Abstract: Systems and methods are provided for improving control of the temperature profile in a cyclic flow reactor, such as a reverse flow reactor, during operation. The improved temperature control is achieved in part based on inclusion of regions having reduced or minimized catalyst density with increased volumetric heat capacity within the reaction zone of the reactor. This improved control over the temperature profile is achieved while reducing or minimizing any loss of reaction capacity due to lowering the amount of catalyst in the reaction zone.

Abstract: Ranking materials for post combustion carbon capture by characterizing sorbent materials with a molecular model workflow that generates microscopic figures of merit for materials by microscopic properties; and evaluating the materials from the molecular model workflow with a process model workflow that generates macroscopic figures of merit for process steps of a carbon recovery process. The materials for applicability as a sorbent material are ranked using a combined microscopic performance and macroscopic process feasibility generator that ranks the materials according to the microscopic figures of merit for materials and the macroscopic figures of merit for the process steps.

Abstract: An upgraded crude composition is provided, along with systems and methods for making such a composition. The upgraded crude composition can include an unexpectedly high percentage of vacuum gas oil boiling range components while having a reduce or minimized amount of components boiling above 593° C. (1100° F.). In some aspects, based in part on the hydroprocessing used to form the upgraded crude composition, the composition can include unexpectedly high contents of nitrogen. Still other unexpected features of the composition can include, but are not limited to, an unexpectedly high nitrogen content in the naphtha fraction; and an unexpected vacuum gas oil fraction including an unexpectedly high content of polynuclear aromatics, an unexpectedly high content of waxy, paraffinic compounds, and/or an unexpectedly high content of n-pentane asphaltenes.

Abstract: An upgraded crude composition is provided, along with systems and methods for making such a composition. The upgraded crude composition can include an unexpectedly high percentage of vacuum gas oil boiling range components while having a reduce or minimized amount of components boiling above 593° C. (1100° F.). In some aspects, based in part on the hydroprocessing used to form the upgraded crude composition, the composition can include unexpectedly high contents of nitrogen. Still other unexpected features of the composition can include, but are not limited to, an unexpectedly high nitrogen content in the naphtha fraction; and an unexpected vacuum gas oil fraction including an unexpectedly high content of polynuclear aromatics, an unexpectedly high content of waxy, paraffinic compounds, and/or an unexpectedly high content of n-pentane asphaltenes.

Abstract: A method for desalinating a liquid, including: contacting, within a hydrate former reactor, a feed gas stream including iso-butane in an amount ranging from above zero mol % to about 3 mol % and liquid seawater or liquid wastewater including a dissolved salt, wherein a temperature and pressure within the hydrate former reactor is controlled so that the feed gas stream and the liquid seawater or liquid wastewater form a hydrate slurry; separating hydrate particles from the hydrate slurry; and decomposing the hydrate particles into its constituents of water and gas or gas mixture containing iso-butane, wherein the water has a concentration of the dissolved salt that is less than that of the liquid seawater or liquid wastewater.

Abstract: Processes for separating carbon dioxide from a gas mixture that comprises CO2 and N2 that are based upon formation of gas hydrates, and systems useful for implementing such processes, are disclosed.

Abstract: The present disclosure relates to methods and systems for converting biomass into biofuels and biochemicals. In particular, the present disclosure relates to methods and systems for converting biomass comprising lignocellulosic material into biofuels and biochemicals, such as those comprising fatty acid esters, that contribute to reduction of greenhouse gas emissions.

Abstract: Processes for separating carbon dioxide from a gas mixture that comprises CO2 and N2 that are based upon formation of gas hydrates, and systems useful for implementing such processes, are disclosed.

Abstract: Processes for separating methane from a gas mixture that comprises methane and C2 gas, including C2+ gas, and other gases, including CO2 and H2S, that are based upon formation of gas hydrates, and systems useful for implementing such processes, are disclosed.

Abstract: A method for desalinating a liquid, including: contacting, within a hydrate former reactor, a feed gas stream including iso-butane in an amount ranging from above zero mol % to about 3 mol % and liquid seawater or liquid wastewater including a dissolved salt, wherein a temperature and pressure within the hydrate former reactor is controlled so that the feed gas stream and the liquid seawater or liquid wastewater form a hydrate slurry; separating hydrate particles from the hydrate slurry; and decomposing the hydrate particles into its constituents of water and gas or gas mixture containing iso-butane, wherein the water has a concentration of the dissolved salt that is less than that of the liquid seawater or liquid wastewater.

Abstract: Processes for forming and sequestering CO2 clathrates in a marine environment are disclosed.

Abstract: Processes for forming and sequestering CO2 clathrates in a marine environment are disclosed.

Abstract: Processes for separating carbon dioxide from a gas mixture that comprises CO2 and N2 that are based upon formation of gas hydrates, and systems useful for implementing such processes, are disclosed.

Abstract: Processes for separating methane from a gas mixture that comprises methane and C2 gas, including C2+ gas, and other gases, including CO2 and H2S, that are based upon formation of gas hydrates, and systems useful for implementing such processes, are disclosed.

Abstract: Provided herein are dual riser fluid catalytic cracking processes for producing light olefins from an oxygenate feed, such as a methanol feed, in a conventional FCC unit. In certain aspects the processes comprise cracking a hydrocarbon feed in a first riser comprising a first catalyst under first riser conditions to form a first effluent enriched in olefins, light gasoil, gasoline, or a combination thereof; cracking a hydrocarbon oxygenate feed in a second riser comprising a second catalyst under second riser conditions to form a second effluent enriched in olefins; recovering the first and second catalyst from the first and second effluents in a common reactor; regenerating the recovered first and second catalyst in a regenerator using heat from the exothermic cracking of the hydrocarbon oxygenate feed; and recirculating the regenerated first and second catalyst to the first and second riser.

Abstract: Systems and methods for rejecting waste heat generated by one or more operating systems installed on an aircraft employ an endothermic fuel that can participate in endothermic catalytic cracking at temperatures below about 80° C. when exposed to a cracking catalyst that contains a superacid operative to induce low-temperature catalytic cracking of the branched alkanes. The endothermic fuel contains an effective amount of the branched alkanes so that a net endothermic effect is realized when the fuel is exposed to the cracking catalyst. The low-temperature, heat-consuming cracking of the branched alkanes increases the heat sink capacity of the endothermic fuel.

Abstract: A heat sink is used to absorb heat produced by a vehicle. The heat sink uses an endothermic catalytic alcohol dehydrogenation reaction to assist with the absorption of excess heat produced in the electronics of the vehicle. In some embodiments, the alcohol can be pre-heated by absorbing heat from various components of the vehicle. Excess heat from the various components or from the vehicle engine can be used to vaporize the reaction fluids in order to further absorb additional heat. Reaction fluids can also be sent to the vehicle's engine/burner for use as a supplemental fuel.

Abstract: Systems and methods for rejecting waste heat generated by one or more operating systems installed on an aircraft employ an endothermic fuel that can participate in endothermic catalytic cracking at temperatures below about 80° C. when exposed to a cracking catalyst that contains a superacid operative to induce low-temperature catalytic cracking of the branched alkanes. The endothermic fuel contains an effective amount of the branched alkanes so that a net endothermic effect is realized when the fuel is exposed to the cracking catalyst. The low-temperature, heat-consuming cracking of the branched alkanes increases the heat sink capacity of the endothermic fuel.

Abstract: A heat sink is used to absorb heat produced by a vehicle. The heat sink uses an endothermic catalytic alcohol dehydrogenation reaction to assist with the absorption of excess heat produced in the electronics of the vehicle. In some embodiments, the alcohol can be pre-heated by absorbing heat from various components of the vehicle. Excess heat from the various components or from the vehicle engine can be used to vaporize the reaction fluids in order to further absorb additional heat. Reaction fluids can also be sent to the vehicle's engine/burner for use as a supplemental fuel.