Patents by Inventor Antonio J. MARTIN-FERNANDEZ

Antonio J. MARTIN-FERNANDEZ has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10676416
    Abstract: The invention relates to a process for methanol synthesis comprising the steps of providing a syngas feed stream comprising hydrogen and a mixture of carbon dioxide and carbon monoxide, wherein carbon dioxide represents from 1 to 50 mol % of the total molar content of the feed stream, carbon monoxide is contained from 0.1 to 85 mol % of the total molar content, and H2 is comprised from 5 to 95 mol % of the total molar content of the feed stream; providing an indium oxide catalyst selected from a bulk catalyst and a supported catalyst comprising indium oxide (In2O3) as the main active phase; putting in contact said stream with said catalyst at a reaction temperature of at least 373 K (99.85° C.) and under a pressure ranging of at least 1 MPa; and recovering the methanol effluents. The invention also relates to an indium oxide based catalyst.
    Type: Grant
    Filed: December 20, 2016
    Date of Patent: June 9, 2020
    Assignees: TOTAL RAFFINAGE CHIMIE, ETH ZURICH
    Inventors: Daniel Curulla-Ferre, Charlotte Drouilly, Oliver Martin, Cecilia Mondelli, Javier Perez-Ramirez, Antonio J. Martin-Fernandez
  • Patent number: 10668450
    Abstract: The invention relates to a process for methanol synthesis comprising the steps of providing a syngas feed stream comprising hydrogen and carbon oxides selected from carbon dioxide or a mixture of carbon dioxide and carbon monoxide, wherein carbon dioxide represents from 1 to 50 mol % of the total molar content of the feed stream, carbon monoxide is contained from 0 to 85 mol % of the total molar content, and H2 is comprised from 5 to 95 mol % of the total molar content of the feed stream, and a catalyst comprising indium oxide (In2O3) on a support wherein the support comprises zirconium dioxide or is zirconium dioxide; putting in contact said stream with said supported catalyst at a reaction temperature of at least 373 K (99.85° C.) and under a pressure ranging of at least 1 MPa; and recovering the methanol effluents. The invention also relates to a supported indium oxide catalyst.
    Type: Grant
    Filed: December 20, 2016
    Date of Patent: June 2, 2020
    Assignee: TOTAL RAFFINAGE CHIMIE
    Inventors: Daniel Curulla-Ferre, Charlotte Drouilly, Oliver Martin, Cecilia Mondelli, Javier Perez-Ramirez, Antonio J. Martin-Fernandez
  • Publication number: 20200061582
    Abstract: The invention relates to a process for methanol synthesis comprising the steps of providing a syngas feed stream comprising hydrogen and carbon oxides selected from carbon dioxide or a mixture of carbon dioxide and carbon monoxide, wherein carbon dioxide represents from 1 to 50 mol % of the total molar content of the feed stream, carbon monoxide is contained from 0 to 85 mol % of the total molar content, and H2 is comprised from 5 to 95 mol % of the total molar content of the feed stream, and a catalyst comprising indium oxide (In2O3) on a support wherein the support comprises zirconium dioxide or is zirconium dioxide; putting in contact said stream with said supported catalyst at a reaction temperature of at least 373 K (99.85° C.) and under a pressure ranging of at least 1 MPa; and recovering the methanol effluents. The invention also relates to a supported indium oxide catalyst.
    Type: Application
    Filed: December 20, 2016
    Publication date: February 27, 2020
    Inventors: Daniel CURULLA-FERRE, Charlotte DROUILLY, Oliver MARTIN, Cecilia MONDELLI, Javier PEREZ-RAMIREZ, Antonio J. MARTIN-FERNANDEZ
  • Publication number: 20200048173
    Abstract: The invention relates to a process for methanol synthesis comprising the steps of providing a syngas feed stream comprising hydrogen and a mixture of carbon dioxide and carbon monoxide, wherein carbon dioxide represents from 1 to 50 mol % of the total molar content of the feed stream, carbon monoxide is contained from 0.1 to 85 mol % of the total molar content, and H2 is comprised from 5 to 95 mol % of the total molar content of the feed stream; providing an indium oxide catalyst selected from a bulk catalyst and a supported catalyst comprising indium oxide (In2O3) as the main active phase; putting in contact said stream with said catalyst at a reaction temperature of at least 373 K (99.85° C.) and under a pressure ranging of at least 1 MPa; and recovering the methanol effluents. The invention also relates to an indium oxide based catalyst.
    Type: Application
    Filed: December 20, 2016
    Publication date: February 13, 2020
    Inventors: Daniel CURULLA-FERRE, Charlotte DROUILLY, Oliver MARTIN, Cecilia MONDELLI, Javier PEREZ-RAMIREZ, Antonio J. MARTIN-FERNANDEZ