Abstract: The invention is a method for producing a cast cermet anode for metal oxide electrolytic reduction by feeding metallic iron and metallic nickel in solid form to an oxidizing reactor; melting and oxidizing the iron and nickel and forming molten nickel ferrite; mixing the molten nickel ferrite with a base metal of high electrical conductivity such as nickel, copper, silver, or alloys thereof in a holding vessel such as ladle or tundish, and casting the mixture into a mold to form a near net shape of the desired anode. Apparatus for carrying out the method, and the resulting product are also disclosed.

Abstract: The invention is a method for producing a cast ceramic anode for metal oxide electrolytic reduction by feeding metallic iron and metallic nickel in solid form to an oxidizing reactor; melting and oxidizing the iron and nickel and forming molten nickel ferrite; mixing the molten nickel ferrite with dopant in a holding vessel such as ladle or tundish to increase electrical conductivity of the mixture, and casting the mixture into a mold to form a near net shape of the desired anode. Apparatus for carrying out the method, and the resulting product are also disclosed.

Abstract: A method for producing a non-carbon inert anode for metal oxide electrolytic reduction by coating a metal, cermet, or ceramic substrate with a molten metal oxide compound of a ferrite and at least one divalent metal selected from iron, nickel, manganese, magnesium, and cobalt. The coated anode is protected from attack by the liberated oxygen and the solute in the electrolysis of metals, such as aluminum, magnesium, lithium, or calcium. Apparatus for carrying out the method, and the resulting product are also disclosed.

Abstract: The invention is a method for producing a cast cermet anode for metal oxide electrolytic reduction by feeding metallic iron and metallic nickel in solid form to an oxidizing reactor; melting and oxidizing the iron and nickel and forming molten nickel ferrite; mixing the molten nickel ferrite with a base metal of high electrical conductivity such as nickel, copper, silver, or alloys thereof in a holding vessel such as ladle or tundish, and casting the mixture into a mold to form a near net shape of the desired anode. Apparatus for carrying out the method, and the resulting product are also disclosed.

Abstract: The invention is a method for producing a cast ceramic anode for metal oxide electrolytic reduction by feeding metallic iron and metallic nickel in solid form to an oxidizing reactor; melting and oxidizing the iron and nickel and forming molten nickel ferrite; mixing the molten nickel ferrite with dopant in a holding vessel such as ladle or tundish to increase electrical conductivity of the mixture, and casting the mixture into a mold to form a near net shape of the desired anode. Apparatus for carrying out the method, and the resulting product are also disclosed.

Abstract: Process for producing novel fluxed PZT dielectric ceramic compositions having sintering temperatures below about 1000.degree., so as to be non-reactive with electrode layers when co-fired therewith. The PZT is sintered with an effective amount of an eutectic mixture of CuO and an oxide of an alkaline earth metal, preferably barium oxide and/or strontium oxide, to reduce the sintering temperature of the PZT composition below about 1000.degree. C. Dopant such as manganese oxide may be added to reduce the dielectric losses.