Abstract: The invention relates to a non-aqueous liquid coating composition comprising a) a polyol, b) a polyisocyanate crosslinker c) one or more thiol-functional compounds, d) a metal-based curing catalyst for catalyzing the addition reaction of isocyanate groups and hydroxyl groups, e) a base having a pKa value of at least 7, and which base does not react with isocyanate groups in a way wherein the basicity is reduced, and f) one or more acid group-containing compounds, wherein the one or more thiol-functional compounds are present in an amount to provide a molar ratio of thiol groups over the metal atoms of the metal-based curing catalyst of 1 or higher, and wherein the base is present in a molar amount lower than the molar amount of thiol groups, and wherein the molar ratio of acid groups and base groups is 1:1 or higher.

Abstract: The invention relates to a coating composition comprising a) a polyacrylate polyol obtainable by polymerization of olefinically unsaturated monomers wherein at least 40 weight-% of the monomers comprises linear or branched alk(en)yl or alk(en)ylene groups having at least 4 carbon atoms; b) a polyester polyol obtainable by esterification of building blocks having ester-forming functional groups wherein at least 30 weight-% of the building blocks comprises linear or branched alk(en)yl or alk(en)ylene groups with at least 4 carbon atoms per ester-forming functional group, the polyester polyol having a hydroxy value above 280 mg KOH/g and a hydroxy functionality of at least 2, and c) an isocyanate-functional crosslinker.

Abstract: The invention relates to a coating composition comprising a polyisocyanate, a polyol, a metal based catalyst for the addition reaction of isocyanate groups and hydroxyl groups, a thiol-functional compound, and a carboxylic acid wherein the carbonyl group of the carboxylic acid is in conjugation with a ?-electron system.

Abstract: The invention relates to a coating composition comprising a) a polyacrylate polyol obtainable by polymerization of olefinically unsaturated monomers wherein at least 40 weight-% of the monomers comprises linear or branched alk(en)yl or alk(en)ylene groups having at least 4 carbon atoms; b) a polyester polyol obtainable by esterification of building blocks having ester-forming functional groups wherein at least 30 weight-% of the building blocks comprises linear or branched alk(en)yl or alk(en)ylene groups with at least 4 carbon atoms per ester-forming functional group, the polyester polyol having a hydroxy value above 280 mg KOH/g and a hydroxy functionality of at least 2, and c) an isocyanate-functional crosslinker.