Abstract: A printing method for three-dimensional painting by UV digital printing device has acts of: First, preparing a printing device having a white print set and a color print set. Second, moving the printing device transversely from one side to the other side of an object for multiple times, wherein the two print sets respectively print on two adjacent zones. Third, moving the printing device longitudinally to next zone on the object. Fourth, repeating the second and third acts until the printing device moves over a last zone on the object. The printing device moves longitudinally after the printing device moves transversely to and fro to finish the height of a zone. Thus, the printing device completes all the heights and the colors in one time of longitudinal moving. Then printing consumes less time and the printing device therefore does not have to be orientated again.