Abstract: The discoloration of a non-acidic room temperature vulcanizable silicone sealant containing a ultraviolet radiation degradable fungicide is delayed by adding zinc oxide.

Abstract: This invention relates to sprayable aqueous silicone emulsions which form silicone elastomers upon the removal of water having improved smoke and fire resistant properties. The aqueous silicone emulsion comprises water, a product of a diorganosiloxane polymer and a crosslinker, a surfactant and a filler selected from the group consisting of aluminum trihydrate, fumed titanium dioxide, magnesium oxide, ceramic fillers and zinc borate. The silicone emulsion has a viscosity of 10,000 to 120,000 mPa s and exhibits pseudo plastic rheology which facilitates its application by spraying. A softening agent may also be added for modulus control.

Abstract: A method for neutralizing a polyorganosiloxane mixture. The method comprises (A) contacting a mixture comprising a polyorganosiloxane and a base with a neutralizing amount of a solid organic acid at a mixture temperature above the melting temperature of the solid organic acid forming a molten organic acid and forming an insoluble adduct of the base with the molten organic acid, (B) lowering the mixture temperature to effect solidification of residual molten organic acid to residual solid organic acid, and (C) effecting separation of the insoluble adduct and the residual solid organic acid from the polyorganosiloxane mixture. The present invention is especially useful for neutralizing mixtures comprising polyorganosiloxane mixtures where the polyorganosiloxane comprises hydrocarbyl groups bonded to silicon.

Abstract: Method for homopolymerization of polyorganosiloxane macromonomers having acryloxy or methacryloxy groups. A miniemulsion of a methacryloxy functional polydimethylsiloxane macromonomer was prepared by mixing the macromonomer with a surfactant(s), and subjecting it to a high shear device. The macromonomer was polymerized in the miniemulsion by using a free radical initiator at high temperature. The amount of unreacted macromonomer is very low.

Abstract: A crosslinked polymer dispersion comprising a preformed polymer, selected from the group consisting of silicon modified organic polymers, mixtures of silicon modified organic polymers, mixtures of silicon modified organic polymer(s) with regular organic polymers, mixtures of silicon modified organic polymer(s) with siloxane polymers, mixtures of above polymers, and mixtures of above polymer(s) with organic plasticizers or solvents.

Abstract: This invention relates to an aqueous silicone emulsion which forms a silicone elastomer upon the removal of water having improved adhesions to substrates. The silicone emulsion comprises the product form by mixing a diorganosiloxane polymer, water, surfactant, optionally a crosslinker, a tin condensation catalyst, optionally an acid and an effective amount of an aminofunctional siloxane which is formed by reacting an aminofunctional silane and a hydroxy-endblocked organosiloxane.

Abstract: A method for neutralizing a polyorganosiloxane mixture. The method comprises (A) contacting a mixture comprising a polyorganosiloxane and an acid with a neutralizing amount of a solid organic base at a mixture temperature above the melting temperature of the solid organic base forming a molten organic base and forming an insoluble adduct of the acid with the molten organic base, (B) lowering the mixture temperature to effect solidification of residual molten organic base to residual solid organic base, and (C) effecting separation of the insoluble adduct and the residual solid organic base from the polyorganosiloxane mixture. The present invention is especially useful for neutralizing mixtures comprising polyorganosiloxane mixtures where the polyorganosiloxane comprises hydrogen atoms bonded to silicon.

Abstract: An aqueous silicone emulsion which upon the evaporation of the water forms a surface modified elastomeric silicone material providing improved coverage and adhesion of paint and reduced staining and coefficients of friction, each relative to other silicone elastomers from aqueous emulsions. The silicone emulsion comprises (A) water; (B) a plurality of particles dispersed in the water comprising a crosslinked product of a diorganosiloxane polymer; (C) a surfactant; and (D) an amount of an oxygen curing compound or a salt thereof effective for the surface modification. If a surface active salt of an oxygen curing compound is used, it may not be required to add additional surfactant in order to form the silicone emulsion.

Abstract: This invention relates to a method of sealing openings in structural components of a building to reduce the amount of smoke which may pass through the opening in the event of a fire. The method comprises filling an opening in a structural component of a building with a support material; applying a coating of a silicone composition over the filled opening and allowing the silicone composition to cure into a continuous elastomeric film having certain properties. These silicone compositions exhibit pseudo plastic rheology which facilitates their application by spraying.

Abstract: The longevity of a surface driving oil layer on a room temperature vulcanizable silicone sealant is increased by adding zinc oxide to a non-acidic composition and exposing the composition to atmospheric moisture which forms the surface drying oil layer on an air exposed surface.