Abstract: A method for the in situ measurement of atomic hydrogen permeation into carbon steel from process streams under operating conditions of up to 3000 psi and temperatures up to 300° F. includes providing a probe assembly that includes a test specimen electrode and a negatively charged counter electrode in a fluid-tight reservoir containing an electrolyte, mounting the probe assembly directly in contact with a process stream and passing electrical conductors from the probe through a supporting, electrically non-conductive isolator positioned between a mounting assembly and the probe; maintaining a constant voltage across the electrodes and thereby directly measuring and recording permeation current flow between the probe electrodes.

Abstract: A high-speed corrosion-resistant rotating cylinder electrode test apparatus for monitoring of corrosion rates of metals includes an electrochemical/permeation cell body adapted to contain a fluid whose corrosive effect is to be monitored, the cell body having a base at a lower surface thereof and the base having an aperture therethrough. A counter electrode/reference electrode complex is mounted within the cell. The system further includes a cylindrical working electrode and a rotatable system shaft having a lower portion below the base and extending therefrom through the aperture into the cell body, the working electrode being mounted on an upper portion of the system shaft to be positioned within the cell body for rotation. A cone-shaped cap formed from a corrosion-resistant polymeric material is positioned above the working electrode and extends upwardly a relatively short distance into the fluid to reduce vortex phenomena. A motor is connectable to the system shaft for rotating the system shaft.

Abstract: A method and corresponding apparatus useful for the in situ measurement of atomic hydrogen permeation into carbon steel from process streams including: (a) a positively-charged test specimen electrode consisting of a planar member of hydrogen damage-resistant steel alloy having an interior surface, the interior surface being provided with a coating of palladium, and an exterior surface that is placed in contact with the process stream; (b) a fluid-tight reservoir containing a basic liquid electrolyte solution in communication with the palladium coating of the test specimen electrode; (c) a negatively charged counter electrode positioned in the electrolyte reservoir proximate the test specimen electrode said reservoir, test specimen electrode and counter electrode constituting a probe assembly; (d) a mounting assembly for supporting and positioning said probe assembly in contact with a process stream and for receiving electrical conductors joined to said probe assembly; and (e) an electrically non-conduct

Abstract: A method and apparatus is provided for the simultaneous measurement of the general corrosion rate and the atomic hydrogen permeation rate through at least two like specimens in the same test cell, under the same conditions at the same time.The nonconductive electrochemical test cell is adapted to receive at least two test specimens and associated electrodes and electronic and physical measuring means. One or more chemical additives can be introduced into the cell to determine their effect on inhibiting hydrogen permeation and corrosion rates as reflected by the respective measurements. This procedure can be repeated for other inhibitors, and, from the data obtained, a comparative ranking of the effectiveness of inhibitors can be assigned.