Abstract: A method is disclosed for dewatering of sludge from a pulp, paper or board making process, such as deinking sludge, including obtaining of an aqueous sludge including an aqueous phase and a fibre material suspended in the aqueous phase. The sludge is subjected to a pre-thickening step, where a first part of the aqueous phase is removed from the sludge and to a pressing step, where a second part of the aqueous phase is removed from the sludge, thereby obtaining a dry pressed sludge. Before or at the pre-thickening step a polymer composition having a charge density of at the most 1.7 meq/g, preferably at most 1.5 meq/g, more preferably at most 1.1 meq/g, is added to the sludge.

Abstract: A method for producing an aqueous copolymer solution, which comprises dissolving a copolymer of (meth)acrylamide and at least 1 mol-% cationic monomers, calculated from total amount of monomers in the dissolving water having calcium hardness of at least mg/l, expressed as Ca2+, and adding acid comprising monoprotic organic acid and/or mineral acid to the dissolving water and/or the aqueous solution of the copolymer in an amount sufficient to provide the aqueous solution of the copolymer with a pH of equal to or less than 4.5. The invention also relates to uses of the obtained polymer solutions in manufacturing of paper, board or the like or in treatment of sludge or water.

Abstract: A polymer composition includes a first host polymer, which is a copolymer of (meth)acrylamide and at least one cationic first monomer, and a second polymer, which is a copolymer of (meth)acrylamide and at least one cationic second monomer. The second polymer is polymerised in presence of the first host polymer, and the first host polymer has a higher cationicity than the second polymer, the difference in cationicity of the first host polymer and the second polymer being at least 3 mol-%, at least 5 mol-%, more preferably at least 7 mol-%. The polymer composition has a standard viscosity of >2.0 mPas, measured at 0.1 weight-% solids content in an aqueous NaCl solution (1 M), at 25° C., using Brookfield VII T viscometer with UL adapter. The invention relates also to uses of said polymer composition.

Abstract: A method for manufacture of paper, board or the like, comprising the step of dissolving a composition into aqueous solution, whereby an aqueous treatment solution is obtained for adding the obtained treatment solution to the pulp. The composition comprising a copolymer of acrylamide and at least one cationic monomer, the copolymer comprising cationic monomers at least 15 mol-%, calculated from total amount of monomers, and an ionic crosslinker agent comprising at least two carboxyl groups, wherein the equivalent ratio of carboxyl groups:cationic monomer is between 1:20 and 1:0.5.

Abstract: The invention relates to an aqueous dry strength composition suitable for use in manufacture of paper, board or the like. The composition includes a mixture of a synthetic polymer component, which is a copolymer of acrylamide and at least one anionic monomer, and a cationic starch component. The polymer component has an anionicity of 1-60 mol-%. The synthetic polymer component and cationic starch component provide the composition with a charge density in the range of 0.05-1 meq/g, when measured at pH 2.8, and 0.2-?3 meq/g, when measured at pH 7.0. The invention also relates to a method for making of paper, board or the like, where the dry strength composition is diluted with water, and the solution of the dry strength composition is added to the fibre stock before or after the addition of a cationic strength agent.

Abstract: A method for manufacturing paper or board is disclosed and further disclosed is an internal sizing system for providing improved retention of hydrophobic internal sizing agents. The internal sizing system includes a hydrophobic internal sizing agent as a first component selected from a group consisting of alkenyl succinic anhydride (ASA), alkyl ketene dimer (AKD), rosin sizes and any combination thereof, and a water-soluble polymer product including amphoteric polyacrylamide as a second component, which amphoteric polyacrylamide has neutral or cationic net charge at pH 7, a weight-average molecular weight of 700,000-18,000,000 g/mol and a total ionicity of 4-28 mol-%, where the first component and the second component are provided as separate components or as a combination of the first component and the second component.

Abstract: Drainage and press dewatering system for manufacture of paper, board or the like, comprising (a) amphoteric polyacrylamide, which is a copolymer obtained by polymerizing (meth)acrylamide and 1-80 mol-% of cationic monomers and/or 0.1-70 mol-% of anionic monomers, the polyacrylamide having an intrinsic viscosity in the range of 6-38 dl/g, (b) inorganic microparticles of siliceous material, such as colloidal silica or bentonite, and (c) a high-charged cationic coagulant having a charge density over 5 meq/g and preferably over 6 meq/g determined at pH 6 and selected from aluminium based coagulants, organic polymers and mixtures thereof.

Abstract: The invention relates to a method for treating starch in pulp, paper and board making processes, in which processes recycled fibre material is used as raw material wherein the recycled fibre material is pulped in a pulper and obtaining a pulp flow comprising an aqueous phase and at least recycled fibres and starch dispersed in the aqueous phase. The method comprising the following steps: —adding amylase enzyme inhibitor and/or at least one biocide to pulp flow or to an aqueous process flow comprising starch for preventing starch degradation, and—adding an amphoteric polymer obtained by copolymerisation of (meth)acrylamide with cationic and anionic monomers to pulp flow or to an aqueous process flow comprising starch for binding starch to the fibres.

Abstract: The invention relates to a water-soluble polymer product in particle form, comprising amphoteric polyacrylamide, which is obtained by gel polymerisation of acrylamide together with anionic and cationic monomers. The amphoteric polyacrylamide has a mass average molecular weight MW of 1 500 000-6 000 000 g/mol, and a total ionicity of 4-15 mol-%, whereby the polymer product has a polymer content of at least 60 weight-%. The invention relates also to uses of the polymer product in paper and board making.

Abstract: A cationic glyoxylated polyacrylamide polymer composition having improved storage stability for use in manufacture of paper, board or the like, which aqueous composition includes a glyoxylated polyacrylamide polymer having a cationic charge density in a range of 0.8-1.8 meq/g of dry polymer in dry content of 5-15% and a buffering acid. The aqueous composition has pH in a range of 2.2-4.0 and a viscosity of less than 80 mPas measured at 25° C. by using a Brookfield viscometer after 30 days storage at 35° C. or after 60 days storage at 23° C.

Abstract: A method is disclosed for dewatering of sludge from a pulp, paper or board making process, such as deinking sludge, including obtaining of an aqueous sludge including an aqueous phase and a fibre material suspended in the aqueous phase. The sludge is subjected to a pre-thickening step, where a first part of the aqueous phase is removed from the sludge and to a pressing step, where a second part of the aqueous phase is removed from the sludge, thereby obtaining a dry pressed sludge. Before or at the pre-thickening step a polymer composition having a charge density of at the most 1.7 meq/g, preferably at most 1.5 meq/g, more preferably at most 1.1 meq/g, is added to the sludge.

Abstract: A polymer composition includes a first host polymer, which is a copolymer of (meth)acrylamide and at least one cationic first monomer, and a second polymer, which is a copolymer of (meth)acrylamide and at least one cationic second monomer. The second polymer is polymerised in presence of the first host polymer, and the first host polymer has a higher cationicity than the second polymer, the difference in cationicity of the first host polymer and the second polymer being at least 3 mol-%, at least 5 mol-%, more preferably at least 7 mol-%. The polymer composition has a standard viscosity of >2.0 mPas, measured at 0.1 weight-% solids content in an aqueous NaCl solution (1 M), at 25° C., using Brookfield VII T viscometer with UL adapter. The invention relates also to uses of said polymer composition.

Abstract: The invention relates to a composition for sizing of a surface of paper, board or the like and its use for increasing strength properties of paper, board or the like. The composition has a solids content of 3-30%, and it comprises degraded non-ionic starch, and at least 0.5 weight-% of anionic polyacrylamide, which has a molecular weight, MW, >500 000 g/mol and <2 500 000 g/mol and an anionicity in the range of 4-35 mol-%. The invention further relates also to a method for producing paper, board or the like, which comprises addition of a first strength composition, which comprises a cationic agent, to a fiber stock, formation of a fibrous web from the fiber stock, drying of the fibrous web to dryness of at least 60%, and application of a second strength composition, which comprises an anionic hydrophilic polymer and a starch component, on the surface of the fibrous web.

Abstract: The invention relates to an aqueous dry strength composition suitable for use in manufacture of paper, board or the like. The composition includes a mixture of a synthetic polymer component, which is a copolymer of acrylamide and at least one anionic monomer, and a cationic starch component. The polymer component has an anionicity of 1-60 mol-%. The synthetic polymer component and cationic starch component provide the composition with a charge density in the range of 0.05-1 meq/g, when measured at pH 2.8, and 0.2-?3 meq/g, when measured at pH 7.0. The invention also relates to a method for making of paper, board or the like, where the dry strength composition is diluted with water, and the solution of the dry strength composition is added to the fibre stock before or after the addition of a cationic strength agent.

Abstract: The present invention relates to a process for producing microcellulose comprising subjecting fibrous cellulosic material to acid hydrolysis at a temperature from 10° C. to less than 140° C. and at a consistency of at least 8% on dry weight of the cellulose, wherein the amount of added acid is from 0.2 to 2%, preferably from 0.3 to 1.9%, more preferably from 0.5 to 1.5% on dry weight of the cellulose.

Abstract: A method for manufacture of paper, board or the like, comprising the step of dissolving a composition into aqueous solution, whereby an aqueous treatment solution is obtained for adding the obtained treatment solution to the pulp. The composition comprising a copolymer of acrylamide and at least one cationic monomer, the copolymer comprising cationic monomers at least 15 mol-%, calculated from total amount of monomers, and an ionic crosslinker agent comprising at least two carboxyl groups, wherein the equivalent ratio of carboxyl groups:cationic monomer is between 1:20 and 1:0.5.

Abstract: Drainage and press dewatering system for manufacture of paper, board or the like, comprising (a) amphoteric polyacrylamide, which is a copolymer obtained by polymerizing (meth)acrylamide and 1-80 mol-% of cationic monomers and/or 0.1-70 mol-% of anionic monomers, the polyacrylamide having an intrinsic viscosity in the range of 6-38 dl/g, (b) inorganic microparticles of siliceous material, such as colloidal silica or bentonite, and (c) a high-charged cationic coagulant having a charge density over 5 meq/g and preferably over 6 meq/g determined at pH 6 and selected from aluminium based coagulants, organic polymers and mixtures thereof.

Abstract: The invention provides new water soluble polymers for the use in industrial processes, where large quantities of water is handled, such as sludge dewatering and papermaking. These new polymers are water soluble cross-linked block copolymers, wherein the block copolymers are cross-linked together using a cross-linking agent. Each of the block copolymers contain two different blocks, and these blocks are formed from different monomers. The blocks are linked together with a molecular spacer derived from a bifunctional initiator used during the polymerization of the blocks. The monomers used in polymerizing the blocks are different with each other and they are selected from a group consisting of N-vinylformamide, acrylic acid, acrylamide and water-soluble derivatives thereof.

Abstract: The invention relates to a method for treating starch in pulp, paper and board making processes, in which processes recycled fibre material is used as raw material wherein the recycled fibre material is pulped in a pulper and obtaining a pulp flow comprising an aqueous phase and at least recycled fibres and starch dispersed in the aqueous phase. The method comprising the following steps: —adding amylase enzyme inhibitor and/or at least one biocide to pulp flow or to an aqueous process flow comprising starch for preventing starch degradation, and—adding an amphoteric polymer obtained by copolymerisation of (meth)acrylamide with cationic and anionic monomers to pulp flow or to an aqueous process flow comprising starch for binding starch to the fibres.

Abstract: The invention relates to a water-soluble polymer product in particle form, comprising amphoteric polyacrylamide, which is obtained by gel polymerisation of acrylamide together with anionic and cationic monomers. The amphoteric polyacrylamide has a mass average molecular weight MW of 1500000-6000000 g/mol, and a total ionicity of 4-15 mol-%, whereby the polymer product has a polymer content of at least 60 weight-%. The invention relates also to uses of the polymer product in paper and board making.