Abstract: A fluorocopolymer which comprises (a) polymerized units based on tetrafluoroethylene and/or chlorotrifluoroethylene, (b) polymerized units based on a fluorinated monomer (excluding tetrafluoroethylene and chlorotrifluoroethylene) and (c) polymerized units based on at least one member selected from the group consisting of itaconic acid, itaconic anhydride, citraconic acid and citraconic anhydride, wherein (a) is from 50 to 99.8 mol %, (b) is from 0.1 to 49.99 mol %, and (c) is from 0.01 to 5 mol %, based on ((a)+(b)+(c)), and which has a volume flow rate of from 0.1 to 1000 mm3/sec.

Abstract: A laminate tube which comprises a layer made of a fluorocopolymer containing repeating units based on at least one fluoromonomer selected from the group consisting of tetrafluoroethylene and chlorotrifluoroethylene and repeating units based on at least one functional monomer selected from the group consisting of an acid anhydride having a polymerizable unsaturated bond and a dicarboxylic acid having a polymerizable unsaturated bond, and a layer made of a non-fluororesin directly laminated, and has a haze of from 0.1 to 30%. The laminate tube is excellent in transparency, excellent in interlaminar adhesion and anti-elution properties, excellent in liquid and gas barrier properties and applicable to transportation of a liquid such as a beverage and a coating composition.

Abstract: A laminate hose comprising a laminate of a fluorocopolymer and a polyamide, wherein the fluorocopolymer comprises repeating units (a) based on tetrafluoroethylene and/or chlorotrifluoroethylene, repeating units (b) based on a cyclic hydrocarbon monomer having a dicarboxylic anhydride group and having a polymerizable unsaturated group in the ring, and repeating units (c) based on another fluoromonomer (excluding tetrfluoroethylene and chlorofluoroethylene) with contents of the repeating units (a) of from 50 to 99.89 mol %, the repeating units (b) of from 0.01 to 5 mol % and the repeating units (c) of from 0.1 to 49.99 mol % based on the total number of mols of the repeating units (a), (b) and (c), and has a flow coefficient of from 0.1 to 1,000 mm3/sec.

Abstract: A fluorocopolymer which comprises repeating units (a) based on tetrafluoroethylene and/or chlorotrifluoroethylene, repeating units (b) based on a cyclic hydrocarbon monomer having a dicarboxylic anhydride group and an endocyclic polymerizable unsaturated group, and repeating units (c) based on other monomer, wherein the repeating units (a) are from 50 to 99.89 mol %, the repeating units (b) are from 0.01 to 5 mol % and the repeating units (c) are from 0.1 to 49.99 mol %, based on the total molar amount of the repeating units (a), (b) and (c), and which has a volume flow rate of from 0.1 to 1,000 mm3/sec., and a laminate and coated product thereof. The fluorocopolymer is excellent in adhesion, heat resistance, weather resistance, stress cracking resistance and fuel barrier properties. The laminate is excellent in interlaminar bonding and fuel barrier properties.

Abstract: (OBJECT) To provide a fluorocopolymer excellent in transparency and excellent in mechanical strength at room temperature and at high temperature, and a film made of it. (MEANS TO ACHIEVE THE OBJECT) A fluorocopolymer comprising polymerized units based on ethylene, polymerized units based on tetrafluoroethylene, polymerized units based on hexafluoropropylene and polymerized units based on a perfluoro(alkyl vinyl ether), characterized in that the molar ratio of polymerized units based on ethylene/polymerized units based on tetrafluoroethylene is from 10/90 to 60/40, the content of the polymerized units based on hexafluoropropylene is from 0.1 to 1.0 mol % based on the total polymerized units, and the content of the polymerized units based on a perfluoro(alkyl vinyl ether) is from 0.1 to 1.0 mol % based on the total polymerized units.

Abstract: A fluorocopolymer which comprises (a) polymerized units based on tetrafluoroethylene and/or chlorotrifluoroethylene, (b) polymerized units based on a fluorinated monomer (excluding tetrafluoroethylene and chlorotrifluoroethylene) and (c) polymerized units based on at least one member selected from the group consisting of itaconic acid, itaconic anhydride, citraconic acid and citraconic anhydride, wherein (a) is from 50 to 99.8 mol %, (b) is from 0.1 to 49.99 mol %, and (c) is from 0.01 to 5 mol %, based on ((a)+(b)+(c)), and which has a volume flow rate of from 0.1 to 1000 mm3/sec.

Abstract: A fluorocopolymer which comprises repeating units (a) based on tetrafluoroethylene and/or chlorotrifluoroethylene, repeating units (b) based on a cyclic hydrocarbon monomer having a dicarboxylic anhydride group and an endocyclic polymerizable unsaturated group, and repeating units (c) based on other monomer, wherein the repeating units (a) are from 50 to 99.89 mol %, the repeating units (b) are from 0.01 to 5 mol % and the repeating units (c) are from 0.1 to 49.99 mol %, based on the total molar amount of the repeating units (a), (b) and (c), and which has a volume flow rate of from 0.1 to 1,000 mm3/sec., and a laminate and coated product thereof. The fluorocopolymer is excellent in adhesion, heat resistance, weather resistance, stress cracking resistance and fuel barrier properties. The laminate is excellent in interlaminar bonding and fuel barrier properties.

Abstract: A tetrafluoroethylene/ethylene copolymer composition comprising a tetrafluoroethylene/ethylene copolymer (A) and a thermoplastic fluoropolymer (B) having a crystallization temperature higher than the crystallization temperature of said tetrafluoroethylene/ethylene copolymer (A) in a mass ratio of (A)/(B)=from 99.8/0.2 to 1/99. The composition is excellent in melt processability, and its formed product is excellent in mechanical properties and fuel barrier properties.

Abstract: A fluorocopolymer which comprises (a) polymerized units based on tetrafluoroethylene and/or chlorotrifluoroethylene, (b) polymerized units based on a fluorinated monomer (excluding tetrafluoroethylene and chlorotrifluoroethylene) and (c) polymerized units based on at least one member selected from the group consisting of itaconic acid, itaconic anhydride, citraconic acid and citraconic anhydride, wherein (a) is from 50 to 99.8 mol %, (b) is from 0.1 to 49.99 mol %, and (c) is from 0.01 to 5 mol %, based on ((a)+(b)+(c)), and which has a volume flow rate of from 0.1 to 1000 mm3/sec.

Abstract: A molding material consisting of a fluorine-containing copolymer, which has a metal elution index ? of at most 10 as the total amount in ng of metals of Na, Mg, Cu, Cr, Ni, K, Ca and Fe per 1 g of the molding material, as obtained by elution analysis of the molding material with nitric acid.

Abstract: A multi-layer hose having a multi-layer structure comprising an inner layer (I) made of a fluorocopolymer and an outer layer (II) made of a polyamide resin, wherein the fluorocopolymer constituting the inner layer (I) is a fluorocopolymer which comprises polymerized units (a) based on tetrafluoroethylene, polymerized units (b) based on ethylene and polymerized units (c) based on itaconic anhydride and/or citraconic anhydride, wherein the molar ratio of (a)/(b) is from 20/80 to 80/20 and the molar ratio of (c)/((a)+(b)) is from 1/10,000 to 5/100 and which has a volume flow rate of from 1 to 1,000 mm3/sec., and the polyamide resin constituting the outer layer (II) is polyamide 11 and/or polyamide 12, which satisfies a condition of (terminal amino group concentration)/(terminal carboxyl group concentration)>1.

Abstract: A multi-layer hose having a multi-layer structure comprising an inner layer (I) made of a fluorocopolymer and an outer layer (II) made of a polyamide resin, wherein the fluorocopolymer constituting the inner layer (I) is a fluorocopolymer which comprises polymerized units (a) based on tetrafluoroethylene, polymerized units (b) based on ethylene and polymerized units (c) based on itaconic anhydride and/or citraconic anhydride, wherein the molar ratio of (a)/(b) is from 20/80 to 80/20 and the molar ratio of (c)/((a)+(b)) is from 1/10,000 to 5/100 and which has a volume flow rate of from 1 to 1,000 mm3/sec., and the polyamide resin constituting the outer layer (II) is polyamide 11 and/or polyamide 12, which satisfies a condition of (terminal amino group concentration)/(terminal carboxyl group concentration)>1.

Abstract: A fluorocopolymer which comprises (A) polymerized units based on tetrafluoroethylene, (B) polymerized units based on ethylene and (C) polymerized units based on itaconic anhydride or citraconic anhydride, wherein the molar ratio of (A)/(B) is from 20/80 to 80/20, and the molar ratio of (C)/((A)+(B)) is from 1/10000 to 5/100, and which has a volume flow rate of from 1 to 1000 mm3/sec. The fluorocopolymer is excellent in the fuel barrier properties and in the adhesive properties to a non-fluorinated polymer.

Abstract: A fluorocopolymer which comprises (A) polymerized units based on tetrafluoroethylene, (B) polymerized units based on ethylene and (C) polymerized units based on a compound represented by CH2═CX(CF2)2Y (wherein each of X and Y which are independent of each other, is a hydrogen atom or a fluorine atom), wherein the molar ratio of (A)/(B) is from 20/80 to 80/20, and the molar ratio of (C)/((A)+(B)) is from 1/1000 to 15/100, and which has a volume flow rate of from 1 to 1000 mm3/sec. The fluorocopolymer has a low fuel permeability coefficient and is excellent in the fuel barrier properties.

Abstract: A tetrafluoroethylene/ethylene copolymer composition comprising a tetrafluoroethylene/ethylene copolymer (A) and a thermoplastic fluoropolymer (B) having a crystallization temperature higher than the crystallization temperature of said tetrafluoroethylene/ethylene copolymer (A) in a mass ratio of (A)/(B)=from 99.8/0.2 to 1/99. The composition is excellent in melt processability, and its formed product is excellent in mechanical properties and fuel barrier properties.

Abstract: A tetrafluoroethylene (TFE)/perfluoro (alkyl vinyl ether) (PVE) copolymer and a method for producing the copolymer, wherein the molar ratio of polymerized units based on TFE/polymerized units based on PVE is in the range of from 98.1/1.9 to 95.0/5.0, and its melt flow rate at 372° C. is from 35 to 60 g/10 min., and a weight-average molecular weight/a number-average molecular weight is from 1 to 1.7. The copolymer of TFE/PVE is excellent in the mechanical properties and the injection molding properties.

Abstract: A fluorocopolymer which comprises (A) polymerized units based on tetrafluoroethylene, (B) polymerized units based on ethylene and (C) polymerized units based on itaconic anhydride or citraconic anhydride, wherein the molar ratio of (A)/(B) is from 20/80 to 80/20, and the molar ratio of (C)/((A)+(B)) is from 1/10000 to 5/100, and which has a volume flow rate of from 1 to 1000 mm3/sec. The fluorocopolymer is excellent in the fuel barrier properties and in the adhesive properties to a non-fluorinated polymer.

Abstract: A fluorocopolymer which comprises (a) polymerized units based on tetrafluoroethylene and/or chlorotrifluoroethylene, (b) polymerized units based on a fluorinated monomer (excluding tetrafluoroethylene and chlorotrifluoroethylene) and (c) polymerized units based on at least one member selected from the group consisting of itaconic acid, itaconic anhydride, citraconic acid and citraconic anhydride, wherein (a) is from 50 to 99.8 mol %, (b) is from 0.1 to 49.99 mol %, and (c) is from 0.01 to 5 mol %, based on ((a)+(b)+(c)), and which has a volume flow rate of from 0.1 to 1000 mm3/sec.

Abstract: A fluorocopolymer which comprises (A) polymerized units based on tetrafluoroethylene, (B) polymerized units based on ethylene and (C) polymerized units based on itaconic anhydride or citraconic anhydride, wherein the molar ratio of (A)/(B) is from 20/80 to 80/20, and the molar ratio of (C)/((A)+(B)) is from 1/10000 to 5/100, and which has a volume flow rate of from 1 to 1000 mm3/sec. The fluorocopolymer is excellent in the fuel barrier properties and in the adhesive properties to a non-fluorinated polymer.

Abstract: A fluorocopolymer which comprises (A) polymerized units based on tetrafluoroethylene, (B) polymerized units based on ethylene and (C) polymerized units based on a compound represented by CH2═CX(CF2)2Y (wherein each of X and Y which are independent of each other, is a hydrogen atom or a fluorine atom), wherein the molar ratio of (A)/(B) is from 20/80 to 80/20, and the molar ratio of (C)/((A)+(B)) is from 1/1000 to 15/100, and which has a volume flow rate of from 1 to 1000 mm3/sec. The fluorocopolymer has a low fuel permeability coefficient and is excellent in the fuel barrier properties.