Patents by Inventor Apostolos Krallis

Apostolos Krallis has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20220234021
    Abstract: A process for the production of polyolefins comprising: feeding a slurry comprising at least one polymerization catalyst, at least one carrier liquid, first olefin monomer(s) and optionally at least one first comonomer into at least one loop reactor; polymerizing the first olefin monomer(s) and optionally the at least one first comonomer yielding a first polyolefin; withdrawing the first polyolefin from the loop reactor; feeding the first polyolefin to a gas-solids olefin polymerization reactor, wherein the gas-solids olefin polymerization reactor comprises: a top zone; a middle zone, which comprises a top end in direct contact with said top zone and which is located below said top zone, the middle zone having a generally cylindrical shape; and a bottom zone, which is in direct contact with a bottom end of the middle zone and which is located below the middle zone; introducing a fluidization gas stream into the bottom zone of the gas-solids olefin polymerization reactor; polymerizing second olefin monomer(s)
    Type: Application
    Filed: April 6, 2020
    Publication date: July 28, 2022
    Inventors: Apostolos Krallis, Vasileios Kanellopoulos, Erno Elovainio, Klaus Nyfors, Joana Kettner
  • Patent number: 11220558
    Abstract: A method and arrangement of producing polymer comprising polymerizing in reactor having a top zone having a generally conical shape, a middle zone in direct contact with and below said top zone having a generally cylindrical shape, a bottom zone having a generally conical shape thereby polymerizing at least one olefin, in the presence of a polymerization catalyst and fluidization gas to obtain (i) a first stream comprising fluidization gas and particles of olefin polymer, (ii) a second stream comprising fluidization gas and agglomerates of olefin polymer, (iii) a third olefin polymer product stream, —directing the first stream comprising fluidization gas and olefin polymer particles to a series of at least three cyclones connected to the fluidized bed reactor, —separating agglomerates of olefin polymer from the second stream, withdrawing from the fluidized bed polymerization reactor the third olefin polymer product stream.
    Type: Grant
    Filed: June 15, 2018
    Date of Patent: January 11, 2022
    Assignee: BOREALIS AG
    Inventors: Vasileios Kanellopoulos, Apostolos Krallis, Klaus Nyfors, Erno Elovainio
  • Patent number: 11208507
    Abstract: An olefin polymerisation method and arrangement comprising polymerising at least one olefin in gas phase in a fluidised bed in the presence of an olefin polymerisation catalyst in a polymerisation reactor having a vertical body; a generally conical downwards tapering bottom zone; a generally cylindrical middle zone, above and connected to said bottom zone; and a generally conical upwards tapering top zone above and connected to said middle zone wherein (i) fluidisation gas is introduced to the bottom zone of the reactor from where it passes upwards through the reactor; (ii) the fluidisation gas is withdrawn from the top zone of the reactor; (iii) a fluidised bed is formed within the reactor where the growing polymer particles are suspended in the upwards rising gas stream; and wherein the polymerisation reactor has an operating temperature set point and which reactor comprises at least one temperature measurement sensor, wherein a temperature difference (DT) between the temperature measurement sensor (Tm), an
    Type: Grant
    Filed: June 15, 2018
    Date of Patent: December 28, 2021
    Assignee: Borealis AG
    Inventors: Apostolos Krallis, Vasileios Kanellopoulos
  • Patent number: 11111324
    Abstract: The present invention relates to a process and apparatus for withdrawing polymer agglomerates from a fluidised bed polymerisation reactor, the polymerisation reactor comprising a bottom zone having a generally conical shape and no fluidisation grid. The agglomerates are withdrawn by using an agglomerate trap below the bottom zone. A value of a process variable indicative of the content of agglomerates in the agglomerate trap is measured and the opening time of the valves transferring polymer to and from the agglomerate trap is adjusted based on the measured value.
    Type: Grant
    Filed: December 15, 2016
    Date of Patent: September 7, 2021
    Assignee: Borealis AG
    Inventors: Mohammad Al-Haj Ali, Vasileios Kanellopoulos, Apostólos Krallis, Klaus Nyfors, Pablo Ivan Aguayo Arellano, Gunter Weickert, Eric-Jan Prinsen
  • Publication number: 20210269560
    Abstract: The present invention is concerned with a process for polymerizing ethylene or copolymerizing ethylene and at least one alpha-olefin comonomer in the presence of a supported polymerization catalyst in a multi-stage process in which the last polymerization stage is a gas phase reactor, the use of said process for reducing particle carry-over in the last polymerization stage and the use of a supported polymerization catalyst with a certain median particle size to polymerize an ethylene homo- or copolymer in said multi-stage process with a span of its particle size distribution which can be predicted from the median particle size of the catalyst.
    Type: Application
    Filed: August 1, 2019
    Publication date: September 2, 2021
    Applicant: BOREALIS AG
    Inventors: Apostolos KRALLIS, Vasileios KANELLOPOULOS, Pascal CASTRO, Vuokko OJANPERÄ, Kumudini JAYARATNE
  • Publication number: 20210130508
    Abstract: The present invention relates to a process for polymerizing at least one olefin in gas phase in a fluidized bed in a polymerization reactor having a top zone of a generally conical shape as such that the equivalent cross-sectional diameter is monotonically decreasing with respect to the flow direction of the fluidization gas, a middle zone in direct contact with and below said top zone of a generally cylindrical shape and a bottom zone in direct contact and below said middle zone and of a generally conical shape as such that the equivalent cross-sectional diameter is monotonically increasing with respect to the flow direction of the fluidization gas, comprising the steps of: a) introducing a first stream of fluidization gas into the bottom zone; b) polymerizing at least one olefin in the presence of a polymerization catalyst in the fluidized bed formed by particles of a polymer of the at least one olefin suspended in an upwards flowing stream of the fluidization gas in the middle zone; c) withdrawing a second
    Type: Application
    Filed: May 29, 2019
    Publication date: May 6, 2021
    Inventors: Apostolos Krallis, Vasileios Kanellopoulos, Erno Elovainio, Klaus Nyfors
  • Patent number: 10988555
    Abstract: The present invention is directed to a process for separating an olefin copolymer from volatile gases using a flash separator. The flash separator can be used with a solution or high pressure process. The mass transport of volatile gases from the viscous polymer melt is increased.
    Type: Grant
    Filed: September 18, 2017
    Date of Patent: April 27, 2021
    Assignee: BOREALIS AG
    Inventors: Vasileios Kanellopoulos, Mohammad Al-Haj Ali, Apostolos Krallis
  • Publication number: 20200369806
    Abstract: The present invention relates to a process and apparatus for withdrawing polymer agglomerates from a fluidised bed polymerisation reactor, the polymerisation reactor comprising a bottom zone having a generally conical shape and no fluidisation grid. The agglomerates are withdrawn by using an agglomerate trap below the bottom zone. A value of a process variable indicative of the content of agglomerates in the agglomerate trap is measured and the opening time of the valves transferring polymer to and from the agglomerate trap is adjusted based on the measured value.
    Type: Application
    Filed: December 15, 2016
    Publication date: November 26, 2020
    Inventors: Mohammad AL-HAJ ALI, Vasileios KANELLOPOULOS, Apostolos KRALLIS, Klaus NYFORS, Pablo Ivan AGUAYO ARELLANO, Gunter Weickert, Eric-Jan PRINSEN
  • Publication number: 20200291143
    Abstract: An olefin polymerisation method and arrangement comprising polymerising at least one olefin in gas phase in a fluidised bed in the presence of an olefin polymerisation catalyst in a polymerisation reactor having a vertical body; a generally conical downwards tapering bottom zone; a generally cylindrical middle zone, above and connected to said bottom zone; and a generally conical upwards tapering top zone above and connected to said middle zone wherein (i) fluidisation gas is introduced to the bottom zone of the reactor from where it passes upwards through the reactor; (ii) the fluidisation gas is withdrawn from the top zone of the reactor; (iii) a fluidised bed is formed within the reactor where the growing polymer particles are suspended in the upwards rising gas stream; and wherein the polymerisation reactor has an operating temperature set point and which reactor comprises at least one temperature measurement sensor, wherein a temperature difference (DT) between the temperature measurement sensor (Tm), an
    Type: Application
    Filed: June 15, 2018
    Publication date: September 17, 2020
    Inventors: Apostolos Krallis, Vasileios Kanellopoulos
  • Patent number: 10676544
    Abstract: A process for polymerising alpha-olefin monomers in a loop reactor comprising the steps of introducing a main feed stream (2) comprising at least one alpha-olefin monomer into the loop reactor (1); introducing a polymerisation catalyst into the loop reactor (1); polymerising the at least one alpha-olefin monomer in the presence of the polymerisation catalyst in the loop reactor (1) to produce a slurry comprising polyolefin particles; withdrawing an outlet stream (4) comprising at least a portion of the slurry from the loop reactor (1); adding a first feed stream (9) comprising the at least one alpha-olefin monomer and/or hydrogen to the outlet stream (4) to form a concentrator inlet stream (8); introducing the concentrator inlet stream (8) into a concentrator (5); withdrawing from the concentrator (5) an overflow stream (6) comprising the polyolefin particles, wherein the concentration of the polyolefin particles in the overflow stream (6) is smaller than in the concentrator inlet stream (8); withdrawing from
    Type: Grant
    Filed: November 22, 2016
    Date of Patent: June 9, 2020
    Assignee: BOREALIS AG
    Inventors: Kauno Alastalo, Mohammad Al-Haj Ali, Vasileios Kanellopoulos, Apostolos Krallis
  • Publication number: 20200123279
    Abstract: A method and arrangement of producing polymer comprising polymerizing in reactor having a top zone having a generally conical shape, a middle zone in direct contact with and below said top zone having a generally cylindrical shape, a bottom zone having a generally conical shape thereby polymerizing at least one olefin, in the presence of a polymerization catalyst and fluidization gas to obtain (i) a first stream comprising fluidization gas and particles of olefin polymer, (ii) a second stream comprising fluidization gas and agglomerates of olefin polymer, (iii) a third olefin polymer product stream—directing the first stream comprising fluidization gas and olefin polymer particles to a series of at least three cyclones connected to the fluidized bed reactor—separating agglomerates of olefin polymer from the second stream, withdrawing from the fluidized bed polymerization reactor the third olefin polymer product stream.
    Type: Application
    Filed: June 15, 2018
    Publication date: April 23, 2020
    Inventors: Vasileios Kanellopoulos, Apostolos Krallis, Klaus Nyfors, Erno Elovainio
  • Publication number: 20190270830
    Abstract: The present invention is directed to a process for separating an olefm copolymer from volatile gases using a flash separator. The flash separator can be used with a solution or high pressure process. The mass transport of volatile gases from the viscous polymer melt is increased.
    Type: Application
    Filed: September 18, 2017
    Publication date: September 5, 2019
    Inventors: Vasileios Kanellopoulos, Mohammad Al-Haj Ali, Apostolos Krallis
  • Patent number: 10358507
    Abstract: The present invention is directed to a process for separating hydrocarbons from a solution comprising a polymer. The process comprises the steps of: (A) withdrawing a solution stream comprising the polymer from a first vessel; (B) passing the solution stream into a flash vessel; (C) spraying the solution stream into droplets in the first flash vessel thereby establishing a stream of droplets within the flash vessel. The solution forms a downwards falling film within the flash vessel.
    Type: Grant
    Filed: March 24, 2016
    Date of Patent: July 23, 2019
    Assignee: BOREALIS AG
    Inventors: Mohammad Al-Haj Ali, Vasileios Kanellopoulos, Apostolos Krallis, Henry Sleijster, Samuli Zitting
  • Publication number: 20180346612
    Abstract: The present invention is directed to a process for separating hydrocarbons from a solution comprising a polymer. The process comprises the steps of: (A) withdrawing a solution stream comprising the polymer from a first vessel; (B) passing the solution stream into a flash vessel; (C) spraying the solution stream into droplets in the first flash vessel thereby establishing a stream of droplets within the flash vessel. The solution forms a downwards falling film within the flash vessel.
    Type: Application
    Filed: March 24, 2016
    Publication date: December 6, 2018
    Inventors: Mohammad AL-HAJ ALI, Vasileios KANELLOPOULOS, Apostolos KRALLIS, Henry SLEIJSTER, Samuli ZITTING
  • Publication number: 20180327518
    Abstract: A process for polymerising alpha-olefin monomers in a loop reactor comprising the steps of introducing a main feed stream (2) comprising at least one alpha-olefin monomer into the loop reactor (1); introducing a polymerisation catalyst into the loop reactor (1); polymerising the at least one alpha-olefin monomer in the presence of the polymerisation catalyst in the loop reactor (1) to produce a slurry comprising polyolefin particles; withdrawing an outlet stream (4) comprising at least a portion of the slurry from the loop reactor (1); adding a first feed stream (9) comprising the at least one alpha-olefin monomer and/or hydrogen to the outlet stream (4) to form a concentrator inlet stream (8); introducing the concentrator inlet stream (8) into a concentrator (5); withdrawing from the concentrator (5) an overflow stream (6) comprising the polyolefin particles, wherein the concentration of the polyolefin particles in the overflow stream (6) is smaller than in the concentrator inlet stream (8); withdrawing from
    Type: Application
    Filed: November 22, 2016
    Publication date: November 15, 2018
    Inventors: Kauno Alastalo, Mohammad Al-Haj Ali, Vasileios Kanellopoulos, Apostolos Krallis
  • Patent number: 9790290
    Abstract: An olefin polymerization process comprising polymerizing olefins in gas phase in a fluidized bed in the presence of an olefin polymerization catalyst in a polymerization reactor having a vertical body; a generally conical downwards tapering bottom zone; a generally cylindrical middle zone having a height to diameter ratio L/D of at least 4, above and connected to said bottom zone; and a generally conical upwards tapering top zone above and connected to said middle zone wherein (i) fluidization gas is introduced to the bottom zone of the reactor from where it passes upwards through the reactor; (ii) the fluidization gas is withdrawn from the top zone of the reactor, filtered, compressed, cooled and returned into the bottom zone of the reactor; (iii) a fluidized bed is formed within the reactor where the growing polymer particles are suspended in the upwards rising gas stream; and (iv) there is no fluidization grid in the reactor; characterized in that the gas velocity is maintained in the reactor such that NBr
    Type: Grant
    Filed: February 27, 2015
    Date of Patent: October 17, 2017
    Assignee: Borealis AG
    Inventors: Vasileios Kanellopoulos, Apostolos Krallis, Mohammad Al-Haj Ali, Ravindra Tupe
  • Patent number: 9539556
    Abstract: The present invention is directed to a process for polymerizing olefins in gas phase in a fluidized bed reactor having a vertical body, a generally conical downwards tapering bottom zone, a generally cylindrical middle zone above the bottom zone, and a generally conical upwards tapering top zone above the middle zone. The fluidization gas is withdrawn from the top zone of the reactor, compressed and cooled so that a part of the fluidization gas condenses and then introduced to the bottom zone of the reactor. The bed is thus cooled upon evaporation of the liquid. There is no fluidization grid in the reactor.
    Type: Grant
    Filed: February 27, 2015
    Date of Patent: January 10, 2017
    Assignee: BOREALIS AG
    Inventors: Mohammad Al-Haj Ali, Apostolos Krallis, Vasileios Kanellopoulos
  • Publication number: 20160355613
    Abstract: An olefin polymerization process comprising polymerizing olefins in gas phase in a fluidized bed in the presence of an olefin polymerization catalyst in a polymerization reactor having a vertical body; a generally conical downwards tapering bottom zone; a generally cylindrical middle zone having a height to diameter ratio L/D of at least 4, above and connected to said bottom zone; and a generally conical upwards tapering top zone above and connected to said middle zone wherein (i) fluidization gas is introduced to the bottom zone of the reactor from where it passes upwards through the reactor; (ii) the fluidization gas is withdrawn from the top zone of the reactor, filtered, compressed, cooled and returned into the bottom zone of the reactor; (iii) a fluidized bed is formed within the reactor where the growing polymer particles are suspended in the upwards rising gas stream; and (iv) there is no fluidization grid in the reactor; characterized in that the gas velocity is maintained in the reactor such that NBr
    Type: Application
    Filed: February 27, 2015
    Publication date: December 8, 2016
    Inventors: Vasileios Kanellopoulos, Apostolos Krallis, Mohammad Al-Haj Ali, Ravindra Tupe
  • Publication number: 20160354747
    Abstract: The present invention is directed to a process for polymerizing olefins in gas phase in a fluidized bed reactor having a vertical body, a generally conical downwards tapering bottom zone, a generally cylindrical middle zone above the bottom zone, and a generally conical upwards tapering top zone above the middle zone. The fluidization gas is withdrawn from the top zone of the reactor, compressed and cooled so that a part of the fluidization gas condenses and then introduced to the bottom zone of the reactor. The bed is thus cooled upon evaporation of the liquid. There is no fluidization grid in the reactor.
    Type: Application
    Filed: February 27, 2015
    Publication date: December 8, 2016
    Inventors: Mohammad Al-Haj Ali, Apostolos Krallis, Vasileios Kanellopoulos