Patents by Inventor Arthur Boller

Arthur Boller has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5454974
    Abstract: Compounds of the formula ##STR1## wherein X.sup.1 denotes fluorine or chlorine and X.sup.2 denotes hydrogen, fluorine or chlorine; R.sup.1 is 3E-alkenyl, 4-alkenyl, 2E-alkenyloxy or 3-alkenyloxy; n stands for the number 0 or 1; one of the groups Y.sup.1 and Y.sup.2 is a single covalent bond, --COO--, --OOC--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O-- or --OCH.sub.2 -- and the other of the groups Y.sup.1 and Y.sup.2 is a single covalent bond; and rings A.sup.1 and A.sup.2 each individually are substituted or unsubstituted trans-1,4-cyclohexylene, in which optionally 2 non-adjacent CH.sub.2 groups are replaced by oxygen, or substituted or unsubstituted 1,4-phenylene, in which optionally 1 CH group or 2 CH groups is/are replaced by nitrogen; with the proviso that X.sup.2 denotes fluorine or chlorine and/or Y.sup.1 or Y.sup.2 denotes --CH.sub.2 O-- or --OCH.sub.2 -- when simultaneously X.sup.1 is fluorine and R.sup.1 is 3E-alkenyl,and their use for liquid crystalline mixtures and electro-optical purposes.
    Type: Grant
    Filed: January 6, 1994
    Date of Patent: October 3, 1995
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Richard Buchecker, Martin Schadt, Alois Villiger
  • Patent number: 5302317
    Abstract: Compounds of the formula ##STR1## wherein X.sup.1 denotes fluorine or chlorine and X.sup.2 denotes hydrogen, fluorine or chlorine; R.sup.1 is 3E-alkenyl, 4-alkenyl, 2E-alkenyloxy or 3-alkenyloxy; n stands for the number 0 or 1; one of the groups Y.sup.1 and Y.sup.2 is a single covalent bond, --COO--, --OOC--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O-- or --OCH.sub.2 -- and the other of the groups Y.sup.1 and Y.sup.2 is a single covalent bond; and rings A.sup.1 and A.sup.2 each individually are substituted or unsubstituted trans-1,4-cyclohexylene, in which optionally 2 non-adjacent CH.sub.2 groups are replaced by oxygen, or substituted or unsubstituted 1,4-phenylene, in which optionally 1 CH group or 2 CH groups is/are replaced by nitrogen; with the proviso that X.sup.2 denotes fluorine or chlorine and/or Y.sup.1 or Y.sup.2 denotes --CH.sub.2 O-- or --OCH.sub.2 -- when simultaneously X.sup.1 is fluorine and R.sup.1 is 3E-alkenyl,and their use for liquid crystalline mixtures and electro-optical purposes.
    Type: Grant
    Filed: March 29, 1993
    Date of Patent: April 12, 1994
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Richard Buchecker, Martin Schadt, Alois Villiger
  • Patent number: 5230826
    Abstract: Compounds of the formula ##STR1## wherein X.sup.1 denotes fluorine or chlorine and X.sup.2 denotes hydrogen, fluorine or chlorine; R.sup.1 is 3E-alkenyl, 4-alkenyl, 2E-alkenyloxy or 3-alkenyloxy; n stands for the number 0 or 1; one of the groups Y.sup.1 and Y.sup.2 is a single covalent bond, --COO--, --OOC--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O-- or --OCH.sub.2 -- and the other of the groups Y.sup.1 and Y.sup.2 is a single covalent bond; and rings A.sup.1 and A.sup.2 each individually are substituted or unsubstituted trans-1,4-cyclohexylene, in which optionally 2 non-adjacent CH.sub.2 groups are replaced by oxygen, or substituted or unsubstituted 1,4-phenylene, in which optionally 1 CH group or 2 CH groups is/are replaced by nitrogen; with the proviso that X.sup.2 denotes fluorine or chlorine and/or Y.sup.1 or Y.sup.2 denotes --CH.sub.2 O-- or --OCH.sub.2 -- when simultaneously X.sup.1 is fluorine and R.sup.1 is 3E-alkenyl,and their use for liquid crystalline mixtures and electro-optical purposes.
    Type: Grant
    Filed: October 26, 1988
    Date of Patent: July 27, 1993
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Richard Buchecker, Martin Schadt, Alois Villiger
  • Patent number: 5013476
    Abstract: A ferroelectric liquid crystal mixture containing at least one compound of the formula ##STR1## wherein n stands for the number 0 or 1; X.sup.1 represents a single covalent bond, --COO-- or --OOC-- and X.sup.2 represents a single covalent bond, --COO--, --OOC--, --CH.sub.2 CH.sub.2 --, --OCH.sub.2 -- or --CH.sub.2 O--; rings A.sup.1, A.sup.2 and A.sup.3 each independently signify 1,4-phenylene optionally substituted with cyano, halogen or lower alkyl or pyrimidin-2,5-diyl, pyrazin-2,5-diyl, when n is 1, trans-1,4-cyclohexylene or trans-m-dioxan-2,5-diyl; with the proviso that one of the rings present stands for pyrimidin-2,5-diyl or pyrazin-2,5-diyl when a further ring signifies trans-1,4-cyclohexylene or when n stands for the number 0 and X.sup.1 stands for a single covalent bond; and R.sup.1 signifies an optionally halogen-substituted alkenyl group with up to 18 carbon atoms in which optionally 1 or 2 non-adjacent CH.sub.2 groups are replaced by --O-- and/or a C.dbd.C double bond; with the proviso that R.
    Type: Grant
    Filed: November 17, 1987
    Date of Patent: May 7, 1991
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Richard Buchecker, Hans-Jurgen Fromm, Stephen Kelly, Martin Schadt, Alois Villiger
  • Patent number: 4704005
    Abstract: Compounds of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently straight-chain C.sub.1 -C.sub.12 -alkyl or when positioned on an aromatic ring R.sup.1 and R.sup.2 may also independently be straight-chain C.sub.1 -C.sub.12 -alkoxy, or one of R.sup.1 and R.sup.2 may also be a group of the formula: ##STR2## X.sup.1 and X.sup.2 are independently single covalent bonds or one of X.sup.1 and X.sup.2 may also be --CH.sub.2 CH.sub.2 --; rings A.sup.1 and A.sup.2 are independently 1,4-phenylene or, when X.sup.1 or X.sup.2 is --CH.sub.2 CH.sub.2 --, rings A.sup.1 and A.sup.2 may also independently be trans-1,4-cyclohexylene; and R.sup.3 is straight-chain C.sub.1 -C.sub.12 -alkyl or when positioned on an aromatic ring R.sup.3 may also be straight-chain C.sub.1 -C.sub.12 -alkoxy. Their manufacture and use in liquid crystalline mixtures are described.
    Type: Grant
    Filed: October 14, 1983
    Date of Patent: November 3, 1987
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Martin Petrzilka, Martin Schadt
  • Patent number: 4629581
    Abstract: Compounds of the formula ##STR1## wherein R.sup.1 is hydrogen or straight-chain alkyl; R.sup.2 is --CN, --R, --COR, --COOR or when R.sup.2 is positioned on an aromatic ring R.sup.2 also can be --OR, --OOCR or --F; R is alkyl; A is a group with 1 to 4 six-membered rings, these rings being linked directly with one another and with ring B in each case via a single covalent bond or being linked at one or two positions also via --COO--, --OOC-- or --CH.sub.2 CH.sub.
    Type: Grant
    Filed: June 26, 1985
    Date of Patent: December 16, 1986
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Martin Petrzilka, Martin Schadt
  • Patent number: 4613208
    Abstract: A liquid crystalline mixture comprising(a) at least one compound of the formula: ##STR1## wherein R.sup.1 is alkyl, alkoxy, p-alkylphenyl, p-alkoxyphenyl, trans-4-alkylcyclohexyl, 4'-alkyl-4-biphenylyl, p-(trans-4-alkylcyclohexyl)phenyl, 2-(trans-4-alkylcyclohexyl)ethyl or p-[2-(trans-4-alkylcyclohexyl)ethyl]phenyl and R.sup.2 is trans-4-alkylcyclohexyl; or R.sup.1 is trans-4-alkylcyclohexyl and R.sup.2 is p-(trans-4-alkylcyclohexyl)phenyl, p-[2-(trans-4-alkylcyclohexyl)ethyl]phenyl or 4'-(trans-4-alkylcyclohexyl)-4-biphenylyl; or R.sup.1 is p-alkylphenyl and R.sup.2 is p-[2-(trans-4-alkylcyclohexyl)ethyl]phenyl; and the alkyl and alkoxy groups in the substituents R.sup.1 and R.sup.2 are straight-chain groups of 1 to 7 carbon atoms, and;(b) at least one dichroic coloring substance selected from the group of compounds consisting of: ##STR2## wherein R.sup.3 is straight-chain C.sub.1 -C.sub.12 -alkyl and R.sup.4 is straight-chain C.sub.1 -C.sub.4 -alkyl, Z.sup.1 is hydrogen or chlorine, one of the symbols Z.
    Type: Grant
    Filed: November 18, 1983
    Date of Patent: September 23, 1986
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Alfred Germann, Martin Petrzilka, Martin Schadt
  • Patent number: 4462923
    Abstract: Pyrimidines of the formula: ##STR1## wherein Y is nitrogen and Z is .dbd.CH--, or Z is nitrogen and Y is .dbd.CH--; R.sup.1 is alkyl and R.sup.2 is cyano, alkyl, p-alkylphenyl or trans-4-alkylcyclohexyl; where each alkyl denotes either a straight chain alkyl group of 1 to 12 carbon atoms or a branched chain alkyl group of the formula C.sub.2 H.sub.5 --CH(CH.sub.3)--(CH.sub.2).sub.n, n is 1, 2 or 3; with the proviso that the compound contains at most only one of said branched chain alkyl group and with the further proviso that the sum of the carbon atoms in all of the alkyl groups within the compound is at most 14are described. Liquid crystalline mixtures comprising Compound I as well as their use in electro-optical devices also are disclosed.
    Type: Grant
    Filed: October 7, 1981
    Date of Patent: July 31, 1984
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Martin Schadt, Alois Villiger
  • Patent number: 4395350
    Abstract: Liquid crystal mixtures containing a coloring substance which comprise about 5 to about 40 weight % of trans-p-[5-(4-alkylcyclohexyl)-2-pyrimidinyl]benzonitriles, about 10 to about 60 weight % of trans-4-alkylcyclohexane carboxylic acid phenyl esters and about 0.1 to about 15 weight % of one or more coloring substances of the formula ##STR1## wherein m stands for the number 1 and X is alkoxy and Y is nitro; or m stands for the number 1 or 2; and X is p-alkoxyphenyl and Y is nitro or dialkylamino, or X is alkoxy and Y is -p-nitrophenyl or -(dialkylamino)phenyl; or m stands for the number 2, and X is alkoxy and Y is alkoxy, nitro or dialkylamino, or both X and Y are dialkylamino; and wherein the alkoxy denotes a straight-chain group containing 1 to 12 carbon atoms and the alkyl groups in the dialkylamino each denote a straight-chain alkyl group containing 1 to 4 carbon atoms are described.
    Type: Grant
    Filed: July 1, 1981
    Date of Patent: July 26, 1983
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Alfred Germann, Martin Schadt, Alois Villiger
  • Patent number: 4391731
    Abstract: Compounds of the formula ##STR1## wherein ring A is saturated or aromatic and a saturated ring A which may be present is trans-linked with the second ring; R.sup.1 is a straight-chain alkyl or alkoxy group containing 1 to 11 carbon atoms; R.sup.2 is cyano, a straight-chain alkyl group containing 1 to 11 carbon atoms, an ester group of the formula ##STR2## or, when ring A is saturated, additionally a straight-chain alkoxy group containing 1 to 11 carbon atoms; in the ester group of formula II ring B is either aromatic and X is oxygen or sulfur and R.sup.3 is cyano or a straight-chain alkyl or alkoxy group containing 1 to 10 carbon atoms, or ring B is a trans-1,4-disubstituted cyclohexane ring and X is oxygen and R.sup.3 is cyano or a straight-chain alkyl group containing 1 to 10 carbon atoms; and the total number of carbon atoms in the alkyl and/or alkoxy groups amounts to at most 12, are described. The compounds of formula I are useful in liquid crystal mixtures.
    Type: Grant
    Filed: August 3, 1981
    Date of Patent: July 5, 1983
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Martin Schadt, Alois Villiger
  • Patent number: 4389329
    Abstract: Pyrimidine derivatives of the formula ##STR1## wherein at least one of rings A and B is a trans-1,4-disubstituted cyclohexane ring and the other, optionally, may be aromatic and R is straight-chain alkyl or alkoxy of 1 to 10 carbon atoms or a branched-chain alkyl group of the formula C.sub.2 H.sub.5 --CH(CH.sub.3)--(CH.sub.2).sub.n -- wherein n is 1, 2 or 3, are described. Processes for the preparation of the compounds of formula I as well as their uses in liquid crystalline mixtures are also described.
    Type: Grant
    Filed: January 30, 1981
    Date of Patent: June 21, 1983
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Martin Schadt, Alois Villiger
  • Patent number: 4364838
    Abstract: Liquid crystalline mixtures comprising trans-phenyldioxane, phenylpyrimidine and phenylbenzoate compounds which are useful in electro-optical apparatuses are disclosed.
    Type: Grant
    Filed: November 10, 1980
    Date of Patent: December 21, 1982
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Alfred Germann, Martin Schadt, Alois Villiger
  • Patent number: 4309539
    Abstract: Optically active pyrimidines of the formula ##STR1## wherein Z is --(CH.sub.2).sub.n -- or --(CH.sub.2).sub.n --O-- wherein n is an integer of 1 to 4 and each of the symbols X is a nitrogen atom and each of the symbols Y is --CH-- or each of the symbols Y is a nitrogen atom and each of the symbols X is --CH--,useful for electro-optical purposes, as well as liquid crystalline mixtures for electro-optical purposes containing compounds of the formula Ia and/or Ib, are described.The compounds of formulas Ia and Ib are useful for electro-optical purposes, for example, in electro-optical apparatuses.
    Type: Grant
    Filed: December 10, 1979
    Date of Patent: January 5, 1982
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Marco Cereghetti, Hanspeter Scherrer
  • Patent number: 4273929
    Abstract: Pyrimidine derivatives of the formula ##STR1## wherein at least one of rings A and B is a trans-1,4-disubstituted cyclohexane ring and the other, optionally, may be aromatic and R is straight-chain alkyl or alkoxy of 1 to 10 carbon atoms or a branched-chain alkyl group of the formulas C.sub.2 H.sub.5 --CH(CH.sub.3)--(CH.sub.2).sub.n --wherein n is 1, 2 or 3, are described. Processes for the preparation of the compounds of formula I as well as their uses in liquid crystalline mixtures are also described.
    Type: Grant
    Filed: January 29, 1980
    Date of Patent: June 16, 1981
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Martin Schadt, Alois Villiger
  • Patent number: 4198130
    Abstract: Liquid crystal mixtures having positive anisotropy of the dielectric constants comprising a nematogenic material having a clearing point above 60.degree. C., one or more compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen or straight-chain alkyl, provided that at least one of R.sub.1 and R.sub.2 is other than hydrogen and that R.sub.1 and R.sub.2 together contain no more than 9 carbon atoms,and, if desired, one or more additional doping agents, are described.
    Type: Grant
    Filed: May 22, 1978
    Date of Patent: April 15, 1980
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Alfred Germann, Martin Schadt, Hanspeter Scherrer
  • Patent number: 4180475
    Abstract: Liquid crystal mixtures having positive anisotropy of the dielectric constants which comprise a nematogenic mixture with a clearing point above 60.degree. C. which is doped with an organic solvent or solvent mixture with a specific resistance of at least 10.sup.7 Ohm.cm. as well as a dipole moment along the longitudinal axis of the molecule of less than 3.5 Debye, or with a compound of the formula ##STR1## wherein R.sub.14 and R.sub.15 are straight-chain alkyl containing a total of not more than 14 carbon atoms or R.sub.14 is straight-chain alkyl and R.sub.15 is straight-chain alkoxy containing a total of not more than 8 carbon atoms,or a compound of the formula ##STR2## wherein R.sub.16 and R.sub.17 are straight-chain alkyl containing a total of not more than 6 carbon atoms,or a compound of the formula ##STR3## wherein R.sub.16 and R.sub.17 are straight-chain alkyl containing a total of not more than 6 carbon atoms,or mixtures thereof, are described.
    Type: Grant
    Filed: February 18, 1977
    Date of Patent: December 25, 1979
    Inventors: Martin Schadt, Hanspeter Scherrer, Arthur Boller
  • Patent number: 4066570
    Abstract: Phenyl-pyrimidines of the formula ##STR1## wherein R.sub.1 and R.sub.2 are as hereinafter set forth, are described. The end products are useful as liquid crystals.
    Type: Grant
    Filed: September 8, 1976
    Date of Patent: January 3, 1978
    Assignee: Hoffman-La Roche Inc.
    Inventors: Arthur Boller, Marco Cereghetti, Hanspeter Scherrer
  • Patent number: 4062798
    Abstract: Compounds of the formula ##STR1## wherein when X is nitrogen, Y and Z are --CH--; or when Y is nitrogen, X and Z are --CH--; or when Z is nitrogen, X and Y are --CH--; and one of R.sub.1 and R.sub.2 is cyano and the other is straight-chain alkyl of 1 to 7 carbon atoms, straight-chain alkoxy of 1 to 7 carbon atoms or straight-chain alkanoyloxy of 2 to 7 carbon atoms,Prepared by a variety of methods, are described. The compounds of the invention are useful as components of nematic mixtures.
    Type: Grant
    Filed: August 30, 1976
    Date of Patent: December 13, 1977
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Marco Cereghetti, Hanspeter Scherrer
  • Patent number: 4061587
    Abstract: Liquid crystalline alkylcinnamic acid p'-cyanophenyl esters, useful, for example, for electro-optical purposes, are described.
    Type: Grant
    Filed: July 8, 1976
    Date of Patent: December 6, 1977
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Hanspeter Scherrer, Arthur Boller
  • Patent number: 4058477
    Abstract: Liquid crystal substances or compounds of the formula ##STR1## wherein R is as hereinafter set forth, as well as compositions and electro-optical apparatuses containing them are described.
    Type: Grant
    Filed: September 8, 1975
    Date of Patent: November 15, 1977
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Arthur Boller, Hanspeter Scherrer