Patents by Inventor Asahi Kawashima
Asahi Kawashima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5634989Abstract: A corrosion-resistant amorphous alloy containing Ta in an amount of from 10 to 40 atomic % and Mo, Cr, W, P, B and/or Si is disclosed.This alloy can be prepared by rapidly cooling and solidifying molten alloy, shows a satisfactory corrosion resistance in high-temperature concentrated phosphoric acid, and is adapted to be used as a plant structural material or a separator for a fuel cell.Type: GrantFiled: July 15, 1992Date of Patent: June 3, 1997Assignees: Mitsubishi Materials Corporation, Koji HashimotoInventors: Koji Hashimoto, Akira Mitsuhashi, Katsuhiko Asami, Asahi Kawashima, Yoshio Takizawa
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Patent number: 5549797Abstract: Amorphous alloy comprising 30 to 75 atomic % Cr, the remainder being substantially at least one element selected from the group consisting of Ti and Zr and alloys represented by the general formula: X.sub.a Cr.sub.b M.sub.c wherein X is at least one element selected from the group consisting of Ti and Zr; M is at least one element selected from the group consisting of Mg, Al, Fe, Co, Ni, Cu, Mo and W; and a, b, and c are, in atomic percentage, a>20, 20 .ltoreq.b.ltoreq.75, 0<c .ltoreq.20 and a+b+c=100. The alloys are excellent in corrosion resistance and wear resistance, form a stable protective film and are spontaneously passive, even in corrosive environment such as a poorly oxidizing, highly corrosive HCl solution containing chlorine ions.Type: GrantFiled: March 7, 1994Date of Patent: August 27, 1996Assignees: Koji Hashimoto, YKK CorporationInventors: Koji Hashimoto, Hideaki Yoshioka, Asahi Kawashima
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Patent number: 5460663Abstract: Amorphous alloys having an extremely high corrosion resistance comprise Cr and at least one element selected from Ta and Nb, as essential components, and are spontaneously passive owing to the formation of stable protective films, even in very corrosive environments such as poorly oxidizing concentrated hydrochloric acid. The amorphous alloy may further include one or more elements appropriately selected from other alloying elements of Al, Ti, Zr, Fe, Co, Ni, Cu, Mo and W. The amorphous alloys have advantageous properties, such as very high corrosion resistance, high corrosion resistance at elevated temperatures and high wear resistance, and, therefore are useful in chemical plants or other industrial and domestic applications.Type: GrantFiled: April 20, 1994Date of Patent: October 24, 1995Assignee: YKK CorporationInventors: Koji Hashimoto, Jinhan Kim, Hideaki Yoshioka, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami
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Patent number: 5326736Abstract: This invention relates to a catalyst for cleaning exhaust gas, which is prepared by dipping in hydrofluoric acid an amorphous alloy composed of 20 to 80 atom % of one or more elements selected from the group consisting of Nb, Ta, Ti and Zr (the sum of Nb and Ta being up to 70 atom %), 0.5 to 20 atom % of one or more elements selected from the group consisting of Ru, Pd, Rh, Pt and Ir, and the balance of one or two of Ni and Co. This catalyst can clean at a low temperature an exhaust gas containing NO or CO discharged from apparatuses or engines wherein various organic substances are burnt.Type: GrantFiled: April 1, 1992Date of Patent: July 5, 1994Assignees: Koji Hashimoto, Daiki Engineering Co., Ltd.Inventors: Koji Hashimoto, Kiyohiro Teruuchi, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami
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Patent number: 5245112Abstract: The present invention provides a method for the decomposition of chlorofluorocarbons to hydrofluoric acid, hydrochloric acid and carbon dioxide by the chlorofluorocarbons' reaction with water at a temperature of 200 .degree. C. or higher and in the presence of a catalyst material consisting of a metal selected from the group consisting of Ti, Zr, Nb and an alloy consisting of at least two elements selected from the same group. The catalyst material may also be composed of an alloy consisting of up to 80 atomic % of at least one element selected from the group consisting of Ni and Co and the substantial balance of being at least one element selected from the group consisting of Ti, Zr and Nb. The metallic catalyst materials of the present invention have a very high catalytic activity for the decomposition of flons at relatively low temperatures and can retain their high activity during the decomposition process, even if they are converted into fluorides.Type: GrantFiled: April 10, 1992Date of Patent: September 14, 1993Assignees: Koji Hashimoto, Yoshida Kogyo K.K.Inventors: Koji Hoshimoto, Akihito Hirota, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami
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Patent number: 5123980Abstract: An amorphous aluminum-valve metal alloy with special characteristics such as high corrosion resistance, high wear resistance and considerable toughness, consisting of Al and at least one element selected from valve metals of Ti and Zr, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Mo, W, Ta and Nb.Type: GrantFiled: October 3, 1990Date of Patent: June 23, 1992Assignees: Yoshida Kogyo K.K., Koji HashimotoInventors: Koji Hashimoto, Hideaki Yoshioka, Katsuhiko Asami, Asahi Kawashima
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Patent number: 5076865Abstract: An amorphous aluminum-valve metal alloy with special characteristics such as high corrosion resistance, high wear resistance and coinsiderable toughness, consisting of Al and at least one element selected from valve metals of Ti and Zr, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Mo, W, Ta and Nb.Type: GrantFiled: October 13, 1989Date of Patent: December 31, 1991Assignees: Yoshida Kogyo K. K., Koji HashimotoInventors: Koji Hashimoto, Hideaki Yoshioka, Katsuhiko Asami, Asahi Kawashima
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Patent number: 5041175Abstract: An amorphous aluminum-refractory metal alloy with special characteristics such as high corrosion resistance, high wear resistance and considerable toughness, consisting of Al and at least one element selected from refractory metals of Ta, Nb, Mo and W, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Ti and Zr.Type: GrantFiled: October 5, 1990Date of Patent: August 20, 1991Assignees: Yoshida Kogyo K.K., Koji HashimotoInventors: Koji Hashimoto, Hideaki Yoshioka, Katsuhiko Asami, Asahi Kawashima
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Patent number: 5030300Abstract: An amorphous aluminum-refractory metal alloy with special characteristics such as high corrosion resistance, high wear resistance and considerable toughness, consisting of Al and at least one element selected from refractory metals of Ta, Nb, Mo and W, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Ti and Zr.Type: GrantFiled: December 21, 1989Date of Patent: July 9, 1991Assignees: Yoshida Kogyo K.K., Koji HashimotoInventors: Koji Hashimoto, Hideaki Yoshioka, Katsuhiko Asami, Asahi Kawashima
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Patent number: 5015352Abstract: A method for preparation of amorphous superlattice alloys consisting of lamellae based on periodic change in the composition by continuous conventional sputtering with a periodic change in the positions of substrates relative to a target or targets by rotating the substrate on a first axis and orbiting the substrate and first axis around a second axis parallel to the first axis.Type: GrantFiled: October 13, 1989Date of Patent: May 14, 1991Assignees: Yoshida Kogyo K.K., Koji HashimotoInventors: Koji Hashimoto, Hideaki Yoshioka, Katsuhiko Asami, Asahi Kawashima
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Patent number: 4968363Abstract: A highly corrosion-resistant amorphous alloy composed of ni-- 15-80 atomic % Ta Ni-- 30-80 atomic % Ta, or Ni-- 20-50 atomic % Ta-- 10-23 atomic % P, with a specific amount of optional elements of Ti, Zr, Nb, W, Fe, Co, Cr, P, B, Si, or C.Type: GrantFiled: November 22, 1988Date of Patent: November 6, 1990Assignees: Mitsui Engineering & Shipbuilding Co., Ltd., Koji HashimotoInventors: Koji Hashimoto, Kazuo Shimamura, Asahi Kawashima, Katsuhiko Asami
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Patent number: 4964967Abstract: Surface activated surface alloy electrodes and a process for preparing them high in corrosion resistance and activity, comprising a corrosion-resistant metal selected from, or a corrosion-resistant alloy composed of two or more metals selected from titanium, zirconium, niobium and tantalum, or a corrosion-resistant metal selected from, or a corrosion-resistant alloy composed of two or more metals selected from titanium, zirconium, niobium and tantalum clad with a corrosion-resistant metal selected from, or a corrosion-resistant alloy composed of two or more metals selected from titanium, zirconium, niobium and tantalum, or with any other metal or alloy, rolled or non-rolled, being used as a substrate metal or alloy; an alloy consisting of 20 to 67 atomic % of one or more metals selected from titanium, zirconium, niobium and tantalum, 0.Type: GrantFiled: February 16, 1990Date of Patent: October 23, 1990Assignees: Daiki Engineering Co., Ltd., Koji HashimotoInventors: Koji Hashimoto, Naokazu Kumagai, Katsuhiko Asami, Asahi Kawashima
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Patent number: 4880482Abstract: A highly corrosion-resistant amorphous Cu alloys with at least one element selected from the group of Ta and Nb and other Cu-Ta alloys with at least one element selected from the group of Nb, Ti and Zr, wherein the total content of alloying elements other than Cu ranges from 15 to 85 at %.Type: GrantFiled: April 19, 1988Date of Patent: November 14, 1989Assignees: Mitsui Engineering & Shipbuilding Co., Ltd., Koji HashimotoInventors: Koji Hashimoto, Kimikado Miura, Katsuhiko Asami, Asahi Kawashima
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Patent number: 4868073Abstract: A highly active powder catalyst with a high concentration of platinum group elements prepared from an amorphous alloy consisting of at least one of valve metals, at least one of platinum group elements and balance being at least one element selected from Ni and Co by immersion in a hydrofluoric acid, and a highly active electrode prepared by using the above mentioned powder catalyst.Type: GrantFiled: May 16, 1988Date of Patent: September 19, 1989Assignees: Yanmar Diesel Engine Co., Ltd., Koji HashimotoInventors: Koji Hashimoto, Toshihisa Kanda, Asahi Kawashima, Katsuhiko Asami
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Patent number: 4834806Abstract: A corrosion-resistant amorphous surface alloy is disclosed which is 150 .mu.m or less thick and bonded onto a substrate crystalline metal or alloy and processed by irradiation of high energy density beam, such alloy being composed of 8-19 at % Cr, 17-22 at % in the sum of P and 2-7 at % B, and the remainder being Ni, Ni--Co containing Co in an atomoic ratio of Co/Ni of 2/3 or less, or Ni--Fe or Ni--Co--Fe containing Fe in an atomic ratio of Fe/Ni or Fe/Ni+Co of 1/5 or less. Also disclosed is a process for producing such alloy.Type: GrantFiled: September 18, 1987Date of Patent: May 30, 1989Assignee: Yoshida Kogyo K. K.Inventors: Koji Hashimoto, Hideaki Yoshioka, Katsuhiko Asami, Asahi Kawashima
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Patent number: 4770949Abstract: Electrode materials and method for their surface activation are described. Alloys consisting of at least one element of the group consisting of Nb, Ta, Ti and Zr, at least one element of the group consisting of Ru, Rh, Pd, Ir and Pt, and balance being Ni are prepared by methods for preparation of amorphous alloys, and are amorphous or supersaturated solid solution. Their surfaces are activated to enhance electrocatalytic activity by enrichment of electrocatalytically active platinum group elements in the surface region in addition to surface roughening as a result of selective dissolution of Ni, Nb, Ta, Ti and Zr from the alloys during immersion in corrosive solutions. The surface-activated amorphous and supersaturated solid solution alloys possess high electrocatalytic activity and selectivity for a specific reaction as well as high corrosion resistance.Type: GrantFiled: August 4, 1986Date of Patent: September 13, 1988Assignees: Daiki Engineering Co., Ltd., Koji HashimotoInventors: Koji Hashimoto, Naokazu Kumagai, Katsuhiko Asami, Asahi Kawashima
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Patent number: 4743314Abstract: A highly corrosion-resistant amorphous Ni-Cu-Ti-Ta, Ni-Cu-Ti-Nb and Ni-Cu-Ti-Ta-Nb alloys in which the sum of Ti and Ta and/or Nb is 30-62.5 atomic %.Type: GrantFiled: September 21, 1987Date of Patent: May 10, 1988Assignees: Mitsui Engineering & Shipbuilding Co., Ltd., Koji HashimotoInventors: Koji Hashimoto, Kimikado Miura, Katsuhiko Asami, Asahi Kawashima