Abstract: The present invention relates to a catalytic bed comprising a particular photocatalytic catalyst. The bed comprises structuring particlesa made of inorganic material, b, combined with at least one semiconductor material, a, with photocatalytic properties, the combination being produced by mixing structuring particles made of inorganic material, b, with the semiconductor material, a, in the form of particles, —and/or by chemical or physicochemical deposition of the semiconductor material, a, on the structuring particles made of inorganic material, b, the structuring particles, b, being of substantially spherical shape and of mean diameter between 22 nm and 8.0 ?m.

Abstract: The invention concerns a method for the photocatalytic reduction of carbon dioxide carried out in the liquid phase and/or in the gas phase under irradiation using a photocatalyst comprising a support made from alumina or silica or silica-alumina and nanoparticles of molybdenum sulfide or tungsten sulfide having a band gap greater than 2.3 eV, said method comprising the following steps: a) bringing a feedstock containing carbon dioxide and at least one sacrificial compound into contact with said photocatalyst, b) irradiating the photocatalyst with at least one source of irradiation producing at least one wavelength smaller than the width of the band gap of said photocatalyst so as to reduce the carbon dioxide and oxidise the sacrificial compound in the presence of said photocatalyst activated by said source of irradiation, in such a way as to produce an effluent containing, at least in part, C1 or above carbon-containing molecules, different from CO2.

Abstract: A process for preparing a catalytic material of an electrode for electrochemical reduction reactions, said material comprising an active phase based on at least one group VIB metal and an electrically conductive support, which process is carried out according to at least the following steps: a) bringing water into contact with said electrically conductive support, b) bringing said wet support into contact with at least one metallic acid hydrate comprising at least one group VIB metal, of which the melting point of said metallic acid hydrate is between 20° C. and 100° C., the weight ratio of said metallic acid to said electrically conductive support being between 0.1 and 4, c) heating, with stirring, to a temperature between the melting point of said metallic acid hydrate and 100° C., d) carrying out a sulfurization step at a temperature of between 100° C. and 600° C.

Abstract: A method for preparing a catalytic material of an electrode for electrochemical reduction reactions, which comprises: a) a step of electrolysis of at least one aqueous and/or organic solution comprising at least one precursor of the active phase comprising at least one group VIB metal in order to obtain a solution comprising at least one precursor comprising at least one group VIB metal which has been partially reduced; b) a step of impregnation of said support with said solution obtained in step a) in order to obtain a catalytic material precursor; c) a step of drying said precursor obtained in step b) at a temperature below 250° C., without subsequent calcination; d) a step of sulfurization of the catalytic material precursor obtained in step c) at a temperature of between 100° C. and 600° C.

Abstract: A process for the preparation of a catalytic material of an electrode for electrochemical reduction reactions, said material comprising an active phase based on at least one metal from group VIb and an electroconductive support, which process is carried out according to at least the following stages: a stage of bringing said support into contact with at least one solution containing at least one precursor of at least one metal from group VIb; a drying stage at a temperature of less than 250° C., without a subsequent calcination stage; a stage of sulfurization at a temperature of between 100° C. and 600° C.

Abstract: The present invention relates to a process for hydroconversion of a heavy hydrocarbon feedstock in the presence of hydrogen, at least one supported solid catalyst and at least one dispersed solid catalyst obtained from at least one salt of a heteropolyanion combining molybdenum and at least one metal selected from cobalt and nickel in a Strandberg, Keggin, lacunary Keggin or substituted lacunary Keggin structure.

Abstract: A two-step hydrocracking process with a distillation step wherein a dividing wall distillation column is used, the dividing wall dividing the lower part of the column into two compartments, located in the section of the column located under the supply of said column with the unconverted effluent resulting from the first hydrocracking step. The distillation column is fed on either side of the vertical dividing wall with the liquid hydrocarbon effluent from the first hydrocracking step and with the liquid hydrocarbon effluent from the second hydrocracking step, allowing the concentration of the HPNAs contained in the effluent from the second hydrocracking step in a specific compartment of the column delimited by the dividing wall and avoiding the dilution of said HPNAs by the unconverted effluent from the first hydrocracking step. The present invention allows purging of purer HPNAs.

Abstract: The invention relates to a method for hydroprocessing a hydrocarbon feed, operated at a temperature of between 180° C. and 450° C., in the presence of a catalyst comprising i) a composite material comprising a compound based on at least one crystalline aluminium solid and carbon, the deposited carbon content being between 1 and 25 wt.

Abstract: The invention relates to a method for hydroprocessing a hydrocarbon feed, operated at a temperature of between 180° C. and 450° C., in the presence of a catalyst comprising i) a composite material comprising a compound based on at least one crystalline aluminium solid and carbon, the deposited carbon content being between 1 and 25 wt.

Abstract: The present invention relates to a process for hydroconversion of a heavy hydrocarbon feedstock in the presence of hydrogen, at least one supported solid catalyst and at least one dispersed solid catalyst obtained from at least one salt of a heteropolyanion combining molybdenum and at least one metal selected from cobalt and nickel in a Strandberg, Keggin, lacunary Keggin or substituted lacunary Keggin structure.

Abstract: The invention concerns a method for the photocatalytic reduction of carbon dioxide carried out in the liquid phase and/or in the gas phase under irradiation using a photocatalyst comprising a support made from alumina or silica or silica-alumina and nanoparticles of molybdenum sulfide or tungsten sulfide having a band gap greater than 2.3 eV, said method comprising the following steps: a) bringing a feedstock containing carbon dioxide and at least one sacrificial compound into contact with said photocatalyst, b) irradiating the photocatalyst with at least one source of irradiation producing at least one wavelength smaller than the width of the band gap of said photocatalyst so as to reduce the carbon dioxide and oxidise the sacrificial compound in the presence of said photocatalyst activated by said source of irradiation, in such a way as to produce an effluent containing, at least in part, C1 or above carbon-containing molecules, different from CO2.