resin to adsorb nickel and copper selectively over ferric or ferrous iron, and recovering nickel.Type: GrantFiled: February 1, 2012Date of Patent: January 14, 2014Assignee: ValeInventors: Tiago Valentim Berni, Antonio Clareti Pereira
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Patent number: 8597601Abstract: A process to use ferric sulphate equilibrium to reduce overall acid consumption and iron extraction, the process comprising the steps of: (i) sulphating; (ii) selective pyrolysis and (iii) selective dissolution.Type: GrantFiled: June 1, 2012Date of Patent: December 3, 2013Assignee: Vale S.A.Inventors: Tiago Valentim Berni, Antonio Clareti Pereira, Flavia Dutra Mendes
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Patent number: 8470272Abstract: The present invention resides in a process of recovering nickel and cobalt, regenerating the main raw materials, said process including the steps of: granulometric separation; leaching; neutralization; MHP production in only one stage and the pressure crystallization of magnesium sulphite. The process proposes a way to recovery nickel and cobalt from laterite ores through the atmospheric and heap leaching with staged addition of ore—by size separation—and H2SO4, decreasing the nickel losses and simplifying the neutralization circuit and producing a more purified MHP. The present process route is employed for nickel extraction, including the one from high magnesium containing lateritic ores.Type: GrantFiled: June 1, 2009Date of Patent: June 25, 2013Assignee: Vale S.A.Inventors: Antonio Clareti Pereira, Felipe Hilario Guimaraes, Joao Alberto de Lessa Tude, Lino Rodrigues de Freitas, Tiago Valentim Berni
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Publication number: 20130028816Abstract: A process to use ferric sulphate equilibrium to reduce overall acid consumption and iron extraction, the process comprising the steps of: (i) sulphating; (ii) selective pyrolysis and (iii) selective dissolution.Type: ApplicationFiled: June 1, 2012Publication date: January 31, 2013Applicant: Vale S/AInventors: Tiago Valentim BERNI, Antonio Clareti Pereira, Flavia Dutra Mendes
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Publication number: 20120269713Abstract: Aspects of the present invention refers to a process for production of nickel carbonate including preparing a magnesium salt solution, contacting the solution with a stream of gaseous CO2, keeping pH between 4 and 10 and temperature between 0 and 100° C., during up to 5 hours to produce a first mixture, contacting the first mixture with a nickel sulphate solution to produce a second mixture, performing a separation of liquid and solid portions of the second mixture, and feeding the magnesium salt solution with the liquid portion. This process recycles the reagent used for producing nickel carbonate and yields a final product that is easy to handle and transport.Type: ApplicationFiled: March 26, 2012Publication date: October 25, 2012Applicant: Vale S/AInventors: Tiago Valentim BERNI, Antonio Clareti Pereira, Felipe Hilário Guimarães
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Publication number: 20120213681Abstract: The present invention refers to a direct purification process of a nickel laterite leaching effluent including adjusting a pH of a leaching solution, employing an ion exchange resin to adsorb nickel and copper selectively over ferric or ferrous iron, and recovering nickel.Type: ApplicationFiled: February 1, 2012Publication date: August 23, 2012Applicant: VALE S.A.Inventors: Tiago Valentim Berni, Antonio Clareti Pereira
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Patent number: 8173086Abstract: A method for recovering base metal values from oxide ore is provided, where the ore includes a first group metal selected from iron, magnesium and aluminum and a second group metal selected from nickel, cobalt and copper. The method includes reducing ore particle size to suit the latter unit operations, favoring contact of the metal elements, contacting the ore with ferric or ferrous chloride, hydrated or anhydrous, to produce a mix of ore and iron(II or III) chloride, subjecting the mixture of the ore and ferric or ferrous chloride to enough energy to decompose the chlorides into hydrochloric acid and a iron oxide, contacting the readily-formed hydrochloric acid with the base metal oxides from the second group, forming their respective chlorides, selectively dissolve the produced base metal chlorides, leaving the metals as oxides and in the solid state, and recovering the dissolved base metal values from aqueous solution.Type: GrantFiled: July 13, 2010Date of Patent: May 8, 2012Assignee: Vale S.A.Inventors: Antonio Clareti Pereira, Tiago Valentim Berni
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Publication number: 20110142736Abstract: A method for recovering base metal values from oxide ore is provided, where the ore includes a first group metal selected from iron, magnesium and aluminum and a second group metal selected from nickel, cobalt and copper. The method includes reducing ore particle size to suit the latter unit operations, favoring contact of the metal elements, contacting the ore with ferric or ferrous chloride, hydrated or anhydrous, to produce a mix of ore and iron(II or III) chloride, subjecting the mixture of the ore and ferric or ferrous chloride to enough energy to decompose the chlorides into hydrochloric acid and a iron oxide, contacting the readily-formed hydrochloric acid with the base metal oxides from the second group, forming their respective chlorides, selectively dissolve the produced base metal chlorides, leaving the metals as oxides and in the solid state, and recovering the dissolved base metal values from aqueous solution.Type: ApplicationFiled: July 13, 2010Publication date: June 16, 2011Applicant: VALE S.A.Inventors: Antonio Clareti Pereira, Tiago Valentim Berni
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Publication number: 20110110832Abstract: The present invention resides in a process of recovering nickel and cobalt, regenerating the main raw materials, said process including the steps of: granulometric separation; leaching; neutralization; MHP production in only one stage and the pressure crystallization of magnesium sulphite. The process proposes a way to recovery nickel and cobalt from laterite ores through the atmospheric and heap leaching with staged addition of ore—by size separation—and H2SO4, decreasing the nickel losses and simplifying the neutralization circuit and producing a more purified MHP. The present process route is employed for nickel extraction, including the one from high magnesium containing lateritic ores.Type: ApplicationFiled: June 1, 2009Publication date: May 12, 2011Applicant: VALE S.A.Inventors: Antonio Clareti Pereira, Felipe Hilario Guimaraes, Joao Alberto de Lessa Tude, Lino Rodrigues de Freitas, Tiago Valentim Berni
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Publication number: 20090241731Abstract: A method for recovering base metal values from oxide ore is provided by the present disclosure. The ore includes a first metal selected from the group consisting at least one of iron and aluminum and a second metal selected from the group consisting of at least one of nickel, cobalt and copper. The method includes the steps of: contacting the oxide ore with hydrogen chloride gas to obtain chlorides of the first and second metals and subjecting at least the first and second metals to pyrohydrolysis at a predetermined temperature to decompose the chlorides of the first metal into oxides. The method also includes the step of mixing the oxides of the first metal and the chlorides of the second metal in an aqueous solution to dissolve the chlorides of the second metal and recovering the dissolved ions of the second metal from the aqueous solution.Type: ApplicationFiled: August 26, 2008Publication date: October 1, 2009Applicant: VALE INCO LIMITEDInventors: Antonio Clareti Pereira, Flavia Dutra Mendes, Tiago Valentim Berni, Ahmed Vahed