Abstract: A drilling fluid composition comprising a base fluid, and a drag reducing agent including an ultra-high molecular weight branched block copolymer having the following structure, where monomer A is an anionic monomer, monomer B is a hydrophilic monomer, monomer C is an anionic monomer, monomer D is a crosslinker-divinyl monomer, and —SSCZ ground being a terminal RAFT agent.

Abstract: A drilling fluid includes an aqueous phase, a clay-based component, and an amphiphilic branched star polymer. The amphiphilic branched star polymer is a crosslinked, polymerized reaction product of crosslinker C, hydrophobic monomer B, and hydrophilic monomer A. The crosslinked polymerized reaction product includes a plurality of block copolymer segments of hydrophobic monomer B and hydrophilic monomer A interconnected via crosslinker C.

Abstract: Methods comprising pre-mixing a flowable universal fluid (UF) composition that is settable from a fluid state to a solid state, wherein the fluid UF composition comprises: an aqueous-based carrier fluid; a cement precursor; and, a delaying agent. And drilling a wellbore in a subterranean formation using the fluid UF composition, wherein a portion of the fluid UF composition remains in the wellbore upon completing the drilling; and introducing an activator and heating the portion of fluid UF composition in the wellbore under formation temperature conditions, thereby solidifying the fluid UF composition into a solid UF composition in the wellbore.

Abstract: A cement emulsion comprising a cement, water, and carbon dioxide is provided. The carbon dioxide may be liquid or super critical and is dispersed in the cement emulsion composition. A method of producing a cement emulsion composition is also provided. The method includes mixing a cement and water to form a hydrated cement composition, and emulsifying the hydrated cement composition with liquid or supercritical CO2. An article comprising the cement emulsion composition is provided. Further, a method of treating a wellbore comprising producing a cement emulsion composition and pumping the cement emulsion composition into a wellbore, and a method of manufacturing an article comprising producing a cement emulsion composition and 3D printing the cement emulsion composition are also provided.

Abstract: A method for inhibiting corrosion in a refinery crude distillation unit includes introducing a corrosion inhibition composition to the refinery crude distillation unit. The corrosion inhibition efficiency of the corrosion inhibition composition may be at least 80%. The corrosion inhibition composition may include a carrier fluid and a corrosion inhibitor consisting essentially of a compound represented by Formula (I): where R1, R2, R3, and R4 are each, independently, a hydrogen or an alkoxy group, and m and n are each, independently integers ranging from 2 to 10, wherein R5 and R6 are each, independently, a saturated C6-C10 hydrocarbon group or an unsaturated C6-C10 hydrocarbon group.

Abstract: This document relates to methods for preventing or inhibiting the cracking or explosion of cement in an oil well using cement compositions that contain polyrotaxane additives. The cement compositions containing the polyrotaxane additives exhibit increased resiliency to cracking as compared to the same cement without the polyrotaxane additive.

Abstract: Hydrogen may be produced from ammonia by catalytic reaction. For example, a method of hydrogen production may include: introducing ammonia to a reactor, wherein the reactor includes therein a catalyst, wherein the catalyst includes a high entropy alloy, and wherein the high entropy alloy has an entropy, S, such that S?11.31 J K?1 mol?1; reacting the ammonia in the presence of the catalyst to form hydrogen gas and nitrogen gas; and separating the hydrogen gas from the nitrogen gas to produce a hydrogen stream including the hydrogen gas from the reactor.

Abstract: A self-healing cement structure may be used for repairing defects. An example method of using such a cement structure includes: providing a cement structure in a wellbore, wherein the cement structure includes: a cement and elastomer particles at 1% by weight of the cement (bwoc) to 25% bwoc; applying heat to the cement structure to heat at least a portion of the elastomer particles above a melting point of an elastomer of the elastomer particles to cause at least a portion of the elastomer to melt and infiltrate into a defect in the cement structure; and allowing the elastomer to cool below the melting point of the elastomer to yield a repaired cement structure.

Abstract: A fluid composition including a mixed metal oxide viscosifier, a clay viscosifier, and solid eutectic metal alloy particles. A method including pumping a drilling fluid downhole in a wellbore. The drilling fluid including water, a mixed metal oxide viscosifier, a clay viscosifier, and solid eutectic metal alloy particles. The method further including allowing the drilling fluid to reach a target zone with elevated permeability and forming a filter cake containing solid eutectic metal alloy particles in the target zone. The method including heating the filter cake to a temperature greater than the melting temperature of the eutectic metal alloy particles, allowing the particles to melt and become liquid eutectic metal alloy particles. The method including discontinuing heating and allowing the filter cake to cool to a temperature lower than the melting temperature of the solid eutectic metal alloy particles to produce a strengthened filter cake.

Abstract: A self-healing cement structure may be used for repairing defects. An example method of using such a cement structure includes: providing a cement structure in a wellbore, wherein the cement structure includes: a cement and elastomer particles at 1% by weight of the cement (bwoc) to 25% bwoc; applying heat to the cement structure to heat at least a portion of the elastomer particles above a melting point of an elastomer of the elastomer particles to cause at least a portion of the elastomer to melt and infiltrate into a defect in the cement structure; and allowing the elastomer to cool below the melting point of the elastomer to yield a repaired cement structure.

Abstract: Metamaterials may be utilized to facilitate conversion of hydrogen sulfide into elemental hydrogen and elemental sulfur in the presence of suitable photocatalyst particles. Photoreactor systems utilizing metamaterials may comprise a flow-through reaction space having at least one metamaterial-catalyst surface. The at least one metamaterial-catalyst surface comprises a metamaterial surface having a plurality of resonators patterned thereon and a plurality of photocatalyst particles located upon at least a portion of the resonators, within a gap between a first region and a second region of one or more resonators, or within a gap between adjacent resonators. The plurality of photocatalyst particles comprise at least one photocatalyst effective to convert hydrogen sulfide into elemental hydrogen and elemental sulfur upon exposure to electromagnetic radiation.

Abstract: Hydrogen may be produced from natural gas (e.g., methane). For example, a method for producing hydrogen from natural gas may include: introducing natural gas to a reactor, wherein the reactor contains therein a catalyst, wherein the catalyst includes a high entropy alloy, and wherein the high entropy alloy has an entropy, S, such that S?11.31 J K?1 mol?1; reacting the natural gas with the catalyst to form hydrogen gas and solid carbon; and separating the hydrogen gas from the solid carbon to produce a hydrogen stream comprising the hydrogen gas from the reactor.

Abstract: A eutectic composite may be utilized in oil and gas servicing. For example, a method of making such a composite may include: crosslinking a mixture including a polymer, a metaphosphate salt, and a plurality of eutectic alloy particles to yield a eutectic composite; and producing a plurality of eutectic composite particles from the eutectic composite. Furthermore, an example composition may include: a cement; water; and a plurality of eutectic composite particles including eutectic alloy particles dispersed in a polymer crosslinked with a metaphosphate salt.

Abstract: This disclosure relates to a fracturing fluid including an acrylamide-based copolymer, a graphene oxide additive, and a crosslinker, and methods of using the fracturing fluid to reduce fluid friction during treatment of a subterranean formation.

Abstract: A composition that includes a polymer-grafted graphene particle and oil-based drilling fluid is provided. At least one side of the graphene particle comprises a grafted polymer. A method of using an oil-based drilling fluid is also provided. The method includes introducing the oil-based drilling fluid into a wellbore and circulating the oil-based drilling fluid during drilling operations. The drilling fluid includes a polymer-grafted graphene particle and oil-based drilling fluid. At least one side of the graphene particle comprises a grafted polymer. The oil-based drilling fluid includes a range of from about 0.01 ppb to 10 ppb of the polymer-grafted graphene particle.

Abstract: A composition that includes a polymer-grafted graphene particle and aqueous-based drilling fluid is provided. At least one side of the graphene particle comprises a grafted polymer. A method of using an aqueous-based drilling fluid is also provided. The method includes introducing the aqueous-based drilling fluid into a wellbore and circulating the aqueous-based drilling fluid during drilling operations. The drilling fluid includes a polymer-grafted graphene particle and aqueous-based drilling fluid. At least one side of the graphene particle comprises a grafted polymer. The aqueous-based drilling fluid includes a range of from about 0.01 ppb to 10 ppb of the polymer-grafted graphene particle.

Abstract: A drilling fluid composition comprising a base fluid, and a viscosifier including an ultra-high molecular weight branched block copolymer having the following structure, where monomer A is an anionic monomer, monomer B is a hydrophilic monomer, monomer C is an anionic monomer, monomer D is a crosslinker-divinyl monomer, and-SSCZ ground being a terminal RAFT agent.

Abstract: A lost circulation material is placed in a cavity. The cavity is defined by an inner bore of a cylindrical wall, intermediate of a piston and a screen. A distance between the piston and the screen is defined as the height of the cavity, which is adjustable. The piston is slid longitudinally, such that the piston comes in contact with the lost circulation material. The lost circulation material is heated to a specified test temperature mimicking a downhole temperature. A compression test is performed on the lost circulation material. The compression test includes flowing a test fluid into the cavity and applying force on the piston to pressurize the test fluid to a specified test pressure mimicking a downhole pressure. The force on the piston is released. The pressure of the test fluid and the height of the cavity are measured throughout the compression test.

Abstract: This disclosure relates to a fracturing fluid including an acrylamide-based copolymer, a graphene oxide additive, and a crosslinker, and methods of using the fracturing fluid to reduce fluid friction during treatment of a subterranean formation.

Abstract: A composition that includes a polymer-grafted graphene particle and oil-based drilling fluid is provided. At least one side of the graphene particle comprises a grafted polymer. A method of using an oil-based drilling fluid is also provided. The method includes introducing the oil-based drilling fluid into a wellbore and circulating the oil-based drilling fluid during drilling operations. The drilling fluid includes a polymer-grafted graphene particle and oil-based drilling fluid. At least one side of the graphene particle comprises a grafted polymer. The oil-based drilling fluid includes a range of from about 0.01 ppb to 10 ppb of the polymer-grafted graphene particle.