Patents by Inventor Attilio Siani

Attilio Siani has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20170320048
    Abstract: A layered catalyst composite for the treatment of exhaust gas emissions, effective to provide lean NOx trap functionality and three-way conversion functionality is described. Layered catalyst composites can comprise catalytic material on a substrate, the catalytic material comprising at least two layers. The first layer comprising rare earth oxide-high surface area refractory metal oxide particles, an alkaline earth metal supported on the rare earth oxide-high surface area refractory metal oxide particles, and at least one first platinum group metal component supported on the rare earth oxide-high surface area refractory metal oxide particles. The second layer comprising a second platinum group metal component supported on a first oxygen storage component (OSC) and/or a first refractory metal oxide support and, optionally, a third platinum group metal supported on a second refractory metal oxide support or a second oxygen storage component.
    Type: Application
    Filed: July 21, 2017
    Publication date: November 9, 2017
    Inventors: Wen-Mei Xue, Attilio Siani, John K. Hochmuth, Markus Kinne, Stefan Kielbassa
  • Patent number: 9744529
    Abstract: A layered catalyst composite for the treatment of exhaust gas emissions, effective to provide lean NOx trap functionality and three-way conversion functionality is described. Layered catalyst composites can comprise catalytic material on a substrate, the catalytic material comprising at least two layers. The first layer comprising rare earth oxide-high surface area refractory metal oxide particles, an alkaline earth metal supported on the rare earth oxide-high surface area refractory metal oxide particles, and at least one first platinum group metal component supported on the rare earth oxide-high surface area refractory metal oxide particles. The second layer comprising a second platinum group metal component supported on a first oxygen storage component (OSC) and/or a first refractory metal oxide support and, optionally, a third platinum group metal supported on a second refractory metal oxide support or a second oxygen storage component.
    Type: Grant
    Filed: March 16, 2015
    Date of Patent: August 29, 2017
    Assignee: BASF Corporation
    Inventors: Wen-Mei Xue, Attilio Siani, John K. Hochmuth, Markus Kinne, Stefan Kielbassa
  • Patent number: 9687818
    Abstract: The present invention relates to a process for preparing a catalyst, at least comprising the steps of adding a protecting agent to an aqueous solution of a metal precursor to give a mixture (M1), adding a reducing agent to mixture (M1) to give a mixture (M2), adding a support material to mixture (M2) to give a mixture (M3), adjusting the pH of mixture (M3), and separating the solid and liquid phase of mixture (M3). Furthermore, the present invention relates to the catalyst as such and its use as diesel oxidation catalyst.
    Type: Grant
    Filed: October 21, 2013
    Date of Patent: June 27, 2017
    Assignee: BASF Corporation
    Inventors: Attilio Siani, Torsten W. Müller-Stach, Torsten Neubauer, Xinyi Wei
  • Patent number: 9266092
    Abstract: Provided are catalyst composites whose catalytic material is effective to substantially simultaneously oxidize carbon monoxide and hydrocarbons and reduce nitrogen oxides. The catalyst composites have a two-metal layer on a carrier, the two-metal layer comprising a rhodium component supported by a first support comprising a refractory metal oxide component or a first ceria-zirconia composite; a palladium component supported by a second support comprising a second ceria-zirconia composite; one or more of a promoter, stabilizer, or binder; wherein the amount of the total of the first and second ceria-zirconia composites in the two-metal layer is equal to or greater than the amount of the refractory metal oxide component. Methods of making and using the same are also provided.
    Type: Grant
    Filed: January 17, 2014
    Date of Patent: February 23, 2016
    Assignee: BASF CORPORATION
    Inventors: Mirko Arnold, Stefan Kotrel, Attilio Siani, Stephan Siemund, Thomas Schmitz, Burkhard Rabe, Gary A Gramiccioni, Oliver Seel, Torsten Neubauer, Knut Wassermann
  • Publication number: 20150266014
    Abstract: A layered catalyst composite for the treatment of exhaust gas emissions, effective to provide lean NOx trap functionality and three-way conversion functionality is described. Layered catalyst composites can comprise catalytic material on a substrate, the catalytic material comprising at least two layers. The first layer comprising rare earth oxide-high surface area refractory metal oxide particles, an alkaline earth metal supported on the rare earth oxide-high surface area refractory metal oxide particles, and at least one first platinum group metal component supported on the rare earth oxide-high surface area refractory metal oxide particles. The second layer comprising a second platinum group metal component supported on a first oxygen storage component (OSC) and/or a first refractory metal oxide support and, optionally, a third platinum group metal supported on a second refractory metal oxide support or a second oxygen storage component.
    Type: Application
    Filed: March 16, 2015
    Publication date: September 24, 2015
    Inventors: Wen-Mei Xue, Attilio Siani, John K. Hochmuth, Markus Kinne, Stefan Kielbassa
  • Patent number: 8858904
    Abstract: Described is a catalyzed soot filter wherein the inlet coating of the filter comprises an oxidation catalyst comprising platinum (Pt) and optionally palladium (Pd), wherein the outlet coating of the filter comprises an oxidation catalyst comprising Pd and optionally Pt, wherein the Pt concentration in the outlet coating is lower than the Pt concentration in the inlet coating and wherein the weight ratio of Pt:Pd in the outlet coating is in the range of from 0:1 to 2:1; and wherein the inlet coating and the outlet coating are present on the wall flow substrate at a coating loading ratio in the range of from 0.5 to 1.5, calculated as ratio of the loading of the inlet coating (in g/inch3 (g/(2.54 cm)3)):loading of the outlet coating (in g/inch3 (g/(2.54 cm)3)). Systems include such catalyzed soot filters, methods of diesel engine exhaust gas treatment and methods of manufacturing catalyzed soot filters are also described.
    Type: Grant
    Filed: February 22, 2011
    Date of Patent: October 14, 2014
    Assignee: BASF Corporation
    Inventors: Alfred Helmut Punke, Gerd Grubert, Yuejin Li, Ruediger Wolff, Stanley Roth, Torsten Müller-Stach, Attilio Siani, Kenneth Voss, Torsten Neubauer
  • Patent number: 8815189
    Abstract: Exhaust systems and components are suitable for use with gasoline engines to capture particulates and to reduce gaseous emissions, where three-way conversion (TWC) catalysts located on a particulate filters are provided. Coated particle filters having washcoat loadings in the range of 1 to 4 g/ft3 result in minimal impact on back pressure while simultaneously providing TWC catalytic activity and particle trapping functionality to meet increasingly stringent regulations such as Euro 6. Sufficient to high levels of oxygen storage components (OSC) are also delivered on and/or within the filter. The filters can have a coated porosity that is substantially the same as its uncoated porosity. The TWC catalytic material can comprise a particle size distribution such that a first set of particles has a first d90 particle size of 7.5 ?m or less and a second set of particles has a second d90 particle size of more than 7.5 ?m.
    Type: Grant
    Filed: April 15, 2011
    Date of Patent: August 26, 2014
    Assignee: BASF Corporation
    Inventors: Mirko Arnold, Stephan Siemund, Attilio Siani, Knut Wassermann
  • Publication number: 20140205523
    Abstract: Provided are catalyst composites whose catalytic material is effective to substantially simultaneously oxidize carbon monoxide and hydrocarbons and reduce nitrogen oxides. The catalyst composites have a two-metal layer on a carrier, the two-metal layer comprising a rhodium component supported by a first support comprising a refractory metal oxide component or a first ceria-zirconia composite; a palladium component supported by a second support comprising a second ceria-zirconia composite; one or more of a promoter, stabilizer, or binder; wherein the amount of the total of the first and second ceria-zirconia composites in the two-metal layer is equal to or greater than the amount of the refractory metal oxide component. Methods of making and using the same are also provided.
    Type: Application
    Filed: January 17, 2014
    Publication date: July 24, 2014
    Applicants: BASF SE, BASF Corporation
    Inventors: Mirko Arnold, Stefan Kotrel, Attilio Siani, Stephan Siemund, Thomas Schmitz, Burkhard Rabe, Gary A. Gramiccioni, Oliver Seel, Torsten Neubauer, Knut Wassermann
  • Publication number: 20140044627
    Abstract: The present invention relates to a process for preparing a catalyst, at least comprising the steps of adding a protecting agent to an aqueous solution of a metal precursor to give a mixture (M1), adding a reducing agent to mixture (M1) to give a mixture (M2), adding a support material to mixture (M2) to give a mixture (M3), adjusting the pH of mixture (M3), and separating the solid and liquid phase of mixture (M3). Furthermore, the present invention relates to the catalyst as such and its use as diesel oxidation catalyst.
    Type: Application
    Filed: October 21, 2013
    Publication date: February 13, 2014
    Applicant: BASF Corporation
    Inventors: Attilio Siani, Torsten W. Müller-Stach, Torsten Neubauer, Xinyi Wei
  • Patent number: 8617496
    Abstract: Provided are exhaust systems and components suitable for use in conjunction with gasoline engines to treat gaseous emissions such as hydrocarbons, nitrogen oxides, and carbon monoxides. Layered three-way conversion (TWC) catalysts comprise an outer layer whose rhodium is supported by an oxygen storage component, such as a ceria-zirconia composite, and the outer layer is substantially free from alumina as a support. The rhodium-containing layer can be free of all other precious metals, such as platinum and palladium. A lower palladium layer is provided where the palladium is supported by a refractory metal oxide. The lower palladium layer can be free of rhodium and platinum and can contain an oxygen storage component that is the same or different from that in the rhodium-containing layer. Methods of making and using these catalysts are also provided.
    Type: Grant
    Filed: January 13, 2012
    Date of Patent: December 31, 2013
    Assignee: BASF Corporation
    Inventors: Junmei Wei, Attilio Siani, Mirko Arnold, Stefan Kotrel, Stephan Siemund, Knut Wassermann
  • Publication number: 20130142714
    Abstract: Diesel oxidation catalysts comprising a first washcoat layer including a platinum group metal impregnated on a promoted non-zeolitic support are described. The promoter is one or more of tin, manganese, indium, group VIII metals. Methods of making and using the diesel oxidation catalyst, including emissions treatment systems, are also described.
    Type: Application
    Filed: December 1, 2011
    Publication date: June 6, 2013
    Applicant: BASF Catalysts LLC
    Inventors: Shiang Sung, Stanley A. Roth, Torsten W. Mueller-Stach, Attilio Siani
  • Patent number: 8449852
    Abstract: Diesel oxidation catalysts comprising a first washcoat layer including a platinum group metal impregnated on a promoted non-zeolitic support are described. The promoter is one or more of tin, manganese, indium, group VIII metals. Methods of making and using the diesel oxidation catalyst, including emissions treatment systems, are also described.
    Type: Grant
    Filed: December 1, 2011
    Date of Patent: May 28, 2013
    Assignee: BASF Corporation
    Inventors: Shiang Sung, Stanley A. Roth, Torsten W. Mueller-Stach, Attilio Siani
  • Patent number: 8252258
    Abstract: Provided is a diesel oxidation catalyst for the treatment of exhaust gas emissions from a diesel engine and a method for treating a diesel exhaust gas stream, the method comprising providing a diesel oxidation catalyst and contacting said diesel exhaust gas stream with said diesel oxidation catalyst for the treatment of exhaust gas emissions. More particularly, the present invention is directed to a catalyst structure comprising three distinct layers; in which layer comprises a precious metal component such as palladium is located between two hydrocarbon storage layers comprising a molecular sieve such as a zeolite.
    Type: Grant
    Filed: January 13, 2010
    Date of Patent: August 28, 2012
    Assignee: BASF Corporation
    Inventors: Torsten W. Müller-Stach, Torsten Neubauer, Alfred H. Punke, Gerd Grubert, Attilio Siani, Corinna Freitag
  • Publication number: 20120180464
    Abstract: Provided are exhaust systems and components suitable for use in conjunction with gasoline engines to treat gaseous emissions such as hydrocarbons, nitrogen oxides, and carbon monoxides. Layered three-way conversion (TWC) catalysts comprise an outer layer whose rhodium is supported by an oxygen storage component, such as a ceria-zirconia composite, and the outer layer is substantially free from alumina as a support. The rhodium-containing layer can be free of all other precious metals, such as platinum and palladium. A lower palladium layer is provided where the palladium is supported by a refractory metal oxide. The lower palladium layer can be free of rhodium and platinum and can contain an oxygen storage component that is the same or different from that in the rhodium-containing layer. Methods of making and using these catalysts are also provided.
    Type: Application
    Filed: January 13, 2012
    Publication date: July 19, 2012
    Applicant: BASF Corporation
    Inventors: Junmei Wei, Attilio Siani, Mirko Arnold, Stefan Kotrel, Stephan Siemund, Knut Wassermann
  • Patent number: 8211392
    Abstract: Provided is a catalyst composition, in particular a diesel oxidation catalyst, for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO). More particularly, the present invention is directed to a catalyst structure comprising at least two, specifically three distinct layers, at least one of which contains an oxygen storage component (OSC) that is present in a layer separate from the majority of the platinum group metal (PGM) components, such as palladium and platinum.
    Type: Grant
    Filed: January 13, 2010
    Date of Patent: July 3, 2012
    Assignee: BASF Corporation
    Inventors: Gerd Grubert, Torsten Neubauer, Alfred H. Punke, Torsten W. Müller-Stach, Attilio Siani, Stanley A. Roth, Jeffrey B. Hoke, Shiang Sung, Yuejin Li, Xinyi Wei, Michel Deeba
  • Publication number: 20120077669
    Abstract: Described is a process for the preparation of a catalyst comprising the steps of: (i) providing one or more support materials; (ii) providing one or more polymers on the support material; and (iii) providing one or more metals on the one or more supported polymers; wherein in step (ii) the one or more polymers do not comprise cross-linked polymers and/or polymers which have been reacted with a cross-linking agent. Also described is a catalyst obtained or obtainable according to said process, as well as the use of the catalyst, in particular in a method for the treatment of automobile engine exhaust gas.
    Type: Application
    Filed: September 28, 2011
    Publication date: March 29, 2012
    Applicants: BASF Corporation, BASF SE
    Inventors: Torsten Müller-Stach, Attilio Siani, Torsten Neubauer, Xinyi Wei
  • Publication number: 20110252773
    Abstract: Provided are exhaust systems and components suitable for use in conjunction with gasoline engines to capture particulates in addition to reducing gaseous emission such as hydrocarbons, nitrogen oxides, and carbon monoxides. Exhaust treatment systems comprising a three-way conversion (TWC) catalyst located on a particulate filters are provided. Coated particle filters having washcoat loadings in the range of 1 to 4 g/ft3 result in minimal impact on back pressure while simultaneously providing TWC catalytic activity and particle trapping functionality to meet increasingly stringent regulations such as Euro 6. Sufficient to high levels of oxygen storage components (OSC) are also delivered on and/or within the filter. The filters can have a coated porosity that is substantially the same as its uncoated porosity. The TWC catalytic material can comprise a particle size distribution such that a first set of particles has a first d90 particle size of 7.
    Type: Application
    Filed: April 15, 2011
    Publication date: October 20, 2011
    Applicant: BASF Corporation
    Inventors: Mirko Arnold, Stephan Siemund, Attilio Siani, Knut Wassermann
  • Publication number: 20110212008
    Abstract: Described is a catalyzed soot filter wherein the inlet coating of the filter comprises an oxidation catalyst comprising platinum (Pt) and optionally palladium (Pd), wherein the outlet coating of the filter comprises an oxidation catalyst comprising Pd and optionally Pt, wherein the Pt concentration in the outlet coating is lower than the Pt concentration in the inlet coating and wherein the weight ratio of Pt:Pd in the outlet coating is in the range of from 0:1 to 2:1; and wherein the inlet coating and the outlet coating are present on the wall flow substrate at a coating loading ratio in the range of from 0.5 to 1.5, calculated as ratio of the loading of the inlet coating (in g/inch3 (g/(2.54 cm)3)):loading of the outlet coating (in g/inch3 (g/(2.54 cm)3)). Systems include such catalyzed soot filters, methods of diesel engine exhaust gas treatment and methods of manufacturing catalyzed soot filters are also described.
    Type: Application
    Filed: February 22, 2011
    Publication date: September 1, 2011
    Inventors: Alfred Helmut Punke, Gerd Grubert, Yuejin Li, Ruediger Wolff, Stanley Roth, Torsten Müeller-Stach, Attilio Siani, Kenneth Voss, Torsten Neubauer
  • Publication number: 20110033353
    Abstract: The present invention relates to a process for preparing a catalyst, at least comprising the steps of adding a protecting agent to an aqueous solution of a metal precursor to give a mixture (M1), adding a reducing agent to mixture (M1) to give a mixture (M2), adding a support material to mixture (M2) to give a mixture (M3), adjusting the pH of mixture (M3), and separating the solid and liquid phase of mixture (M3). Furthermore, the present invention relates to the catalyst as such and its use as diesel oxidation catalyst.
    Type: Application
    Filed: July 27, 2010
    Publication date: February 10, 2011
    Applicant: BASF Corporation
    Inventors: Attilio Siani, Torsten Muller-Stach, Torsten Neubauer, Xinyi Wei
  • Publication number: 20100180582
    Abstract: Provided is a diesel oxidation catalyst for the treatment of exhaust gas emissions from a diesel engine and a method for treating a diesel exhaust gas stream, the method comprising providing a diesel oxidation catalyst and contacting said diesel exhaust gas stream with said diesel oxidation catalyst for the treatment of exhaust gas emissions. More particularly, the present invention is directed to a catalyst structure comprising three distinct layers; in which layer comprises a precious metal component such as palladium is located between two hydrocarbon storage layers comprising a molecular sieve such as a zeolite.
    Type: Application
    Filed: January 13, 2010
    Publication date: July 22, 2010
    Applicant: BASF Catalysts LLC
    Inventors: Torsten Wolfgang Mueller-Stach, Torsten Neubauer, Alfred Helmut Punke, Gerd Grubert, Attilio Siani, Corinna Freitag