Patents by Inventor Armenag H. Dekmezian

Armenag H. Dekmezian has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10253174
    Abstract: A heterogeneous vulcanized polymer blend comprising a continuous phase comprising a thermoplastic polypropylene having a crystallinity of at least 30% and a dispersed phase comprising particles of an elastomeric copolymer dispersed in the continuous phase and having an average particle size of less than 5 micron. The elastomeric copolymer has a crystallinity of less than 20% and is at least partially cross-linked such that no more than about 80 wt % of the elastomeric copolymer is extractable in cyclohexane at 23° C.
    Type: Grant
    Filed: July 24, 2017
    Date of Patent: April 9, 2019
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sunny Jacob, Peijun Jiang, Aspy K. Mehta, Pradeep Shirodkar, Armenag H. Dekmezian
  • Publication number: 20180009976
    Abstract: A heterogeneous vulcanized polymer blend comprising a continuous phase comprising a thermoplastic polypropylene having a crystallinity of at least 30% and a dispersed phase comprising particles of an elastomeric copolymer dispersed in the continuous phase and having an average particle size of less than 5 micron. The elastomeric copolymer has a crystallinity of less than 20% and is at least partially cross-linked such that no more than about 80 wt % of the elastomeric copolymer is extractable in cyclohexane at 23° C.
    Type: Application
    Filed: July 24, 2017
    Publication date: January 11, 2018
    Inventors: Sunny Jacob, Peijun Jiang, Aspy K. Mehta, Pradeep Shirodkar, Armenag H. Dekmezian
  • Patent number: 9745461
    Abstract: A heterogeneous vulcanized polymer blend comprising a continuous phase comprising a thermoplastic polypropylene having a crystallinity of at least 30% and a dispersed phase comprising particles of an elastomeric copolymer dispersed in the continuous phase and having an average particle size of less than 5 micron. The elastomeric copolymer has a crystallinity of less than 20% and is at least partially cross-linked such that no more than about 80 wt % of the elastomeric copolymer is extractable in cyclohexane at 23° C.
    Type: Grant
    Filed: June 26, 2014
    Date of Patent: August 29, 2017
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sunny Jacob, Peijun Jiang, Aspy K. Mehta, Pradeep P. Shirodkar, Armenag H. Dekmezian
  • Publication number: 20140309358
    Abstract: A heterogeneous vulcanized polymer blend comprising a continuous phase comprising a thermoplastic polypropylene having a crystallinity of at least 30% and a dispersed phase comprising particles of an elastomeric copolymer dispersed in the continuous phase and having an average particle size of less than 5 micron. The elastomeric copolymer has a crystallinity of less than 20% and is at least partially cross-linked such that no more than about 80 wt % of the elastomeric copolymer is extractable in cyclohexane at 23° C.
    Type: Application
    Filed: June 26, 2014
    Publication date: October 16, 2014
    Inventors: Sunny Jacob, Peijun Jiang, Aspy K. Mehta, Pradeep P. Shirodkar, Armenag H. Dekmezian
  • Patent number: 8481647
    Abstract: This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3 wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%.
    Type: Grant
    Filed: December 19, 2011
    Date of Patent: July 9, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag H. Dekmezian, Kevin R. Squire, Cesar A. Garcia-Franco
  • Patent number: 8481646
    Abstract: This invention relates to the preparation of thermoplastic vulcanizates (TPVs) with unique morphological features, more specifically, this invention relates to a method for preparing TPV compositions wherein the mixing of plastomers and elastomers are carried out in solvent with curatives to induce cross-linking.
    Type: Grant
    Filed: February 23, 2011
    Date of Patent: July 9, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Weiqing Weng, Sunny Jacob, Peijun Jiang, Armenag H. Dekmezian, Aspy K. Mehta, James R. Ayers, David J. Lohse, Peter W. Manders, Palanisamy Arjunan
  • Patent number: 8436100
    Abstract: A homogeneous polymer blend comprises a thermoplastic first polymer having a crystallinity of at least 30%; and a second polymer having a crystallinity of more than 5% and being at least partially cross-linked.
    Type: Grant
    Filed: February 25, 2011
    Date of Patent: May 7, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Sunny Jacob, Aspy K. Mehta, Pradeep P. Shirodkar, Armenag H. Dekmezian, Palanisamy Arjunan
  • Publication number: 20130059981
    Abstract: This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3 wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%.
    Type: Application
    Filed: December 19, 2011
    Publication date: March 7, 2013
    Inventors: Peijun JIANG, Armenag H. Dekmezian, Kevin R. Squire, Cesar A. Garcia-Franco
  • Publication number: 20120149846
    Abstract: This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3 wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%.
    Type: Application
    Filed: December 19, 2011
    Publication date: June 14, 2012
    Inventors: Peijun JIANG, Armenag H. Dekmezian, Kevin R. Squire, Cesar A. Garcia-Franco
  • Publication number: 20120045600
    Abstract: This invention relates to the preparation of thermoplastic vulcanizates (TPVs) with unique morphological features, more specifically, this invention relates to a method for preparing TPV compositions wherein the mixing of plastomers and elastomers are carried out in solvent with curatives to induce cross-linking.
    Type: Application
    Filed: February 23, 2011
    Publication date: February 23, 2012
    Inventors: Weiqing Weng, Sunny Jacob, Peijun Jiang, Armenag H. Dekmezian, Aspy K. Mehta, James R. Ayers, David J. Lohse, Peter W. Manders, Palanisamy Arjunan
  • Patent number: 8106127
    Abstract: An in-reactor polymer blend comprises (a) a propylene-containing first polymer; and (b) an ethylene-containing second polymer such that the polymer blend comprises between about 50 wt % and about 80 wt % units derived from ethylene and between about 50 wt % and about 20 wt % units derived from propylene. The blend is substantially free of dienes and the content of ethylene in the second polymer in the form of ethylene-ethylene-ethylene triads is at least 40%. The second polymer contains at least 0.1 branch having 8 or more carbon atoms per 10,000 carbons. In addition, the blend has a strain hardening index of at least 1.8, a shear thinning slope in the plot of log(dynamic viscosity) versus log(frequency) of less than ?0.2 and exhibits at least two peaks when subjected to Differential Scanning Calorimetry (first melt) corresponding to a first melting point of at least 150° C. and a second melting point of at least 40° C.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: January 31, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Carlos U. De Gracia, Kevin R. Squire, Peijun Jiang, Armenag H. Dekmezian, Beverly J. Poole, Cesar A. Garcia-Franco
  • Patent number: 8101685
    Abstract: This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3, wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%. Specifically this invention relates to an in-reactor polymer blend comprising: (a) a first ethylene polymer comprising 90 to 100 wt % ethylene and from 0 to less than 10 wt % comonomer, said first ethylene polymer component having density of greater than 0.920 g/cm3, an Mw of 20,000 g/mol or more; and (b) a second ethylene polymer comprising from 70 to 90 wt % ethylene and 30 to 10 wt % comonomer, said second ethylene polymer having a density of 0.910 g/cm3 or less, wherein the polymer blend has: (a) a Tm of at least 100° C. over a density ranging from 0.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: January 24, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag H. Dekmezian, Kevin R. Squire, Cesar A. Garcia-Franco
  • Patent number: 8093335
    Abstract: This invention relates to a molded article comprising an in-reactor polymer blend comprising: (a) a first propylene polymer comprising 90 to 100 wt % propylene and from 0 to less than 10 wt % comonomer, said first propylene component having a Tm of 135° C. or more; and (b) a second propylene polymer comprising from 30 to 90 wt % propylene and 70 to 10 wt % comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend has: (a) a Tm of at least 135° C., (b) a melt flow rate of at least 70 dg/min, (c) a tensile strength of at least 8 MPa, (d) an elongation at break of at least 200%, (e) a tensile strength at break of 10 MPa or more, and (f) a GME 60280 scratch resistance of less than 1.2 DL at a scratching load of 5 Newtons.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: January 10, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag H. Dekmezian, Joseph Gustaaf M. Flendrig
  • Patent number: 8093336
    Abstract: A heterogeneous polymer blend comprises a dispersed phase comprising a thermoplastic first polymer having a crystallinity of at least 30% and a continuous phase comprising a second polymer different from the first polymer. The second polymer has a crystallinity of less than 20% and is at least partially cross-linked.
    Type: Grant
    Filed: April 20, 2011
    Date of Patent: January 10, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sunny Jacob, Peijun Jiang, Aspy K. Mehta, Pradeep P. Shirodkar, Armenag H. Dekmezian, Weiqing Weng
  • Patent number: 8038917
    Abstract: The present invention relates to a process for preparing a thermoplastic vulcanizate (TPV) comprising: contacting a thermoplastic polymer, a cross-linkable elastomer, at least one curative, and at least one cure activator in a solvent to form Composition A. The solvent is then removed, and thereafter the cross-linkable elastomer is at least partially cured. The average particle size of the cross-linkable elastomer is 10 microns or less after the solvent is removed.
    Type: Grant
    Filed: March 23, 2011
    Date of Patent: October 18, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Weiqing Weng, Sunny Jacob, Peijun Jiang, Armenag H. Dekmezian, Aspy K. Mehta, Peter W. Manders, Pradeep Shirodkar, Palanisamy Arjunan
  • Patent number: 8022142
    Abstract: An in-reactor polymer blend including (a) a propylene-containing first polymer; and (b) propylene-containing second polymer having a different crystallinity from the first polymer. The polymer blend has a melting temperature, Tm, of at least 135° C., a melt flow rate of at least 70 dg/min, a tensile strength of at least 8 MPa, an elongation at break of at least 300%.
    Type: Grant
    Filed: December 15, 2008
    Date of Patent: September 20, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag H. Dekmezian, Kevin R. Squire, Carlos U. de Gracia, Keith Edward Jolibois, Cesar A. Garcia-Franco, Ronald Raymond Thackston
  • Publication number: 20110196102
    Abstract: A heterogeneous polymer blend comprises a dispersed phase comprising a thermoplastic first polymer having a crystallinity of at least 30% and a continuous phase comprising a second polymer different from the first polymer. The second polymer has a crystallinity of less than 20% and is at least partially cross-linked.
    Type: Application
    Filed: April 20, 2011
    Publication date: August 11, 2011
    Inventors: Sunny JACOB, Peijun Jiang, Aspy K. Mehta, Pradeep P. Shirodkar, Armenag H. Dekmezian, Weiqing Weng
  • Publication number: 20110196101
    Abstract: A homogeneous polymer blend comprises a thermoplastic first polymer having a crystallinity of at least 30%; and a second polymer having a crystallinity of more than 5% and being at least partially cross-linked.
    Type: Application
    Filed: February 25, 2011
    Publication date: August 11, 2011
    Inventors: Peijun JIANG, Sunny Jacob, Aspy K. Mehta, Pradeep P. Shirodkar, Armenag H. Dekmezian, Palanisamy Arjunan
  • Publication number: 20110169199
    Abstract: The present invention relates to a process for preparing a thermoplastic vulcanizate (TPV) comprising: contacting a thermoplastic polymer, a cross-linkable elastomer, at least one curative, and at least one cure activator in a solvent to form Composition A. The solvent is then removed, and thereafter the cross-linkable elastomer is at least partially cured. The average particle size of the cross-linkable elastomer is 10 microns or less after the solvent is removed.
    Type: Application
    Filed: March 23, 2011
    Publication date: July 14, 2011
    Inventors: Weiqing Weng, Sunny Jacob, Peijun Jiang, Armenag H. Dekmezian, Aspy K. Mehta, Peter W. Manders, Pradeep Shirodkar, Palanisamy Arjunan
  • Patent number: 7951872
    Abstract: A heterogeneous polymer blend comprises a dispersed phase comprising a thermoplastic first polymer having a crystallinity of at least 30% and a continuous phase comprising a second polymer different from the first polymer. The second polymer has a crystallinity of less than 20% and is at least partially cross-linked.
    Type: Grant
    Filed: December 7, 2005
    Date of Patent: May 31, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sunny Jacob, Peijun Jiang, Aspy K. Mehta, Pradeep P. Shirodkar, Armenag H. Dekmezian, Weiqing Weng