Abstract: Apparatuses, systems and methods for producing Pips stream for manufacturing catalytic C5 hydrocarbon resins containing all the key reactive monomers that are already present in the C5 fraction of the pyrolysis gasoline, which is otherwise lost with the crude isoprene stream, are disclosed herein. Embodiments of the invention are directed to producing a hydrocarbon resin grade DCPD stream consisting of dimers and codimers of isoprene which are of value in manufacturing thermal hydrocarbon resins, either polymer grade isoprene and gasoline quality raffinate (free or sulfur and acetylenes) or a relatively small crude isoprene stream with maximum utilization of isoprene by moving some of the isoprene to a DCPD stream used to manufacture thermal hydrocarbon resins.

Abstract: Apparatuses, systems and methods for separating heavy hydrocarbons from a solvent stream are disclosed. The heavy hydrocarbons and solvent can be recovered and processed further.

Abstract: Apparatuses, systems and methods for separating heavy hydrocarbons from a solvent stream are disclosed. The heavy hydrocarbons and solvent can be recovered and processed further.

Abstract: Apparatuses, systems and methods for producing Pips stream for manufacturing catalytic C5 hydrocarbon resins containing all the key reactive monomers that are already present in the C5 fraction of the pyrolysis gasoline, which is otherwise lost with the crude isoprene stream, are disclosed herein. Embodiments of the invention are directed to producing a hydrocarbon resin grade DCPD stream consisting of dimers and codimers of isoprene which are of value in manufacturing thermal hydrocarbon resins, either polymer grade isoprene and gasoline quality raffinate (free or sulfur and acetylenes) or a relatively small crude isoprene stream with maximum utilization of isoprene by moving some of the isoprene to a DCPD stream used to manufacture thermal hydrocarbon resins.

Abstract: High temperatures and oxygen exposure during extractive distillation can result in polymerization of vinyl aromatic compounds. In various embodiments, the present disclosure relates to methods for inhibiting polymerization of vinyl aromatic compounds during extractive distillation. In various embodiments, the methods include a) providing a mixture containing at least one vinyl aromatic compound, b) adding at least one dinitrophenol inhibitor to the mixture, and c) after step b), performing an extractive distillation on the mixture to isolate the at least one vinyl aromatic compound. Purified styrene can be isolated by the methods described herein. In some embodiments, the dinitrophenol inhibitor is 2-sec-butyl-4,6-dinitrophenol (DNBP).

Abstract: High temperatures and oxygen exposure during extractive distillation can result in polymerization of vinyl aromatic compounds. In various embodiments, the present disclosure relates to methods for inhibiting polymerization of vinyl aromatic compounds during extractive distillation. In various embodiments, the methods include a) providing a mixture containing at least one vinyl aromatic compound, b) adding at least one dinitrophenol inhibitor to the mixture, and c) after step b), performing an extractive distillation on the mixture to isolate the at least one vinyl aromatic compound. Purified styrene can be isolated by the methods described herein. In some embodiments, the dinitrophenol inhibitor is 2-sec-butyl-4,6-dinitrophenol (DNBP).