Patents by Inventor Armenag Dekmezian

Armenag Dekmezian has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9644092
    Abstract: A heterogeneous in-situ polymer blend comprising a continuous phase comprising a polypropylene having a crystallinity of at least 30% and a melting point temperature Tm greater than 130° C., and a heat of fusion ?Hf greater than 65 J/g; and a dispersed phase comprising particles of an elastomeric copolymer dispersed in the continuous phase and having an average particle size of less than 5 micron, the elastomeric copolymer comprising ethylene units and 0.001 to 5 wt % diene by weight of the copolymer, and having a crystallinity of less than 20% and being at least partially cross-linked such that the degree of cross-link is at least 20%.
    Type: Grant
    Filed: June 26, 2014
    Date of Patent: May 9, 2017
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag Dekmezian, Aspy K. Mehta, Sunny Jacob, Andrew G. Narvaez, Jr., Pradeep P. Shirodkar, Weiqing Weng
  • Publication number: 20140309359
    Abstract: A heterogeneous in-situ polymer blend comprising a continuous phase comprising a polypropylene having a crystallinity of at least 30% and a melting point temperature Tm greater than 130° C., and a heat of fusion ?Hf greater than 65 J/g; and a dispersed phase comprising particles of an elastomeric copolymer dispersed in the continuous phase and having an average particle size of less than 5 micron, the elastomeric copolymer comprising ethylene units and 0.001 to 5 wt % diene by weight of the copolymer, and having a crystallinity of less than 20% and being at least partially cross-linked such that the degree of cross-link is at least 20%.
    Type: Application
    Filed: June 26, 2014
    Publication date: October 16, 2014
    Inventors: Peijun Jiang, Armenag Dekmezian, Aspy K. Mehta, Sunny Jacob, Andrew G. Narvaez, Jr., Pradeep P. Shirodkar, Weiqing Weng
  • Patent number: 8227547
    Abstract: This invention relates to a foamable blend comprising an in-reactor polymer blend comprising: (a) a first propylene polymer component comprising 90 to 100 wt % propylene and from 0 to less than 10 wt % comonomer, said first propylene component having a Tm of 120° C. or more; and (b) a second propylene polymer component comprising from 30 to 90 wt % propylene and 70 to 10 wt % comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend, prior to combination with a foaming agent, has: (i) a Tm of at least 120° C.; (ii) a MFR of 10 dg/min or more; (iii) a tensile strength of at least 8 MPa; (iv) an elongation at break of at least 200%, and (v) a ratio of elongational viscosity at break to linear viscosity of 5 or more when the elongational viscosity is measured at a strain rate of 1 sec?1 and temperature of 180° C.
    Type: Grant
    Filed: January 7, 2011
    Date of Patent: July 24, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Abdelhadi Sahnoune, Armenag Dekmezian
  • Publication number: 20110118370
    Abstract: This invention relates to a foamable blend comprising an in-reactor polymer blend comprising: (a) a first propylene polymer component comprising 90 to 100 wt % propylene and from 0 to less than 10 wt % comonomer, said first propylene component having a Tm of 120° C. or more; and (b) a second propylene polymer component comprising from 30 to 90 wt % propylene and 70 to 10 wt % comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend, prior to combination with a foaming agent, has: (i) a Tm of at least 120° C.; (ii) a MFR of 10 dg/min or more; (iii) a tensile strength of at least 8 MPa; (iv) an elongation at break of at least 200%, and (v) a ratio of elongational viscosity at break to linear viscosity of 5 or more when the elongational viscosity is measured at a strain rate of 1 sec?1 and temperature of 180° C.
    Type: Application
    Filed: January 7, 2011
    Publication date: May 19, 2011
    Inventors: Peijun JIANG, Abdelhadi Sahnoune, Armenag Dekmezian
  • Publication number: 20070293640
    Abstract: This invention relates to a polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 15 mole % of ethylene, where the polymer has: a) a Dot T-Peel of 1 Newton or more; and b) a branching index (g?) of 0.95 or less measured at the Mz of the polymer; c) an Mw of 100,000 or less. This invention also relates a polymer comprising one or more C3 to C40 olefins where the polymer has: a) a Dot T-Peel of 1 Newton or more on Kraft paper; b) a branching index (g?) of 0.95 or less measured at the Mz of the polymer; c) a Mw of 10,000 to 100,000; and d) a heat of fusion of 1 to 70 J/g. This invention also relates a polymer comprising one or more C3 to C40 olefins where the polymer has: a) a Dot T-Peel of 1 Newton or more on Kraft paper; b) a branching index (g?) of 0.98 or less measured at the Mz of the polymer; c) a Mw of 10,000 to 60,000; d) a heat of fusion of 1 to 50 J/g.
    Type: Application
    Filed: August 2, 2007
    Publication date: December 20, 2007
    Inventors: Peijun Jiang, Armenag Dekmezian, Jo Ann Canich, Charles Sims, Ramin Abhari, Cesar Garcia-Franco, David Johnsrud
  • Publication number: 20060293462
    Abstract: A heterogeneous polymer blend comprises a continuous phase comprising a thermoplastic first polymer having a crystallinity of at least 30% and a dispersed phase comprising particles of a second polymer different from the first polymer dispersed in said continuous phase and having an average particle size of less than 5 micron. The second polymer has a crystallinity of less than 20% and is at least partially cross-linked such that no more than about 50 wt % of the second polymer is extractable in cyclohexane at 23° C.
    Type: Application
    Filed: December 7, 2005
    Publication date: December 28, 2006
    Inventors: Sunny Jacob, Peijun Jiang, Aspy Mehta, Pradeep Shirodkar, Armenag Dekmezian
  • Publication number: 20060293455
    Abstract: A heterogeneous polymer blend comprises a continuous phase comprising a thermoplastic first polymer having a crystallinity of at least 30% and a dispersed phase comprising particles of a second polymer different from the first polymer dispersed in said continuous phase, the second polymer having a crystallinity of less than 20% and being at least partially cross-linked, and the average particle size of the particles of the second polymer being less than 1 micron.
    Type: Application
    Filed: June 16, 2006
    Publication date: December 28, 2006
    Inventors: Peijun Jiang, Armenag Dekmezian, Aspy Mehta, Sunny Jacob, Andrew Narvaez, Pradeep Shirodkar, Weiqing Weng
  • Publication number: 20060293461
    Abstract: In a process for producing a heterogeneous polymer blend, at least one first monomer is polymerized in a first reaction zone in the presence of a supported catalyst to produce a thermoplastic first polymer having a crystallinity of at least 30%. At least part of said first polymer is then contacted with at least one second monomer and at least one polyene in a second reaction zone under conditions sufficient to polymerize said second monomer to produce a second polymer having a crystallinity of less than 20%. The second polymer is at least partially cross-linked in the second reaction zone such that at least a fraction of the second polymer is insoluble in xylene and such that the first and second polymers form different phases of the blend.
    Type: Application
    Filed: December 7, 2005
    Publication date: December 28, 2006
    Inventors: Peijun Jiang, Aspy Mehta, Armenag Dekmezian, Sunny Jacob, Andrew Narvaez, Pradeep Shirodkar
  • Publication number: 20060293460
    Abstract: A heterogeneous polymer blend comprises a dispersed phase comprising a thermoplastic first polymer having a crystallinity of at least 30% and a continuous phase comprising a second polymer different from the first polymer. The second polymer has a crystallinity of less than 20% and is at least partially cross-linked.
    Type: Application
    Filed: December 7, 2005
    Publication date: December 28, 2006
    Inventors: Sunny Jacob, Peijun Jiang, Aspy Mehta, Pradeep Shirodkar, Armenag Dekmezian
  • Publication number: 20060293453
    Abstract: A homogeneous polymer blend comprises a thermoplastic first polymer having a crystallinity of at least 30%; and a second polymer having a crystallinity of more than 5% and being at least partially cross-linked.
    Type: Application
    Filed: December 7, 2005
    Publication date: December 28, 2006
    Inventors: Peijun Jiang, Sunny Jacob, Pradeep Shirodkar, Armenag Dekmezian, Aspy Mehta
  • Patent number: 7101936
    Abstract: A method of lowering MFR response of a high-melt-flow-rate-polymer-producing metallocene catalyst is provided. The method includes contacting the metallocene catalyst with a sufficient quantity of ?,?-diene monomer such that when the catalyst composition is contacted with polymerizable reactants under suitable polymerization conditions, the resulting polymer has an MFR rate in the range of 0.1 to 1000. Hydrogen and ethylene may also be present in the polymerization. Additionally a catalyst composition is provided which includes a high-melt-flow-rate-polymer-producing metallocene catalyst and a sufficient quantity of ?,?-diene monomers such that when the catalyst composition is contacted with a monomer under polymerization conditions, the resulting polymer has an MFR rate in the range of 0.1 to 1000.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: September 5, 2006
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Weiqing Weng, Aspy K. Mehta, Pawan K. Agarwal, Armenag Dekmezian
  • Publication number: 20050065298
    Abstract: Linear low density polyethylenes (LLDPEs) that have relatively high melt index ratios (MIR) and relatively high melt strength (MS) are described. This combination of melt properties is achieved by a substantially non-blended LLDPE. Catalysts used to produce these polyethylenes are generally a blend of bridged bisindenyl zirconocene dichlorides, where one zirconocene contains saturated indenyls and the other unsaturated indenyls.
    Type: Application
    Filed: September 28, 2004
    Publication date: March 24, 2005
    Inventors: Armenag Dekmezian, Natalie Merrill
  • Patent number: 6780936
    Abstract: This invention relates to compositions derived from polyolefins combined with a polymeric nucleating agent. The nucleating agent is specifically a diene-propylene copolymer.
    Type: Grant
    Filed: February 11, 2003
    Date of Patent: August 24, 2004
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Pawan K. Agarwal, Armenag Dekmezian, Aspy K. Mehta, Weiqing Weng
  • Publication number: 20040157999
    Abstract: This invention relates to compositions derived from polyolefins combined with polymeric nucleating agent. The nucleating agent is specifically a diene-propylene copolymer.
    Type: Application
    Filed: February 11, 2003
    Publication date: August 12, 2004
    Inventors: Pawan K. Agarwal, Armenag Dekmezian, Aspy K. Mehta, Weiqing Weng
  • Publication number: 20040054098
    Abstract: A method of lowering MFR response of a high-melt-flow-rate-polymer-producing metallocene catalyst is provided. The method includes contacting the metallocene catalyst with a sufficient quantity of &agr;,&ohgr;-diene monomer such that when the catalyst composition is contacted with polymerizable reactants under suitable polymerization conditions, the resulting polymer has an MFR rate in the range of 0.1 to 1000. Hydrogen and ethylene may also be present in the polymerization. Additionally a catalyst composition is provided which includes a high-melt-flow-rate-polymer-producing metallocene catalyst and a sufficient quantity of &agr;,&ohgr;-diene monomers such that when the catalyst composition is contacted with a monomer under polymerization conditions, the resulting polymer has an MFR rate in the range of 0.1 to 1000.
    Type: Application
    Filed: June 2, 2003
    Publication date: March 18, 2004
    Inventors: Weiqing Weng, Aspy K. Mehta, Pawan K. Agarwal, Armenag Dekmezian
  • Patent number: 5039614
    Abstract: An automated, on-line solvent elimination interface system is described for use in characterizing the Composition Distribution (CD) of unknown materials emerging from a fractionating unit or a process stream. Fractionated samples to be analyzed, such as a polymer, in highly diluted form in one or more solvents, are provided by a fractionation unit such as a gel permeation chromatograph (GPC), a high pressure liquid chromatograph (HPLC), or a field flow fractionator (FFF). A number of discharges of each particular fraction are supplied to individual collection units within the interface system under controlled conditions of flow rate, temperature and pressure (vacuum) such that the solvents are flash-evaporated at the collection unit. A sufficient solid residue is built up on the collection unit for analysis by, for example, a Fourier transform infrared (FTIR) analyzer.
    Type: Grant
    Filed: June 15, 1990
    Date of Patent: August 13, 1991
    Inventors: Armenag Dekmezian, Tetsuya Morioka