Abstract: The present invention relates to an expandable polymeric composition comprising: a) a polymeric matrix containing vinyl aromatic polymers and/or copolymers; b) from 0.1% to 20% by weight, calculated on the polymeric matrix (a), of an athermanous agent; c) from 0.01% to 10% by weight, calculated on the polymeric matrix (a), of at least one non-polymeric brominated flame retardant additive; d) from 0.01% to 10% by weight, calculated on the polymeric matrix (a), of at least one brominated polymer containing at least 50% bromine; e) from 0.01% to 5% by weight, calculated on the polymeric matrix (a), of a synergistic flame retardant additive; f) from 1% by weight to 10% by weight of at least one blowing agent.

Abstract: Expandable vinyl aromatic polymers which comprise: a matrix obtained by polymerizing 50-100% by weight of one or more vinyl aromatic monomers and 0-50% by weight of at least one copolymer izable monomer; 1-10% by weight, calculated with respect to the polymer (a), of an expanding agent englobed in the polymeric matrix; 0.05-25% by weight, calculated with respect to the polymer (a), of a filler comprising coke with a surface area, measured according to ASTM D-3037/89, ranging from 5 to 50 m2/g.

Abstract: Expandable vinyl aromatic polymers comprising: a matrix obtained by polymerizing 50-100% by weight of one or more vinyl aromatic monomers and 0-50% by weight of at least one co-polymerizable monomer; 1-10% by weight, calculated with respect to polymer (a), of an expanding agent embedded in the polymeric matrix; 0-25% by weight, calculated with respect to polymer (a), of a filler comprising carbon coke having an average diameter of between 0.5 and 100 ?m, with a surface area, measured according to ASTM D-3037/89, ranging from 5 to 200 m2/g; 0.05-10% by weight, calculated with respect to polymer (a), of expanded graphite in particle form, with a particle average diameter (size) ranging from 1 to 30 ?m, a surface area, measured according to ASTM D-3037/89, ranging from 5 to 500 m2/g and a density ranging from 1.5 to 5 g/cm3.

Abstract: The present invention relates to an expandable polymeric composition comprising: a) a polymeric matrix containing vinyl aromatic polymers and/or copolymers; b) from 0.1% to 20% by weight, calculated on the polymeric matrix (a), of an athermanous agent; c) from 0.01% to 10% by weight, calculated on the polymeric matrix (a), of at least one non-polymeric brominated flame retardant additive; d) from 0.01% to 10% by weight, calculated on the polymeric matrix (a), of at least one brominated polymer containing at least 50% bromine; e) from 0.01% to 5% by weight, calculated on the polymeric matrix (a), of a synergistic flame retardant additive; f) from 1% by weight to 10% by weight of at least one blowing agent.

Abstract: The present invention relates to a self-extinguishing polymeric composition comprising: a) a stabilizing polymeric composition containing i) from 80% to 99.5% by weight of one or more vinylaromatic polymers compatible with each other; and ii) from 0.5% to 20% by weight of at least one block copolymer containing: 1) at least one vinylaromatic polymer block compatible N with (i) and constituting a weight quantity equal to or higher than 15% by weight with respect to the whole block copolymer, and 2) at least one vinyl copolymer block containing epoxy groups so that there is from 0.7% to 19% by weight of oxirane oxygen calculated on the total of block copolymer; and b) from 0.03 phr by weight to 10 phr by weight, calculated on the basis of component (a), of at least one halogenated flame retardant.

Abstract: Expandable vinyl aromatic polymers comprising: a matrix obtained by polymerizing 50-100% by weight of one or more vinyl aromatic monomers and 0-50% by weight of at least one co-polymerizable monomer; 1-10% by weight, calculated with respect to polymer (a), of an expanding agent embedded in the polymeric matrix; 0-25% by weight, calculated with respect to polymer (a), of a filler comprising carbon coke having an average diameter of between 0.5 and 100 ?m, with a surface area, measured according to ASTM D-3037/89, ranging from 5 to 200 m2/g; 0.05-10% by weight, calculated with respect to polymer (a), of expanded graphite in particle form, with a particle average diameter (size) ranging from 1 to 30 ?m, a surface area, measured according to ASTM D-3037/89, ranging from 5 to 500 m2/g and a density ranging from 1.5 to 5 g/cm3.

Abstract: The present invention relates to a concentrated polymeric composition which comprises: a) vinyl aromatic polymers and/or copolymers in an amount ranging from 10% to 90% by weight, calculated with respect to the overall composition, with respect to the overall composition, b) at least one compound containing epoxy functional groups in an amount ranging from 0.01% to 5% by weight, calculated with respect to the overall composition, with respect to the overall composition, c) at least one infrared absorbing agent, in an amount ranging from 10% to 90% by weight, calculated with respect to the overall composition, with respect to the overall composition.

Abstract: Compositions based on self-extinguishing expandable vinyl aromatic polymers in granules comprising: a. a polymeric matrix and, homogeneously englobed in the polymeric matrix, b. 3-10% by weight, calculated with respect to the polymer (a), of an expanding system; c. 0.005-5% by weight, calculated with respect to the polymer (a), of a brominated flame-retardant agent; d. 0.001-2% by weight, calculated with respect to the polymer (a), of a synergic additive; e. 0.005-5% by weight, calculated with respect to the polymer (a), of at least one stabilizing additive selected from: i. pyrophosphates of alkaline or alkaline earth metals, an ammonium group or a unit deriving from melamine; ii. melamine polyphosphate; iii. partially or completely salified polycarboxylic acids; iv. citrates of alkaline or alkaline earth metals; v. polyfunctional alcohols with 2 or more alcohol functions; vi. esters of poly-functional alcohols.

Abstract: The present invention relates to a self-extinguishing polymeric composition comprising: a) a stabilizing polymeric composition containing i) from 80% to 99.5% by weight of one or more vinylaromatic polymers compatible with each other; and ii) from 0.5% to 20% by weight of at least one block copolymer containing: 1) at least one vinylaromatic polymer block compatible N with (i) and constituting a weight quantity equal to or higher than 15% by weight with respect to the whole block copolymer, and 2) at least one vinyl copolymer block containing epoxy groups so that there is from 0.7% to 19% by weight of oxirane oxygen calculated on the total of block copolymer; and b) from 0.03 phr by weight to 10 phr by weight, calculated on the basis of component (a), of at least one halogenated flame retardant.

Abstract: The present invention relates to a concentrated polymeric composition which comprises: a) vinyl aromatic polymers and/or copolymers in an amount ranging from 10% to 90% by weight, calculated with respect to the overall composition, with respect to the overall composition, b) at least one compound containing epoxy functional groups in an amount ranging from 0.01% to 5% by weight, calculated with respect to the overall composition, with respect to the overall composition, c) at least one infrared absorbing agent, in an amount ranging from 10% to 90% by weight, calculated with respect to the overall composition, with respect to the overall composition.

Abstract: Process for the preparation of beads of expandable vinyl aromatic polymers by means of polymerization in aqueous suspension, which comprises polymerizing at least one vinyl aromatic monomer in aqueous suspension in the presence of a peroxide initiator system, active at a temperature higher than 800 C, an expanding agent, and in the presence of: —an amide having the general formula R1CONHCH2—CH2NHCOR2 (I) a flame retardant system comprising a brominated additive with a bromine content higher than 30% by weight.

Abstract: Expandable granulates, having compositions based on vinyl-aromatic polymers, including: a) 65-99.8% by weight of a copolymer obtained by polymerizing 85-100% by weight of one or more vinyl-aromatic monomers and 0-15% by weight of an ?-alkylstyrene in which the alkyl group contains from 1 to 4 carbon atoms; b) 0.01-20% by weight, calculated with respect to the polymer (a), of a carbon black having an average diameter ranging from 10 to 1000 nm and a surface area ranging from 5 to 200 m2/g; c) 0.01-5% by weight, calculated with respect to the polymer (a), of c1) oxides and sulfates and lamellar dichalcogenides of metals; or c2) oxides and sulfates of metals, or c3) lamellar dichalcogenides of metals; or c4) oxides of metals; or c5) sulfates and lamellar dichalcogenides of metals; or c6) sulfates of metals; d) at least one of the following additives d1) and d2): d1) 0.01-5% by weight, calculated with respect to the polymer (a), of graphite having an average diameter ranging from 0.5 to 50 ?m; d2) 0.

Abstract: Compositions based on self-extinguishing expandable vinyl aromatic polymers in granules comprising: a. a polymeric matrix and, homogeneously englobed in the polymeric matrix, b. 3-10% by weight, calculated with respect to the polymer (a), of an expanding system; c. 0.005-5% by weight, calculated with respect to the polymer (a), of a brominated flame-retardant agent; d. 0.001-2% by weight, calculated with respect to the polymer (a), of a synergic additive; e. 0.005-5% by weight, calculated with respect to the polymer (a), of at least one stabilizing additive selected from: i. pyrophosphates of alkaline or alkaline earth metals, an ammonium group or a unit deriving from melamine; ii. melamine polyphosphate; iii. partially or completely salified polycarboxylic acids; iv. citrates of alkaline or alkaline earth metals; v. polyfunctional alcohols with 2 or more alcohol functions; vi. esters of poly-functional alcohols.

Abstract: Expandable particle composite material suitable for the preparation of expanded materials having a density lower than 40 g/l and a content of closed cells of at least 60%, including heterophase cavities and/or heterophase domains, whose matrix is a synthetic thermoplastic resin having at least 60% by weight of a vinyl aromatic polymer and in which an expanding system is contained, together with a heterogeneously distributed graphite material, having a graphitization degree, calculated by means of the Maire and Mering formula, of at least 0.2.

Abstract: Process for the preparation of beads of expandable vinyl aromatic polymers by means of polymerization in aqueous suspension, which comprises polymerizing at least one vinyl aromatic monomer in aqueous suspension in the presence of a peroxide initiator system, active at a temperature higher than 800 C, an expanding agent, and in the presence of:—an amide having the general formula R1CONHCH2—CH2NHCOR2 (I) a flame retardant system comprising a brominated additive with a bromine content higher than 30% by weight.

Abstract: Thermo-insulating expanded articles having a density ranging from 5 to 50 g/l, which can be obtained from particle compositions of expandable vinyl aromatic polymers comprising: a. 10-90% by weight of beads/granules of expandable vinyl aromatic polymer pigmented with an athermanous material comprising from 0.05 to 25% by weight of coke in particle form with an average particle diameter (size) ranging from 0.5 to 100 ?m; b. 90-10% by weight of beads/granules of essentially white expandable vinyl aromatic polymer.

Abstract: A thermoinsulating expanded article with improved resistance to solar irradiation, which includes an expanded polymeric matrix, obtained by the expansion and sintering of beads or granules containing a vinyl aromatic (co)polymer, where the interior of the beads or granules contains a homogeneously dispersed filler containing at least one athermanous material selected from coke, graphite and carbon black and optionally contains an active inorganic additive within the wave-lengths ranging from 100 to 20,000 cm?1. The polymeric matrix contains a copolymer of styrene and at least one vinyl aromatic comonomer substituted in the ring or on the vinyl group, a mixture of polystyrene and up to 10% by weight, with respect to the mixture, of a thermoplastic polymer compatible with polystyrene and having a Tg>100° C., or both.

Abstract: Process for improving the insulating capacity of expanded vinyl aromatic which includes: 1) preparing beads of expandable vinyl aromatic polymers containing 1-10% by weight, calculated with respect to the polymer, of an expanding agent englobed in the polymeric matrix, and 0.01-25% by weight, calculated with respect to the polymer, of an athermanous additive comprising carbon black homogeneously distributed in the polymeric matrix; 2) treating the surface of the beads, before deposition of the coating, with a liquid lubricating agent; and 3) thermally treating the beads with hot air at a temperature ranging from 30 to 60° C.

Abstract: Expandable vinyl aromatic polymers comprising: —a matrix obtained by polymerizing 50-100% by weight of one or more vinyl aromatic monomers and 0-50% by weight of at least one co-polymerizable monomer; —1-10% by weight, calculated with respect to polymer (a), of an expanding agent embedded in the polymeric matrix; 0-25% by weight, calculated with respect to polymer (a), of a filler comprising carbon coke having an average diameter of between 0.5 and 100 ?m, with a surface area, measured according to ASTM D-3037/89, ranging from 5 to 200 m2/g; 0.05-10% by weight, calculated with respect to polymer (a), of expanded graphite in particle form, with a particle average diameter (size) ranging from 1 to 30 ?m, a surface area, measured according to ASTM D-3037/89, ranging from 5 to 500 m2/g and a density ranging from 1.5 to 5 g/cm3.

Abstract: Expandable vinyl aromatic polymers which comprise: a matrix obtained by polymerizing 50-100% by weight of one or more vinyl aromatic monomers and 0-50% by weight of at least one copolymer izable monomer; 1-10% by weight, calculated with respect to the polymer (a), of an expanding agent englobed in the polymeric matrix; 0.05-25% by weight, calculated with respect to the polymer (a), of a filler comprising coke with a surface area, measured according to ASTM D-3037/89, ranging from 5 to 50 m2/g.