Patents by Inventor Avelino Corma Canós

Avelino Corma Canós has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20180093895
    Abstract: The present invention relates to a new process for synthesising the silicoaluminate form of the AEI zeolite structure based on the use of another zeolite, zeolite Y, as the only source of silicon and aluminum, in order to obtain high synthesis yields (greater than 80%) in the absence of any other source of silicon, phosphine-derivedcationsand fluoride anions in the synthesis medium. The N,N-dimethyl-3,5-dimethylpiperidinium cation may be used as the OSDA, and the FAU crystal structure is transformed into the AEI crystal structure with high yields. It also discloses the preparation of catalysts based on the silicoaluminate form of the AEI crystal structure, wherein Cu atoms have been introduced, and the subsequent application thereof as a catalyst, preferably in the SCR of NOx.
    Type: Application
    Filed: April 14, 2016
    Publication date: April 5, 2018
    Applicants: Consejo Superior de Investigaciones Científicas (CSIC), Universitat Politècnica de València
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martín García
  • Publication number: 20180086690
    Abstract: Process for preparing aminated aromatic hydrocarbons that may be substituted comprising the steps of reacting an aromatic hydrocarbon with ammonia in the presence of a catalyst having a crystalline microporous structure wherein the catalyst comprises vanadium aluminophosphate molecular sieve (VAPO) and/or aluminophosphate molecular sieve (AlPO) and wherein the catalyst is preferably impregnated with nickel and/or copper, and wherein the aromatic hydrocarbon may be substituted.
    Type: Application
    Filed: February 23, 2016
    Publication date: March 29, 2018
    Inventors: Avelino Corma Canos, Patricia Concepcion Heydorn
  • Publication number: 20180079650
    Abstract: The present invention relates to a new synthesis process of a crystalline material with the CHA structure, which comprises the following steps: i) Preparation of a mixture that comprises one source of water, one source of a tetravalent element Y, one source of an alkaline or alkaline earth cation (A), one source of a trivalent element X, and one organic molecule (OSDA1) with the structure [R1R2R3R4N+]Q?, being the molar composition: n X2O3:YO2:a A:m OSDA1:z H2O, ii) crystallisation of the mixture obtained in i) in a reactor, iii) recovery of the crystalline material obtained in ii).
    Type: Application
    Filed: December 11, 2015
    Publication date: March 22, 2018
    Applicants: Consejo Superior de Investigaciones Científicas (CSIC), Universitat Politècnica De València Ctro.
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martín García
  • Patent number: 9878313
    Abstract: Process for the direct synthesis of Cu-SSZ-13 from a synthesis mixture comprising water, at least one silicon source, at least one Al source, at least one Cu source, at least one polyamine for complexing with Cu, and a single organic structure directing agent. A Cu containing molecular sieve having the framework structure of SSZ-13, obtainable by the process and use of the Cu containing molecular sieve.
    Type: Grant
    Filed: December 6, 2013
    Date of Patent: January 30, 2018
    Assignee: Haldor Topsoe A/S
    Inventors: Manuel Moliner Marin, Raquel Martinez Franco, Avelino Corma Canós, Joakim Reimer Thøgersen
  • Patent number: 9856145
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1-g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, a method for its preparation and its use.
    Type: Grant
    Filed: June 19, 2015
    Date of Patent: January 2, 2018
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantin Sanz, Jose Luis Jordá Moret
  • Patent number: 9855528
    Abstract: An exhaust gas cleaning system, comprising an active regenerable particulate filter and an SCR catalyst comprising a hydrothermally microporous stable zeolite having the AEI type framework and being promoted with copper, where the zeolite is SSZ-39.
    Type: Grant
    Filed: July 7, 2016
    Date of Patent: January 2, 2018
    Assignee: Haldor Topsoe A/S
    Inventors: Manuel Moliner Marin, Cristina Franch Marti, Antonio Eduardo Palomares Gimeno, Avelino Corma Canós, Peter N. R. Vennestrøm, Marie Grill, Arkady Kustov, Joakim Reimer Thøgersen
  • Patent number: 9840677
    Abstract: The invention relates to a method for producing a biofuel from an aqueous mixture of carbonized biomass obtained by means of a method for the hydrothermal carbonization of biomass, characterized in that it comprises: (a) grinding the aqueous mixture of carbonized biomass until a maximum size of less than 500 micrometers of the particles contained in the mixture is obtained; (b) applying a method for the physical separation of inorganic substances; and (c) reducing the moisture content until a water content of between 25 and 55 wt. % is reached. The invention also relates to the biofuel obtained by said method, and to the use thereof in various applications.
    Type: Grant
    Filed: September 17, 2013
    Date of Patent: December 12, 2017
    Assignee: INGELIA, S.L.
    Inventors: Martin Hitzl, Michael Renz, Avelino Corma Canos
  • Patent number: 9815758
    Abstract: A method of preparing 4-methyl-3-decen-5-one. The method includes the step of oxidizing 4-methyl-3-decen-5-ol in the presence of (i) oxygen and (ii) a metal catalyst, wherein the metal catalyst contains a catalytic metal deposited on nanoparticle support.
    Type: Grant
    Filed: December 12, 2016
    Date of Patent: November 14, 2017
    Assignee: INTERNATIONAL FLAVORS & FRAGRANCES INC.
    Inventors: Avelino Corma Canós, Sara Iborra Chornet, Alexandra Velty, Manuel Querol Sans, Amadeo Fernández Miranda, Jaime Renovell Gomez
  • Publication number: 20170320799
    Abstract: The present invention relates to a process for obtaining 1-octanol which comprises a contact step between ethanol, n-hexanol and a catalyst, wherein said catalyst comprises: i) a metal oxide that comprises the following metals: M1 is at least one bivalent metal selected from Mg, Zn, Cu, Co, Mn, Fe, Ni and Ca; M2 is at least one trivalent metal selected from Al, La, Fe, Cr, Mn, Co, Ni, and Ga; ii) a noble metal selected from Pd, Pt, Ru, Rh and Re; and iii) optionally, comprises V; with the proviso that the catalyst comprises at least V, Ga or any of their combinations.
    Type: Application
    Filed: November 12, 2015
    Publication date: November 9, 2017
    Applicant: Abengoa Bioenergia Nuevas Tecnologias, S.A.
    Inventors: Avelino Corma Canos, Marcelo Eduardo Domine, Juan Luis Sanz Yague, Francisco Antonio Ladron de Guevara Vidal
  • Patent number: 9764311
    Abstract: The present invention refers to a microporous crystalline material, to the method for the production thereof and to the use of same, the material having a composition: xX2O3:zZO2:yYO2 in which: X is a trivalent element such as Al, B, Fe, In, Ga, Cr, or mixtures thereof, where (y+z)/x can have values of between 9 and infinity; Z corresponds to a tetravalent element selected from Si, Ge or mixtures thereof; and Y corresponds to a tetravalent element such as Ti, Sn, Zr, V or mixtures thereof, where z/y can have values of between 10 and infinity.
    Type: Grant
    Filed: October 17, 2014
    Date of Patent: September 19, 2017
    Assignees: Universitat Politecnica De Valencia, Consejo Superior de Investigaciones Cientificas (CSIC)
    Inventors: Avelino Corma Canós, Fernando Rey García, Manuel Hernández Rodríguez, José Luis Jordá Moret
  • Publication number: 20170259253
    Abstract: Synthesis of the silicoaluminophosphate and metal silicoaluminophosphate polymorphs of the molecular sieve SAPO-18 using cyclic quaternary ammoniums as organic structure-directing agents (OSDA) and use thereof as a catalyst.
    Type: Application
    Filed: June 3, 2015
    Publication date: September 14, 2017
    Applicants: CONSEJO SUPERIOR DE INVESTIGACIONES CIENTÍFICAS, UNIVERSITAT POLITÈNCIA DE VALÈNCIA
    Inventors: Avelino CORMA CANÓS, Manuel MOLINER MARÍN, Raquel MARTÍNEZ FRANCO
  • Patent number: 9738539
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
    Type: Grant
    Filed: June 19, 2015
    Date of Patent: August 22, 2017
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Edward W. Corcoran, Jr., Pavel Kortunov, Charanjit S. Paur, Peter I. Ravikovitch, Yu Wang, Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantín Sanz, Miguel Palomino Roca
  • Patent number: 9695056
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
    Type: Grant
    Filed: June 19, 2015
    Date of Patent: July 4, 2017
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Edward W. Corcoran, Jr., Pavel Kortunov, Charanjit S. Paur, Peter I. Ravikovitch, Yu Wang, Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantin Sanz, Miguel Palomino Roca
  • Patent number: 9688542
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
    Type: Grant
    Filed: June 19, 2015
    Date of Patent: June 27, 2017
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Edward W. Corcoran, Jr., Pavel Kortunov, Charanjit S. Paur, Peter I. Ravikovitch, Yu Wang, Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantin Sanz, Miguel Palomino Roca
  • Publication number: 20170166504
    Abstract: A method of preparing 4-methyl-3-decen-5-one. The method includes the step of oxidizing 4-methyl-3-decen-5-ol in the presence of (i) oxygen and (ii) a metal catalyst, wherein the metal catalyst contains a catalytic metal deposited on nanoparticle support.
    Type: Application
    Filed: December 12, 2016
    Publication date: June 15, 2017
    Inventors: Avelino Corma Canós, Sara Iborra Chornet, Alexandra Velty, Manuel Querol Sans, Amadeo Fernández Miranda, Jaime Renovell Gomez
  • Patent number: 9617164
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
    Type: Grant
    Filed: June 19, 2015
    Date of Patent: April 11, 2017
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Edward W. Corcoran, Jr., Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantin Sanz, Miguel Palomino Roca
  • Patent number: 9561468
    Abstract: The invention provides a method and system for the purification of exhaust gas from an internal combustion engine, comprising a filter and a SCR catalyst. The filter is periodically regenerated increasing the temperature of the exhaust gas up to 850° C. and the water vapor content up to 100% by volume. The SCR catalyst comprises a hydrothermally microporous stable zeolite and/or zeotype having the AEI type framework and being promoted with copper.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: February 7, 2017
    Assignee: Haldor Topsoe A/S
    Inventors: Manuel Moliner Marin, Cristina Franch Marti, Antonio Eduardo Palomares Gimeno, Avelino Corma Canós, Peter N. R. Vennestrøm, Marie Grill, Arkady Kustov, Joakim Reimer Thøgersen
  • Patent number: 9561498
    Abstract: A process for the direct synthesis of Cu-SAPO-34 comprising at least the steps: preparation of a mixture of water, at least one silicon source, at least one Al source, at least one P source, at least one Cu source, at least one 0SDA1 (any polyamine), and at least one OSDA2 source (where OSDA2 is any organic molecule capable of directing the synthesis of SAPO 34); and where the final synthesis mixture has the molar composition: a Si:0.5 Al:c Cu:d OSDA1:e OSDA2:f H2O wherein a is in the range from 0.01 to 0.3; b is in the range from 0.2 to 0.49; c is in the range from 0.001 to 0.6; d is in the range from 0.001 to 0.6; e is in the range from 0.001 to 2; f is in the range 1 to 200; hydrothermal treatment of the mixture at 80?200° C. until formation of the crystalline material, and recovery of the crystalline material.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: February 7, 2017
    Assignee: Haldor Topsoe A/S
    Inventors: Raquel Martinez Franco, Manuel Moliner Marin, Avelino Corma Canós, Arkady Kustov, Joakim Reimer Thøgersen
  • Patent number: 9556384
    Abstract: The invention relates to a method for extracting biochemical products obtained from a process of hydrothermal carbonization of biomass, which includes feeding an aqueous mixture of biomass from a preheating tube for the aqueous mixture of biomass to a vertical reactor with a predetermined level of floatation and an area for accumulation of steam and gases in the upper part thereof, wherein said method for extracting biochemical products is characterized in that it includes (a) heating the aqueous mixture of biomass to, or above, evaporation temperature in said vertical reactor and/or in a previous stage of preheating the aqueous mixture of biomass, increasing the generation of stream and/or gases at the predetermined flotation level of the vertical reactor, (b) extracting the steam and/or gases generated in the previous stage and accumulated in the upper part of the vertical reactor, and (c) cooling the gases and/or condensing the steam extracted in the previous stage at different levels of temperature and pr
    Type: Grant
    Filed: December 22, 2011
    Date of Patent: January 31, 2017
    Assignee: INGELIA, S.L.
    Inventors: Martin Hitzl, Michael Renz, Avelino Corma Canos
  • Patent number: 9550706
    Abstract: The invention relates to a heterogeneous method for oligomerising alkenes in order to produce hydricarbons within a diesel fraction in the present of a catalyst based on the ITQ-39 zeolite. The oligomerisation method described in the present invention includes at least: a. feeding a catalyst containing at least the ITQ-39 zeolitic material into the reactor; b. supplying the reactor with a stream that includes at least one olefinic compound; and c. enabling the catalyst containing at least the ITQ-39 material and the organic compound to remain in contact during the time required for the reaction to take place.
    Type: Grant
    Filed: January 19, 2015
    Date of Patent: January 24, 2017
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Avelino Corma Canós, Cristina Martínez Sánchez