Abstract: A process for the production of an aqueous polyurethane urea resin dispersion with a carboxyl number of 10 to 50 mg KOH/g resin solids and a ketone content of 5 to 10 wt. % relative to resin solids, comprising the steps: 1) producing a carboxylate-functional, non-gelled, water-dispersible polyurethane prepolymer with a free isocyanate group content of 1.5 to 3 wt.

Abstract: The invention is directed to a process for multilayer coating of substrates comprising the following steps: 1. applying a base coat layer of a water-based colour- and/or special effect-imparting base coat composition onto an optionally precoated vehicle substrate, 2. optionally drying or curing the base coat layer obtained in step 1, 3. applying a clear coat layer of a transparent clear coat onto the base coat layer and 4.

Abstract: Aqueous binder dispersions, which may be produced by 1) mixing 50 to 95 solids pbw (parts by weight) of non-aqueous polyurethane resin with 5 to 50 solids pbw of non-aqueous aminoplast resin, wherein the total of the solids pbw amounts to 100 and wherein polyurethane resin and aminoplast resin are inert towards each other, 2) converting the resultant non-aqueous mixture into an aqueous dispersion by mixing with water, and 3) subjecting the resultant aqueous dispersion to conditions which give rise to condensation reactions of the aminoplast resin present in the dispersion particles, until a tetrahydrofuran-insoluble binder fraction of the dispersion solids of 20 to 90 wt. % is obtained.

Abstract: Aqueous binders containing 0.2 to 7 wt-% of layered silicate, relative to binder solids content, obtainable by converting a homogeneous mixture of layered silicate and non-aqueous binder (precursor) into the aqueous phase by mixing with water and, in the case of a binder precursor, concluding synthesis of the binder in the aqueous phase.

Abstract: Aqueous binder dispersion which is suitable for the preparation of coating compositions for multilayer lacquerings and is based on polyurethane resins, which can be (meth)acrylated, the optionally (meth)acrylated polyurethane dispersion particles comprising 0.5 to 5 wt. %, based on their solids content, of water-insoluble cellulose esters.

Abstract: Aqueous binders containing 0.2 to 7 wt-% of layered silicate, relative to binder solids content, obtainable by converting a homogeneous mixture of layered silicate and non-aqueous binder (precursor) into the aqueous phase by mixing with water and, in the case of a binder precursor, concluding synthesis of the binder in the aqueous phase.

Abstract: Water-dilutable binder composition containing one or more water-dilutable hydroxy-functional polyurethane urea paste resins having a urea group content (calculated as —NHCONH—) of from 10 to 300 mmol, a urethane group content (calculated as —NHCOO—) of from 20 to 300 mmol, in each case in 100 g of solid resin, an OH number of from 20 to 250, an acid number of from 15 to 80 and a molar mass Mn of from 1000 to 20,000, obtainable by I) preparing an NCO-group-containing polyurethane prepolymer by reacting a1) hydroxy-functional compounds having a molar mass (Mn) of from 360 to 8000 with a2) polyisocyanates and a3) compounds having at least one group that is able to react with isocyanates and at least one ionic group, II) subsequently reacting the polyurethane prepolymer with a4) hydroxy-functional monoamines and, optionally, polyols, and III) neutralising groups that can be converted into ionic groups, and from 2.0 to 25 wt.

Abstract: Aqueous coating agents suitable for multi-layered finishes containing an aqueous binder dispersion based on polyurethane/polymer hybrid polymers with a ratio by weight of polyurethane fraction to polymer fraction of 0.1:1 to 50:1, with a hydroxyl value of 0 to 150 mg KOH/g, an acid value of 1.5 to 60 mg KOH/g, and a concentration of 0.5 to 300 mmol of silicon per 100 g of solid resin in the form of siloxane bridges (—Si—O—Si—) incorporated into the polyurethane fraction and/or in the form of silanol groups bonded to the polyurethane fraction, obtainable by polymerization of olefinically unsaturated monomers in the presence of polyurethane prepolymers which do not contain olefinic double bonds.

Abstract: A pigment paste containing water-dilutable hydroxy-functional polyurethaneurea paste resins with a urea group content (calculated as —NHCONH—) of 10 to 300 mmol, a urethane group content (calculated as —NHCOO—) of 20 to 300 mmol, each per 100 g of solid resin, an OH value of 20 to 250 mg KOH/g, an acid value of 15 to 80 and a molecular weight Mn of 1000 to 20000 obtainable by I) preparing a NCO group-containing polyurethane prepolymer by reacting a1) hydroxy-functional compounds with a molecular weight (Mn) of 360 to 8000 with a2) polyisocyanates and a3) compounds with at least one group which can react with isocyanate and at least one ionic group, II) subsequent reaction of the prepolymer with a4) hydroxy-functional monoamines and optionally polyols and III) neutralisation of groups which can be converted into ionic groups.

Abstract: A process for multi-layer coating by application of a base coat layer of a water-borne base coat to a substrate and subsequent application of a clear coat layer of a powder clear coat, followed by joint baking of both coating layers, wherein said water-borne base coat contains an effective amount, preferably 0.5 to 10 wt. %, of one or more water-insoluble cellulose esters, largely avoids the formation of blisters in the powder clear coat layer.

Abstract: A method for anodic electro-dip lacquer coating, wherein coating medium which is consumed in an anodic electro-dip bath is compensated for by an under-neutralised anodic replenishment material, wherein the replenishment material comprises A) a pigment-free aqueous binder vehicle component with a solids content of 40 to 70% by weight, an MEQ value of 15 to 40 and a content of organic solvent of ≦0.5% by weight, and B) a pigment-containing aqueous paste resin component with a solids content of 60 to 75% by weight, an MEQ value of 5 to 15 and a content of organic solvent of ≦1.0 % by weight, wherein A) and B) are present in a ratio by weight of 1:1 to 4:1 and the mixture of A) and B) has a solids content of 45 to 73% by weight, a solvent content of ≦0.75% by weight and an MEQ value which is 50 to 70% lower than the MEQ value of the electro-dip bath.

Abstract: Water-borne base coats, the resin solid of which contain 40 to 90 wt-% of a water-dilutable polyester binder, 0 to 50 wt-% of one or more additional binders, 0 to 20 wt-% of one or more paste resins and 10 to 40 wt-% of one or more cross-linking agents, wherein the water-dilutable polyester binder has a weight average molecular mass of 5000 to 50000, an acid value of 10 to 50 mg KOH/g, a hydroxyl value of 30 to 100 mg KOH/g and an average hydroxyl-functionality of 2 to 3 and consists of 5 to 25 wt-% of structural units —O—R—O— derived from one or more macrodiols having a hydroxyl value of 25 to 120 mg KOH/g, wherein R represents residues located between the terminal hydroxyl groups of the one or more macrodiols, are suitable for preparing water-borne base coat/clear coat-two-layer coatings, in particular water-borne base coat/powder clear coat two-layer coatings.

Abstract: Described are a method for the preparation of a multilayer coating and a coating material from an aqueous dispersion of a polymer with a particle diameter of the polymeric phase of 10 nm to 500 nm. The polymer has a number average molecular weight of 10,000 to 500,000 and an acid number of 12 to 40. The dispersion was obtained by polymerization without addition of emulsifier and in the presence of water insoluble initiators of a) 0.

Abstract: A pigment paste forming resin having a viscosity of from about 50 to about 5,000 mPa and a solids content of from about 20 to about 40%, containing from about 20 to about 50 parts of a polyester urethane resin having an acid number of from about 10 to about 50, with from about 70 to about 100% of the acid groups being neutralized, the resin being prepared by the reaction of (a) one or more polyester polyols that do not contain any carboxyl groups, having an OH number of from about 35 to about 200, and a number average molecular weight of from about 500 to about 5000, mixed with from about 2 to about 30 wt. % based on the polyester polyol of one or more low molecular weight diols having a molecular weight of from about 60 to about 350, whereby a part of the low molecular weight diol contains at least one acid group capable of forming an anion, and with 0 to about 6 wt.

Abstract: The invention relates to an aqueous coating agent which contains an organic synthetic resin binding agent which can be made dilutable with water by protonization with acids, containing crosslinking agents and a synthetic resin component containing organic amino groups and hydroxyl groups, and, in some cases, crosslinking catalysts and, if desired, pigments, fillers, corrosion inhibitors or anticorrosives, conventional lacquer adjuvants, and, in some cases, organic solvents in an amount up to 10% of the total weight of the coating agent.

Abstract: An externally crosslinkable aminopoly(meth)acrylate resin free from epoxy groups for water-dilutable lacquers having an amine number of from 30 to 150 and a hydroxyl number of from 30 to 450, obtainable by reacting a poly(meth)acrylate resin containing epoxy groups and having an average molecular weight (Mn) of from 600 to 10,000 and an epoxy equivalent weight of from 300 to 4000 with an excess of primary and/or secondary monoamines and/or amionoalcohols to react all the free epoxy groups with the amine groups and distilling off the unreacted excess amine compound, a process for its production and its use. The invention also relates to a CED bath which contains these aminopoly(meth)acrylate resins and crosslinking agents and, optionally, hydroxyfunctional resins and to its use for coating objects.

Abstract: Aqueous electrodip lacquer coating compound capable of being deposited cathodically, containing, as synthetic resin binder,(A) 55 to 95% by weight of synthetic resin binder which can be rendered water soluble by protonation with acid and(B) 5 to 45% by weight of a cross-linking agent containing ester groups capable of transesterification and/or transamidation and having terminal ester groups which are substantially stable in a neutral aqueous medium but capable of reacting with synthetic resin binder (A) in an alkaline medium at temperatures above 140.degree. C., component (A) containing in its molecule at least one molecule-enlarging diamine of the formula ##STR1## wherein the symbol Y stands for H or C.sub.m H.sub.2m+1 (m=1 to 8) or an organic group used for defunctionalization, which is formed by the reaction of the primary amino group with monoepoxides, and the symbol X represents a molecular grouping having at least one amide and/or urea group.