Patents by Inventor Aurélien Vantomme
Aurélien Vantomme has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10550251Abstract: The present invention relates to a rotomolded article, comprising at least one metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B, wherein the polyethylene resin comprises: at least 25% to at most 55% by weight of polyethylene fraction A based on the total weight of the polyethylene resin, wherein fraction A has a melt index MI2 of at least 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg, and a density at least 0.005 g/cm3 higher than the density of the polyethylene resin; and wherein the polyethylene resin has a density of at least 0.938 g/cm3 to at most 0.950 g/cm3 as measured according to ASTM D-1505 at 23° C.; a melt index MI2 of at least 1.0 g/10 min to at most 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg. The present invention also relates to a process for preparing said rotomolded article.Type: GrantFiled: November 10, 2015Date of Patent: February 4, 2020Assignee: Total Research & Technology FeluyInventors: Aurélien Vantomme, Eric Maziers, Christopher Willocq
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Patent number: 10544245Abstract: The present invention relates to a process for preparing a polyethylene product having a multimodal molecular weight distribution, said process comprising the steps of: (a) feeding ethylene monomer, a diluent, at least one metallocene catalyst, optionally hydrogen, and optionally one or more olefin co-monomers into a first slurry loop reactor; and polymerizing the ethylene monomer, and the optionally one or more olefin co-monomers, in the presence of said at least one metallocene catalyst, and optionally hydrogen, in said first slurry loop reactor thereby producing a first polyethylene fraction; (b) feeding the first polyethylene fraction to a second slurry loop reactor serially connected to the first slurry loop reactor, and in the second slurry loop reactor polymerizing ethylene, and optionally one or more olefin co-monomers, in the presence of the first polyethylene fraction, and optionally hydrogen, thereby producing a second polyethylene fraction; and (c) feeding the second polyethylene fraction to a gasType: GrantFiled: July 13, 2016Date of Patent: January 28, 2020Assignee: Total Research & Technology FeluyInventors: Aurélien Vantomme, Christopher Willocq
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Patent number: 10538651Abstract: The present invention relates to a rotomolded article, comprising at least one layer, wherein said at least one layer comprising comprises at least one metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B; and at least one ionomer; wherein the polyethylene resin comprises: at least 25% to at most 55% by weight of polyethylene fraction A based on the total weight of the polyethylene resin, wherein fraction A has a density at least 0.005 g/cm3 higher than the density of the polyethylene resin; and wherein the polyethylene resin has a density of at least 0.930 g/cm3 to at most 0.954 g/cm3 as measured according to ASTM D-1505 at 23° C.; a melt index MI2 of at least 1.0 g/10 min to at most 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg. The present invention also relates to a process for preparing said rotomolded article.Type: GrantFiled: November 10, 2015Date of Patent: January 21, 2020Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Aurélien Vantomme, Eric Maziers, Christopher Willocq
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Patent number: 10501615Abstract: The present invention relates to a polypropylene composition comprising: a first polypropylene homopolymer or random copolymer (PPR1) having a comonomer content lower than the comonomer content of the second polypropylene, a second polypropylene (PPR2) which is a random copolymer of propylene and of the comonomer; said comonomer being an alpha-olefin different from propylene, the melting temperature of the polypropylene composition (Tm(PPR)) being defined as Tm(PPR)>165?6.9*[total comonomer content]?8.4*[comonomer content of the first polypropylene], the difference between the melting temperature and the crystallization temperature of the polypropylene composition ranges from 27 and 33, and a xylene soluble fraction (XS) at 23° C. of not more than 1.5 wt. %. The present invention also relates to a process for the preparation of said polypropylene composition. The present invention further relates to the use of said polypropylene composition for producing films or moulded articles.Type: GrantFiled: January 22, 2016Date of Patent: December 10, 2019Assignee: Total Research & Technology FeluyInventors: Alain Standaert, Kristien Roegiers, Aurélien Vantomme
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Patent number: 10465021Abstract: An uncompounded particulate metallocene-produced polyethylene can have a multimodal molecular weight distribution and particle size distribution measured by obtaining at least four fractions by sieving. A set of Mw values including an Mw value for each fraction can be obtained. A set of Mn values including an Mn value for each fraction can be obtained. A ratio between a standard deviation value of the Mw set and a mean value of the Mw set can be equal to or less than 0.15. A ratio between a standard deviation value of the Mn set and a mean value of the Mn set can be equal to or less than 0.15. The uncompounded particulate metallocene-produced polyethylene can be prepared by a process that includes polymerization in an apparatus. The apparatus can include at least three serially connected loop reactors.Type: GrantFiled: July 26, 2013Date of Patent: November 5, 2019Assignee: FINA TECHNOLOGY, INC.Inventors: Aurelien Vantomme, Christopher Willocq, Daan Dewachter
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Patent number: 10336892Abstract: The present invention relates to a metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B, wherein the polyethylene resin comprises: at least 25% to at most 55% by weight of polyethylene fraction A based on the total weight of the polyethylene resin, wherein fraction A has a density at least 0.005 g/cm3 higher than the density of the polyethylene resin; and a melt index MI2 of at least 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg; and wherein the polyethylene resin has a density of at least 0.938 g/cm3 to at most 0.954 g/cm3 as measured according to ASTM D-1505 at 23° C.; a melt index MI2 of at least 2.5 g/10 min to at most 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg and a molecular weight distribution Mw/Mn of at least 2.6 to at most 4.Type: GrantFiled: November 10, 2015Date of Patent: July 2, 2019Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Aurélien Vantomme, Eric Maziers, Christopher Willocq
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Publication number: 20190161565Abstract: The invention covers a supported catalyst system prepared according to a process comprising the following step: i). impregnating a silica-containing catalyst support having a specific surface area of from 150 m2/g to 800 m2/g, preferably 280 m2/g to 600 m2/g, with one or more titanium compounds of the general formula selected from RnTi(OR?)m and (RO)nTi(OR?)m, wherein R and R? are the same or different and are selected from hydrocarbyl groups containing from 1 to 12 carbon and halogens, and wherein n is 0 to 4, m is 0 to 4 and m+n equals 4, to form a titanated silica-containing catalyst support having a Ti content of at least 0.1 wt % based on the weight of the Ti-impregnated catalyst support wherein the supported catalyst system further comprises an alumoxane and a metallocene.Type: ApplicationFiled: January 30, 2019Publication date: May 30, 2019Inventors: Christopher Willocq, Aurélien Vantomme, Martine Slawinski
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Patent number: 10233268Abstract: The invention covers a supported catalyst system prepared according to a process comprising the following step: i). impregnating a silica-containing catalyst support having a specific surface area of from 150 m2/g to 800 m2/g, preferably 280 m2/g to 600 m2/g, with one or more titanium compounds of the general formula selected from RnTi(OR?)m and (RO)nTi(OR?)m, wherein R and R? are the same or different and are selected from hydrocarbyl groups containing from 1 to 12 carbon and halogens, and wherein n is 0 to 4, m is 0 to 4 and m+n equals 4, to form a titanated silica-containing catalyst support having a Ti content of at least 0.1 wt % based on the weight of the Ti-impregnated catalyst support wherein the supported catalyst system further comprises an alumoxane and a metallocene.Type: GrantFiled: July 1, 2011Date of Patent: March 19, 2019Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Christopher Willocq, Aurélien Vantomme, Martine Slawinski
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Publication number: 20190002603Abstract: Processes for preparing a polyethylene in at least one continuously stirred tank reactor are described herein. The process may comprise the step of: polymerizing ethylene in the presence of at least one supported metallocene catalyst, a diluent, optionally one or more co-monomers, and optionally hydrogen, thereby obtaining the polyethylene, wherein the supported metallocene catalyst comprises a solid support, a co-catalyst and at least one metallocene, wherein the solid support has a surface area within the range of from 100 to 500 m2/g, and has a D50 value within the range of from 4 ?m to 18 ?m, with D50 being defined as the particle size for which fifty percent by weight of the particles has a size lower than the D50; and D50 being measured by laser diffraction analysis on a Malvern type analyzer. Polyethylene obtained by the disclosed process and articles comprising the polyethylene are also described.Type: ApplicationFiled: September 10, 2018Publication date: January 3, 2019Inventors: Aurelien Vantomme, Christopher Willocq, Alexandre Welle, Martine Slawinski
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Publication number: 20180340058Abstract: The present invention relates to a polypropylene composition comprising: a first polypropylene homopolymer or random copolymer (PPR1) having a comonomer content lower than the comonomer content of the second polypropylene, a second polypropylene (PPR2) which is a random copolymer of propylene and of the comonomer; said comonomer being an alpha-olefin different from propylene, the melting temperature of the polypropylene composition (Tm(PPR)) being defined as Tm(PPR)>165?6.9*[total comonomer content]?8.4*[comonomer content of the first polypropylene], the difference between the melting temperature and the crystallization temperature of the polypropylene composition ranges from 27 and 33, and a xylene soluble fraction (XS) at 23° C. of not more than 1.5 wt. %. The present invention also relates to a process for the preparation of said polypropylene composition. The present invention further relates to the use of said polypropylene composition for producing films or moulded articles.Type: ApplicationFiled: January 22, 2016Publication date: November 29, 2018Inventors: Alain Standaert, Kristien Roegiers, Aurélien Vantomme
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Patent number: 10100135Abstract: Processes for preparing a polyethylene in at least one continuously stirred tank reactor are described herein. The process may comprise the step of: polymerizing ethylene in the presence of at least one supported metallocene catalyst, a diluent, optionally one or more co-monomers, and optionally hydrogen, thereby obtaining the polyethylene, wherein the supported metallocene catalyst comprises a solid support, a co-catalyst and at least one metallocene, wherein the solid support has a surface area within the range of from 100 to 500 m2/g, and has a D50 value within the range of from 4 ?m to 18 ?m, with D50 being defined as the particle size for which fifty percent by weight of the particles has a size lower than the D50; and D50 being measured by laser diffraction analysis on a Malvern type analyzer. Polyethylene obtained by the disclosed process and articles comprising the polyethylene are also described.Type: GrantFiled: June 11, 2015Date of Patent: October 16, 2018Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Aurelien Vantomme, Christopher Willocq, Alexandre Welle, Martine Slawinski
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Patent number: 10053522Abstract: A metallocene-catalyzed polyethylene resin having a multimodal molecular weight and composition distribution, comprising from 45% by weight to 75% by weight of a low density fraction, said fraction having a density below or equal to 918 g/cm3 as measured following the method of standard test ISO 1183 at a temperature of 23° C., wherein the density of the polyethylene resin is from 0.920 to 0.945 g/cm3, wherein the Mw/Mn of the polyethylene is of from 2.8 to 6, wherein the melt index MI2 of the polyethylene resin of from 0.1 to 5 g/10 min measured following the method of standard test ISO 1133 Condition D at a temperature of 190° C. and under a load of 2.16 kg; and wherein the composition distribution breadth index (CDBI) of the polyethylene resin is below 70%, as analyzed by quench TREF (temperature rising elution fractionation) analysis.Type: GrantFiled: July 6, 2012Date of Patent: August 21, 2018Assignee: Total Research & Technology FeluyInventors: Aurélien Vantomme, Pierre Bernard, Jacques Michel, Christopher Willocq, Armelle Sigwald
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Patent number: 10053563Abstract: A process may include providing a polyethylene post consumer resin, providing a virgin polyethylene resin, and blending the polyethylene post consumer resin with the virgin polyethylene resin to produce a composition. The polyethylene post consumer resin may have an ESCR of at most 10 hours, a density ranging from 0.950 to 0.967 g/cm3, and an HLMI of 40 to 70 g/10 min. The virgin polyethylene resin may include fractions A and B, with fraction A having a higher molecular weight and lower density than fraction B. Fraction A may have an HL275 of at least 0.1 g/10 min and of at most 4 g/10 min, and a density of at least 0.920 g/cm3 and of at most 0.942 g/cm. The virgin polyethylene resin may have an HLMI of 5 to 75 g/10 min, and a density ranging from 0.945 to 0.960 g/cm3.Type: GrantFiled: July 2, 2015Date of Patent: August 21, 2018Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Yves Trolez, Aurélien Vantomme, Jurjen Meeuwissen
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Patent number: 10016923Abstract: A polyethylene resin having a multimodal molecular weight distribution comprising at least two polyethylene fractions A and B, fraction A being substantially free of comonomer and having a lower weight average molecular weight and a higher density than fraction B, each fraction prepared in different reactors of two reactors connected in series in the presence of a Ziegler-Natta catalyst system, the polyethylene resin having a density of from 0.950 to 0.965 g/cm3 and a melt index MI2 of from 0.5 to 5 g/10 min.Type: GrantFiled: February 27, 2017Date of Patent: July 10, 2018Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Jean-Marie Boissiere, Aurélien Vantomme, Pierre Belloir, Alain Van Sinoy
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Publication number: 20170348891Abstract: A polyethylene resin having a multimodal molecular weight distribution comprising at least two polyethylene fractions A and B, fraction A being substantially free of comonomer and having a lower weight average molecular weight and a higher density than fraction B, each fraction prepared in different reactors of two reactors connected in series in the presence of a Ziegler-Natta catalyst system, the polyethylene resin having a density of from 0.950 to 0.965 g/cm3 and a melt index MI2 of from 0.5 to 5 g/10 min.Type: ApplicationFiled: February 27, 2017Publication date: December 7, 2017Applicant: Total Research & Technology FeluyInventors: Jean-Marie Boissiere, Aurélien Vantomme, Pierre Belloir, Alain Van Sinoy
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Patent number: 9821504Abstract: This invention covers injection stretch blow molded articles prepared from polyethylene resin having a bimodal molecular weight distribution (MWD), defined by the ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn), of from 2 to 20, comprising two polyethylene fractions A and B, fraction A being substantially free of comonomer and having a lower weight average molecular weight and a higher density than fraction B, each fraction prepared in different reactors of two reactors connected in series in the presence of a metallocene-containing catalyst system.Type: GrantFiled: January 10, 2012Date of Patent: November 21, 2017Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Jean-Marie Boissiere, Aurelien Vantomme, Pierre Belloir, Alain Van Sinoy
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Publication number: 20170321046Abstract: The present invention relates to a rotomolded article, comprising at least one metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B, wherein the polyethylene resin comprises: at least 25% to at most 55% by weight of polyethylene fraction A based on the total weight of the polyethylene resin, wherein fraction A has a melt index MI2 of at least 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg, and a density at least 0.005 g/cm3 higher than the density of the polyethylene resin; and wherein the polyethylene resin has a density of at least 0.938 g/cm3 to at most 0.950 g/cm3 as measured according to ASTM D-1505 at 23° C.; a melt index MI2 of at least 1.0 g/10 min to at most 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg. The present invention also relates to a process for preparing said rotomolded article.Type: ApplicationFiled: November 10, 2015Publication date: November 9, 2017Applicant: Total Research & Technology FeluyInventors: Aurélien Vantomme, Eric Maziers, Christopher Willocq
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Publication number: 20170321047Abstract: The present invention relates to a metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B, wherein the polyethylene resin comprises: at least 25% to at most 55% by weight of polyethylene fraction A based on the total weight of the polyethylene resin, wherein fraction A has a density at least 0.005 g/cm3 higher than the density of the polyethylene resin; and a melt index MI2 of at least 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg; and wherein the polyethylene resin has a density of at least 0.938 g/cm3 to at most 0.954 g/cm3 as measured according to ASTM D-1505 at 23° C.; a melt index MI2 of at least 2.5 g/10 min to at most 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg and a molecular weight distribution Mw/Mn of at least 2.6 to at most 4.Type: ApplicationFiled: November 10, 2015Publication date: November 9, 2017Inventors: Aurélien Vantomme, Eric Maziers, Christopher Willocq
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Publication number: 20170313863Abstract: The present invention relates to a rotomolded article, comprising at least one layer, wherein said at least one layer comprising comprises at least one metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B; and at least one ionomer; wherein the polyethylene resin comprises: at least 25% to at most 55% by weight of polyethylene fraction A based on the total weight of the polyethylene resin, wherein fraction A has a density at least 0.005 g/cm3 higher than the density of the polyethylene resin; and wherein the polyethylene resin has a density of at least 0.930 g/cm3 to at most 0.954 g/cm3 as measured according to ASTM D-1505 at 23° C.; a melt index MI2 of at least 1.0 g/10 min to at most 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg. The present invention also relates to a process for preparing said rotomolded article.Type: ApplicationFiled: November 10, 2015Publication date: November 2, 2017Inventors: Aurélien Vantomme, Eric Maziers, Christopher Willocq
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Patent number: 9670342Abstract: An injection stretch blow molded article may include a Ziegler-Natta catalyzed polyethylene resin having a multimodal molecular weight distribution and including at least two polyethylene fractions A and B. Fraction A may have a higher molecular weight and a lower density than fraction B. Each fraction may be prepared in different reactors of at least two reactors connected in series. Fraction A may have a melt index HL275 of at least 11 g/10 min and of at most 20 g/10 min, and a density of at least 941 kg/m3 and of at most 946 kg/m3. The polyethylene resin may have a melt index MI2 of at least 1.5 g/10 min and of at most 3.0 g/10 min, and a density of at least 950 kg/m3 and of at most 965 kg/m3.Type: GrantFiled: August 12, 2014Date of Patent: June 6, 2017Assignee: Total Research & Technology FeluyInventors: Jean-Marie Boissiere, Aurélien Vantomme, Jurjen Meeuwissen