Patents by Inventor Antonio Pasquale

Antonio Pasquale has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6818581
    Abstract: A method for denitrification of water, in which the water to be denitrified is made to flow over a porous carrier which comprises a transition metal, preferably palladium, used in an amount between 0.01 and 5% by weight on the carrier and on which denitrifying bacterial strains capable of surviving in the presence of hydrogen are made to adhere, and in which hydrogen is used as a reducing agent and the pH of the reaction is adjusted to values of 4.5 to 7.8 preferably by using carbon dioxide.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: November 16, 2004
    Assignee: SUD Chemie MT S.r.l.
    Inventors: Antonio Pasquale, Carlo Rubini, Michele Rossi, Luigi Cavalli
  • Patent number: 6763714
    Abstract: Method for controlling the level of a liquid (2) contained in at least one vessel (3), which comprises the following operative steps: inserting a measure tube (1) in the liquid (2); arranging an auxiliary duct (6; 21) inside or outside the vessel (3); measuring the pressure in said measure tube (1); measuring the pressure in said auxiliary duct (6; 21); determining the difference between the pressures in the measure tube (1) and in the auxiliary duct (6; 21); determining the value of the density or the specific weight of the liquid (2) in the vessel (3); dividing said pressure difference by said value of the density or specific weight of the liquid (2). The present invention also relates to an apparatus for carrying out said method.
    Type: Grant
    Filed: November 21, 2002
    Date of Patent: July 20, 2004
    Assignee: Gigi Molina Brevetti Plastici, S.p.A.
    Inventors: Mario Molina, Antonio Pasquale
  • Publication number: 20040118759
    Abstract: A method for denitrification of water, in which the water to be denitrified is made to flow over a porous carrier which comprises a transition metal, preferably palladium, used in an amount between 0.01 and 5% by weight on the carrier and on which denitrifying bacterial strains capable of surviving in the presence of hydrogen are made to adhere, and in which hydrogen is used as a reducing agent and the pH of the reaction is adjusted to values of 4.5 to 7.8 preferably by using carbon dioxide.
    Type: Application
    Filed: October 30, 2003
    Publication date: June 24, 2004
    Applicant: SUD Chemie MT S.R.L.
    Inventors: Antonio Pasquale, Carlo Rubini, Michele Rossi, Luigi Cavalli
  • Patent number: 6669847
    Abstract: A method for denitrification of water, in which the water to be denitrified is made to flow over a porous carrier which comprises a transition metal, preferably palladium, used in an amount between 0.01 and 5% by weight on the carrier and on which denitrifying bacterial strains capable of surviving in the presence of hydrogen are made to adhere, and in which hydrogen is used as a reducing agent and the pH of the reaction is adjusted to values of 4.5 to 7.8 preferably by using carbon dioxide.
    Type: Grant
    Filed: July 20, 2001
    Date of Patent: December 30, 2003
    Assignee: Sud Chemie MT S.r.l.
    Inventors: Antonio Pasquale, Carlo Rubini, Michele Rossi, Luigi Cavalli
  • Patent number: 6627777
    Abstract: Catalysts for the fluid-bed hydrodechlorination of carbon tetrachloride to chloroform having high catalytic stability and comprising platinum supported on microspheroidal gamma alumina, characterized in that the platinum is in the form of particles dispersed throughout the mass of the support.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: September 30, 2003
    Assignee: Sud Chemie MT S.R.L.
    Inventors: Michele Rossi, Carlo Rubini, Antonio Pasquale, Luigi Cavalli
  • Publication number: 20030131661
    Abstract: Method for controlling the level of a liquid (2) contained in at least one vessel (3), which comprises the following operative steps: inserting a measure tube (1) in the liquid (2); arranging an auxiliary duct (6; 21) inside or outside the vessel (3); measuring the pressure in said measure tube (1); measuring the pressure in said auxiliary duct (6; 21); determining the difference between the pressures in the measure tube (1) and in the auxiliary duct (6; 21); determining the value of the density or the specific weight of the liquid (2) in the vessel (3); dividing said pressure difference by said value of the density or specific weight of the liquid (2). The present invention also relates to an apparatus for carrying out said method.
    Type: Application
    Filed: November 21, 2002
    Publication date: July 17, 2003
    Inventors: Mario Molina, Antonio Pasquale
  • Publication number: 20020033366
    Abstract: A method for denitrification of water, in which the water to be denitrified is made to flow over a porous carrier which comprises a transition metal, preferably palladium, used in an amount between 0.01 and 5% by weight on the carrier and on which denitrifying bacterial strains capable of surviving in the presence of hydrogen are made to adhere, and in which hydrogen is used as a reducing agent and the pH of the reaction is adjusted to values of 4.5 to 7.8 preferably by using carbon dioxide.
    Type: Application
    Filed: July 20, 2001
    Publication date: March 21, 2002
    Inventors: Antonio Pasquale, Carlo Rubini, Michele Rossi, Luigi Cavalli
  • Patent number: 5877357
    Abstract: The invention relates to a process for preparing perhaloethers from perhaloolefins and to a few "per se" new classes of perhaloethers thereby obtained.The process consists in reacting a perhalomonoolefin with a fluoroxy compound R.sub.x --OF (wherein R.sub.x represents a perhalogenated alkyl radical) at a temperature not exceeding 20.degree. C. in a liquid reaction medium and in the presence of inert gases.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: March 2, 1999
    Assignee: Ausimont S.p.A.
    Inventors: Antonio Marraccini, Antonio Pasquale, Tiziana Fiorani, Walter Navarrini
  • Patent number: 5648560
    Abstract: A process for preparing perhaloethers from perhaloolefins by reacting at least one fluorooxy compound R.sub.x --OF, wherein R.sub.x is a perhaloalkyl radical, with a perfluoroolefin in a liquid phase, optionally containing an organic solvent inert to the perfluoroolefin, while maintaining the temperature of the liquid phase in the range of -30.degree. to -120.degree. C. The process includes continuously feeding to the liquid phase a stream of an inert gas and a gaseous stream of the fluorooxy compound.
    Type: Grant
    Filed: December 9, 1994
    Date of Patent: July 15, 1997
    Assignee: Ausimont S.p.A.
    Inventors: Antonio Marraccini, Antonio Pasquale, Tiziana Fiorani, Walter Navarrini
  • Patent number: 5237108
    Abstract: The invention relates to new peroxide perfluoropolyethers having formula: ##STR1## wherein: A and B are end groups,X represents a (R'O).sub.m R" group where R' is selected from the class consisting of ##STR2## and R" is a perfluoroalkyl group; the value of "m" ranging from 0 to 6. The invention relates also to processes for preparing said perfluoropolyethers and other classes of non peroxide perfluoropolyethers derived therefrom.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: August 17, 1993
    Assignee: Ausimont S.r.l.
    Inventors: Antonio Marraccini, Antonio Pasquale, Anna M. Staccione, Giuseppe Marchinonni
  • Patent number: 5220076
    Abstract: The invention relates to new peroxide perfluoropolyethers having formula: ##STR1## wherein: A and B are end groups,X represents a (R'O).sub.m R" group where R' is selected from the class consisting of --CF.sub.2 --, --CF.sub.2 --CF.sub.2 -- and ##STR2## and R" is a perfluoroalkyl group; the value of "m" ranging from 0 to 6. The invention relates also to processes for preparing said perfluoropolyethers and other classes of non peroxide perfluoropolyethers derived therefrom.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: June 15, 1993
    Assignee: Ausimont S.r.l.
    Inventors: Antonio Marraccini, Antonio Pasquale, Anna M. Staccione, Giuseppe Marchionni
  • Patent number: 5144092
    Abstract: The invention relates to new peroxide perfluoropolyethers having formula: ##STR1## wherein: A and B are end groups,X represents a (R'O).sub.m R" group where R' is selected from the class consisting of ##STR2## and R" is a perfluoroalkyl group; the value of "m" ranging from 0 to 6. The invention relates also to processes for preparing said perfluoropolyethers and other classes of non peroxide perfluoropolyethers derived therefrom.
    Type: Grant
    Filed: March 5, 1991
    Date of Patent: September 1, 1992
    Assignee: Ausimont S.r.l.
    Inventors: Antonio Marraccini, Antonio Pasquale, Anna M. Staccione, Giuseppe Marchionni
  • Patent number: 5087765
    Abstract: In the process for preparing chlorotrifluoroethylene telomers by reaction of chlorotrifluoroethylene with CF.sub.3 CF or R.sub.x --CF.sub.2 OF (wherein R.sub.x may be also a perfluoroalkyl radical having 1 to 10 carbon atoms), the content of telomers with end groups --F is increased or mixtures of telomers containing species with end groups --Cl are obtained by adding F.sub.2, according to particular modalities, to the reaction medium.
    Type: Grant
    Filed: January 11, 1990
    Date of Patent: February 11, 1992
    Assignee: Ausimont S.r.L.
    Inventors: Antonio Marraccini, Antonio Pasquale, Marco Vincenti
  • Patent number: 4996370
    Abstract: Preparing fluorinated conjugated olefinic products having, among others, the formulae:R.sub.x O--(CF.dbd.CF).sub.m --F (A)R.sub.x O--(CF.dbd.CF).sub.m --OR.sub.x (B)F--(CF.dbd.CF).sub.m --F (C)andR.sub.y --(CF.dbd.CF).sub.m --F (D)wherein:R.sub.x and R.sub.y represent, among others, a perhalogenated alkyl radical containing from 1 to 10 carbon atoms in the case of R.sub.x and from 1 to 9 carbon atoms in the case of R.sub.y, andm is a numeral in the range of from 2 to 10.These olefinic products are obtained by reacting telomeric products having, among others, the formulae:R.sub.x O--(CFCl--CFCl).sub.m --FR.sub.x O--(CFCl--CFCkl).sub.m --OR.sub.xF--(CFCl--CFCl).sub.m --F, andR.sub.y --(CFCl--CFCl).sub.m --Fwith zinc powder, at temperatures within the range of from 40.degree. C. up to 160.degree. C., in an organic solvent selected from among alcohols, dimethylformide and dimethylsulfoxide. Many of these products, among which those corresponding to formulae (A), (B) and (D), are new.
    Type: Grant
    Filed: April 3, 1990
    Date of Patent: February 26, 1991
    Assignee: Ausimont S.r.l.
    Inventors: Antonio Marraccini, Antonio Pasquale, Tiziana Fiorani
  • Patent number: 4947006
    Abstract: Preparing fluorinated conjugated olefinic products having, among others, the formulae:R.sub.x O--(CF.dbd.CF).sub.m --F (A)R.sub.x O--(CF.dbd.CF).sub.m --OR.sub.x (B)F--(CF.dbd.CF).sub.m --F (C), andR.sub.y --(CF.dbd.CF).sub.m --F (D)wherein:R.sub.x and R.sub.y represent, among others, a perhalogenated alkyl radical containing from 1 to 10 carbon atoms in the case of R.sub.x and from 1 to 9 carbon atoms in the case of R.sub.y, andm is a numeral in the range of from 2 to 10.These olefinic products are obtained by reacting telomeric products having, among others, the formulae:R.sub.x O--(CFCl--CFCl).sub.m --FR.sub.x O--(CFCl--CFCl).sub.m --OR.sub.xF--(CFCl--CFCl).sub.m --F, andR.sub.y --(CFCl--CFCl).sub.
    Type: Grant
    Filed: June 29, 1989
    Date of Patent: August 7, 1990
    Assignee: AUSIMONT S.r.l.
    Inventors: Antonio Marraccini, Antonio Pasquale, Tiziana Fiorani
  • Patent number: 4814113
    Abstract: Process for the preparation of a perfluoroacyl fluoride wherein the acyl radical is a propionyl or butyryl group, characterized in that perfluoroalkylvinylether wherein the alkyl radical is a methyl or ethyl group is thermally treated in the presence of a catalyst selected from the group consisting of:(A) a fluoride of Li, Na, K, Cs or Rb, or another compound of Li, Na, K, Cs or Rb which is easily fluorinated under the reaction conditions;(B) a fluoride of Be, Mg, Ca, Sr, or Ba, or another compound of Be, Mg, Ca, Sr, or Ba which is easily fluorinatable under the reaction conditions:(C) a fluoroaluminate, fluorosilicate, fluorotitanate or fluorometallate of an alkali metal, or of a metal belonging to group IIA of the Periodic Table, i.e.
    Type: Grant
    Filed: September 18, 1987
    Date of Patent: March 21, 1989
    Assignee: Ausimont S.p.A.
    Inventors: Paolo Cuzzato, Arsenio Castellan, Antonio Pasquale
  • Patent number: 4684408
    Abstract: Silane quinacridone dyes, composite pigments obtainable therefrom by association with an inorganic substrate, and the processes for preparing them. The dyes have the general formula: ##STR1## wherein X is an --SO.sub.2 NHR group, where R is an alkyl group, linear or branched, having from 1 to 6 carbon atoms, a cycloalkyl group, a phenyl group optionally substituted by one or more alkyl or alkoxy groups (C.sub.1 -C.sub.6), a halogen;Y and Z indicate a silane group having the formula: ##STR2## wherein R.sub.1 is an alkoxy group (C.sub.1 -C.sub.2), R.sub.2 is an alkyl group (C.sub.1 -C.sub.4) or a phenyl group; n is 3, 4 or 5; q is 0 or 1; p and m are integers, such that when q is 1, p is 2 and m is 0, 1 or 2, and when q is 0, p is 3 and m is 0, 1, 2 or 3; W indicates an --SO.sub.3 H group; a, b and c are 0 or 1, selected in such a way that the sum a+b+c is equal to 1.
    Type: Grant
    Filed: February 28, 1986
    Date of Patent: August 4, 1987
    Assignee: Montedison S.p.A.
    Inventors: Antonio Marraccini, Filippo M. Carlini, Antonio Pasquale, Michele Pontevivo
  • Patent number: 4655843
    Abstract: Silane diimidic tetracarboxylic perylene dyes, the composite pigments obtainable therefrom by means of grafting onto an inorganic substrate, and the processes for preparing same.The dyes have the general formula: ##STR1## in which R is the residue of a silane group of formula: ##STR2## in which n is 3, 4 or 5; q is 0 or 1; p and m are such integers than when q is 0, p is 3 and m is 0, 1, 2 or 3, and when q is 1, p is 2 and m is 0, 1 or 2; R.sub.2 is an alkyl C.sub.1 -C.sub.4 or a phenyl; R.sub.3 is an alkoxyl C.sub.1 -C.sub.2 ; R.sub.1 may be the same as R or represent an alkyl C.sub.1 -C.sub.6, a cycloalkyl, a phenyl optionally substituted by one or more alkyl or alkoxyl groups C.sub.1 -C.sub.6 or a halogen.The dyes and the composite pigments obtained from said dyes are utilized in paints, air and stove enamels, in the pigmentation of plastic materials, and in printing inks.
    Type: Grant
    Filed: March 12, 1986
    Date of Patent: April 7, 1987
    Assignee: Montedison S.p.A.
    Inventors: Antonio Marraccini, Filippo M. Carlini, Giorgio Bottaccio, Antonio Pasquale, Giorgio Maranzana
  • Patent number: 4613667
    Abstract: Silane diimidic tetracarboxylic perylene dyes, the composite pigments obtainable therefrom by means of grafting onto an inorganic substrate, and the processes for preparing same.The dyes have the general formula: ##STR1## in which R is the residue of a silane group of formula: ##STR2## in which n is 3, 4 or 5; q is 0 or 1, p and m are such integers than when q is 0, p is 3 and m is 0, 1, 2 or 3, and when q is 1, p is 2 and m is 0, 1 or 2; R.sub.2 is an alkyl C.sub.1 -C.sub.4 or a phenyl; R.sub.3 is an alkoxyl C.sub.1 -C.sub.2 ; R.sub.1 may be the same as R or represent an alkyl C.sub.1 -C.sub.6, a cycloalkyl, a phenyl optionally substituted by one or more alkyl or alkoxyl groups C.sub.1 -C.sub.6 or a halogen.The dyes and the composite pigments obtained from said dyes are utilized in paints, air and stove enamels, in the pigmentation of plastic materials, and in printing inks.
    Type: Grant
    Filed: October 22, 1984
    Date of Patent: September 23, 1986
    Assignee: Montedison S.p.A.
    Inventors: Antonio Marraccini, Filippo M. Carlini, Giorgio Bottaccio, Antonio Pasquale, Giorgio Maranzana
  • Patent number: 4609404
    Abstract: This invention relates to organic dyes containing silane groups; composite pigments obtainable by grafting said dyes onto an inorganic substrate; and, the respective processes for preparing said dyes and composite pigments.The dyes have general formula: ##STR1## wherein R.sub.1 and R.sub.2, which may be equal or different, are selected from the group consisting of H, --NH.sub.2, --NHR wherein R is an alkyl group having from 1 to 4 carbon atoms or a phenyl group, --NHCOCH.sub.3, --NHCOC.sub.6 H.sub.5, --NO.sub.2, a halogen, --OH, --O--C.sub.6 H.sub.5 and --S--C.sub.6 H.sub.5 ; n is a number selected from 3, 4 and 5; W is selected from the group consisting of an alkyl group having from 1 to 4 carbon atoms and a phenyl group; Y is an alkoxy group having from 1 to 4 carbon atoms; q is a number selected from 0 and 1; X is 3 and m is a number selected from 0, 1, 2 and 3 when q is 0; x is 2 and m is a number selected from 0, 1 and 2 when q is 1.
    Type: Grant
    Filed: August 17, 1983
    Date of Patent: September 2, 1986
    Assignee: Montedison S.p.A.
    Inventors: Antonio Marraccini, Filippo M. Carlini, Antonio Pasquale, Giorgio Maranzana