Abstract: A method for preparing a purified styrene composition with a styrene yield of at least 80%. The method comprises providing a crude composition containing styrene, and subjecting the crude composition to at least one crystallization step. The at least one crystallization step comprises at least one static crystallization stage and at least one dynamic crystallization stage.

Abstract: A method for preparing a purified styrene composition is provided. The method includes providing a crude composition and subjecting the crude composition to at least one crystallization step. The crude composition contains 70% by weight or more styrene based on the total weight of the crude composition. The at least one crystallization step comprises at least one of a static crystallization stage and a dynamic crystallization stage. The crude composition contains at least one impurity selected from the group consisting of: color inducing species, oxygenates, sulfur species, alpha-methylstyrene, and mixtures thereof.

Abstract: A method for preparing a purified styrene composition with a styrene yield of at least 80%. The method comprises providing a crude composition containing styrene, and subjecting the crude composition to at least one crystallization step. The at least one crystallization step comprises at least one static crystallization stage and at least one dynamic crystallization stage.

Abstract: A method for preparing a purified styrene composition with a styrene yield of at least 80%. The method comprises providing a crude composition containing styrene, and subjecting the crude composition to at least one crystallization step. The at least one crystallization step comprises at least one static crystallization stage and at least one dynamic crystallization stage.

Abstract: A method for preparing a purified styrene composition is provided. The method includes providing a crude composition and subjecting the crude composition to at least one crystallization step. The crude composition contains 70% by weight or more styrene based on the total weight of the crude composition. The at least one crystallization step comprises at least one of a static crystallization stage and a dynamic crystallization stage. The crude composition contains at least one impurity selected from the group consisting of: color inducing species, oxygenates, sulfur species, alpha-methylstyrene, and mixtures thereof.

Abstract: Apparatuses, systems and methods for producing Pips stream for manufacturing catalytic C5 hydrocarbon resins containing all the key reactive monomers that are already present in the C5 fraction of the pyrolysis gasoline, which is otherwise lost with the crude isoprene stream, are disclosed herein. Embodiments of the invention are directed to producing a hydrocarbon resin grade DCPD stream consisting of dimers and codimers of isoprene which are of value in manufacturing thermal hydrocarbon resins, either polymer grade isoprene and gasoline quality raffinate (free or sulfur and acetylenes) or a relatively small crude isoprene stream with maximum utilization of isoprene by moving some of the isoprene to a DCPD stream used to manufacture thermal hydrocarbon resins.

Abstract: Apparatuses, systems and methods for separating heavy hydrocarbons from a solvent stream are disclosed. The heavy hydrocarbons and solvent can be recovered and processed further.

Abstract: Apparatuses, systems and methods for separating heavy hydrocarbons from a solvent stream are disclosed. The heavy hydrocarbons and solvent can be recovered and processed further.

Abstract: Apparatuses, systems and methods for producing Pips stream for manufacturing catalytic C5 hydrocarbon resins containing all the key reactive monomers that are already present in the C5 fraction of the pyrolysis gasoline, which is otherwise lost with the crude isoprene stream, are disclosed herein. Embodiments of the invention are directed to producing a hydrocarbon resin grade DCPD stream consisting of dimers and codimers of isoprene which are of value in manufacturing thermal hydrocarbon resins, either polymer grade isoprene and gasoline quality raffinate (free or sulfur and acetylenes) or a relatively small crude isoprene stream with maximum utilization of isoprene by moving some of the isoprene to a DCPD stream used to manufacture thermal hydrocarbon resins.

Abstract: High temperatures and oxygen exposure during extractive distillation can result in polymerization of vinyl aromatic compounds. In various embodiments, the present disclosure relates to methods for inhibiting polymerization of vinyl aromatic compounds during extractive distillation. In various embodiments, the methods include a) providing a mixture containing at least one vinyl aromatic compound, b) adding at least one dinitrophenol inhibitor to the mixture, and c) after step b), performing an extractive distillation on the mixture to isolate the at least one vinyl aromatic compound. Purified styrene can be isolated by the methods described herein. In some embodiments, the dinitrophenol inhibitor is 2-sec-butyl-4,6-dinitrophenol (DNBP).

Abstract: High temperatures and oxygen exposure during extractive distillation can result in polymerization of vinyl aromatic compounds. In various embodiments, the present disclosure relates to methods for inhibiting polymerization of vinyl aromatic compounds during extractive distillation. In various embodiments, the methods include a) providing a mixture containing at least one vinyl aromatic compound, b) adding at least one dinitrophenol inhibitor to the mixture, and c) after step b), performing an extractive distillation on the mixture to isolate the at least one vinyl aromatic compound. Purified styrene can be isolated by the methods described herein. In some embodiments, the dinitrophenol inhibitor is 2-sec-butyl-4,6-dinitrophenol (DNBP).