Patents by Inventor Bênoit DE-GAUDEMARIS
Bênoit DE-GAUDEMARIS has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11802194Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbonbased resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.Type: GrantFiled: May 17, 2022Date of Patent: October 31, 2023Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Benoit De Gaudemaris, Alain Hut
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Publication number: 20220363875Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbonbased resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.Type: ApplicationFiled: May 17, 2022Publication date: November 17, 2022Inventors: BENOIT DE GAUDEMARIS, ALAIN HUT
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Patent number: 11492465Abstract: A rubber composition is based on at least: from 60 to 100 phr of one or more diene elastomers, referred to as very low glass transition temperature (Tg) diene elastomers, exhibiting a Tg within a range extending from ?110° C. to ?70° C., chosen from butadiene homopolymers, copolymers of butadiene and of vinylaromatic monomer, exhibiting a content of vinylaromatic unit of between 0% and 5% by weight, and the mixtures of these; a reinforcing filler; crosslinking system; and from 50 to 150 phr of at least one hydrocarbon resin predominantly composed of units resulting from ?-pinene monomers, the resin exhibiting an aliphatic proton content of greater than 95%.Type: GrantFiled: April 13, 2018Date of Patent: November 8, 2022Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Benoit De Gaudemaris, Justin Belz
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Patent number: 11479618Abstract: A process for preparing a functionalized polybutadiene is provided. The process comprises the following steps: a) homopolymerising butadiene with a catalytic system based on at least one preforming conjugated diene, a salt of one or more rare earth metals of an organic phosphoric acid, an aluminium-containing alkylating agent, an alkylaluminium halide; b) adding a polyfunctional compound to the pseudo-living elastomer formed in step (a); and c) adding a functionalizing agent to the mixture formed in step (b). The total molar amount of aluminium in the polymerization medium is such that the (aluminium/rare earth salt) molar ratio has a value between 1 and 5 and the polymerization is carried out at a temperature between 40° C. and 90° C. A functionalized polybutadiene that can be obtained by the process, and a rubber composition containing the functionalized polybutadiene is also provided.Type: GrantFiled: May 23, 2019Date of Patent: October 25, 2022Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Florent Vaultier, Gael Courbes, Rokhiyatou Said-Diatta, Benoit De Gaudemaris
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Publication number: 20220267489Abstract: Described herein are hydrocarbon polymer modifiers for use in various applications. The hydrocarbon polymer modifier comprises a cyclic component, and has a glass transition temperature and Mn defined by the following two equations: (1) Tg?95?2.2*(% H Ar); and (2) Tg??53+(0.265*Mn) and an aromaticity content of greater than 6 mole %, wherein Tg is glass transition temperature as expressed in ° C. of the modifier, the % H Ar represents the content of aromatic protons in the hydrocarbon polymer modifier, and Mn represents the number average molecular weight of the hydrocarbon polymer modifier, and the cyclic component is selected from the group of a distillation cut from a petroleum refinery stream, and/or C4 C5 or C6 cyclic olefins and mixtures thereof. The hydrocarbon modifiers are particularly useful in high Tg applications where low molecular weight resin is desirable.Type: ApplicationFiled: July 10, 2020Publication date: August 25, 2022Inventors: Ranjan Tripathy, Rajesh P. Raja, Derek W. Thurman, Olivier Jean Francois Georjon, Alexandra K. Valdez, Benoit de Gaudemaris, Laurent Copey, Fabien Bonnette
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Publication number: 20220259415Abstract: Described herein are tires comprising a rubber composition based on at least an elastomer matrix comprising from 50 to 100 phr of one or more copolymers of butadiene and of vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight and a Tg within a range extending from ?110° C. to ?70° C.; and a hydrocarbon resin, wherein the hydrocarbon resin is based on a cyclic monomer selected from the group consisting of a distillation cut from a petroleum refinery stream, and/or C4, C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon resin has a content of aromatic protons (H Ar, expressed in mol %), a glass transition temperature (Tg, expressed in ° C.), and a number average molecular weight (Mn, expressed in g/mol) that are represented by (1) H Ar>6 mol %, (2) Tg?95?2.2*(H Ar), and (3) Tg??53+(0.265*Mn).Type: ApplicationFiled: July 10, 2020Publication date: August 18, 2022Inventors: FABIEN BONNETTE, LAURENT COPEY, BENOIT DE GAUDEMARIS, OLIVIER J. F. GEORJON, DEREK W. THURMAN, RANJAN TRIPATHY, ALAIN HUT
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Publication number: 20220251349Abstract: Described herein are tires comprising a rubber composition based on at least an elastomer matrix comprising from 50 to 100 phr of one or more copolymers of butadiene and of vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight and a Tg within a range extending from ?110° C. to ?70° C.; and a hydrocarbon resin, wherein the hydrocarbon resin is based on a cyclic monomer selected from the group consisting of a distillation cut from a petroleum refinery stream, and/or C4, C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon resin has a content of aromatic protons (H Ar, expressed in mol %), a glass transition temperature (Tg, expressed in ° C.), and a number average molecular weight (Mn, expressed in g/mol) that are represented by (1) H Ar?6 mol %, (2) Tg?95?2.2*(H Ar), (3) Tg?125?(0.08*Mn).Type: ApplicationFiled: July 10, 2020Publication date: August 11, 2022Inventors: FABIEN BONNETTE, LAURENT COPEY, BENOIT DE GAUDEMARIS, OLIVIER J. F. GEORJON, DEREK W. THURMAN, RANJAN TRIPATHY, ALAIN HUT
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Publication number: 20220251350Abstract: Described herein are tires comprising a rubber composition based on at least an elastomer and a hydrocarbon resin, wherein [[said]]the hydrocarbon resin is based on a cyclic monomer selected from the group consisting of a distillation cut from a petroleum refinery stream, and/or C4, C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon resin has a number average molecular weight (Mn) of between 150 and 800 g/mol, and a content of aromatic protons (H Ar, expressed in mol %), a glass transition temperature (Tg, expressed in ° C.), and a number average molecular weight (Mn, expressed in g/mol) that are represented by (1) H Ar<6 mol %, (2) Tg?95?2.2*(H Ar), (3) Tg?125?(0.08*Mn).Type: ApplicationFiled: July 10, 2020Publication date: August 11, 2022Inventors: FABIEN BONNETTE, LAURENT COPEY, BENOIT DE GAUDEMARIS, OLIVIER J. F. GEORJON, DEREK W. THURMAN, RANJAN TRIPATHY, ALAIN HUT
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Publication number: 20220251270Abstract: Described herein are hydrocarbon polymer modifiers for use in various applications. The hydrocarbon polymer modifier comprises a cyclic component, and has a glass transition temperature and Mn defined by the following two equations: (1) Tg?95-2.2*(% H Ar); and (2) Tg?125?(0.08*Mn) and an aromaticity content of less than or equal to 6 mole %, wherein Tg is glass transition temperature as expressed in ° C. of the modifier, the % H Ar represents the content of aromatic protons in the hydrocarbon polymer modifier, and Mn represents the number average molecular weight of the hydrocarbon polymer modifier, and the cyclic component is selected from the group of a distillation cut from a petroleum refinery stream, and/or C4 C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon polymer modifier has number average molecular weight (Mn) of between 150 and 800 g/mol.Type: ApplicationFiled: July 10, 2020Publication date: August 11, 2022Inventors: Ranjan Tripathy, Rajesh P. Raja, Derek W. Thurman, Olivier Jean Francois Georjon, Alexandra K. Vaidez, Benoit de Gaudemaris, Laurent Copey, Fabien Bonnette
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Publication number: 20220227975Abstract: Described herein are tires comprising a rubber composition based on at least an elastomer and a hydrocarbon resin, wherein the hydrocarbon resin is based on a cyclic monomer selected from the group consisting of a distillation cut from a petroleum refinery stream, and/or C4, C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon resin has a content of aromatic protons (H Ar, expressed in mol %), a glass transition temperature (Tg, expressed in ° C.), and a number average molecular weight (Mn, expressed in g/mol) that are represented by (1) H Ar>6 mol %, (2) Tg?95?2.2*(H Ar), and (3) Tg??53+(0.265*Mn).Type: ApplicationFiled: July 10, 2020Publication date: July 21, 2022Inventors: FABIEN BONNETTE, LAURENT COPEY, BENOIT DE GAUDEMARIS, OLIVIER J. F. GEORJON, DEREK W. THURMAN, RANJAN TRIPATHY, ALAIN HUT
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Patent number: 11365308Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbon-based resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.Type: GrantFiled: October 14, 2016Date of Patent: June 21, 2022Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Benoit De Gaudemaris, Alain Hut
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Publication number: 20220127422Abstract: A rubber composition based at least on a reinforcing filler comprising a content of silica of greater than or equal to 80 phr and on an elastomer matrix comprising a content of a modified diene elastomer of greater than or equal to 75 phr is provided. The modified diene elastomer includes macromolecules comprising, within their structure, a linear or branched polyether block comprising, at each of the two ends of the block, a branch point to which up to three diene elastomer branches and up to three —OR groups are bonded, R representing, independently of one another, a C1-C8 alkyl substituent or a hydrogen atom b—the. The copolymer is composed: of at least 20% of branched macromolecules comprising a polyether block to which at least three diene elastomer blocks are bonded, of at most 80% of linear macromolecules, and d—each of the branch points includes a silicon atom.Type: ApplicationFiled: November 7, 2019Publication date: April 28, 2022Applicant: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Charlotte DIRE, Benoît DE-GAUDEMARIS, Julien CHATARD, Kevin ROOS
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Patent number: 11220591Abstract: A rubber composition based on at least: from 50 to 100 phr of one or more diene elastomers, referred to as very low glass transition temperature (Tg) diene elastomers, having a Tg within a range of from ?110° C. to ?70° C., selected from butadiene homopolymers, copolymers of butadiene and of a vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight, and mixtures thereof a reinforcing filler a crosslinking system; and from 40 to 150 phr of at least one hydrogenated hydrocarbon resin predominantly composed of units derived from C9 monomers, the resin having a content of aromatic protons of less than 25% and a content of ethylenic protons of less than 1%.Type: GrantFiled: December 5, 2017Date of Patent: January 11, 2022Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Benoit De Gaudemaris, Philippe Labrunie
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Publication number: 20210403609Abstract: A rubber composition based at least on a reinforcing filler comprising a content of silica of greater than or equal to 80 phr, preferably of greater than or equal to 100 phr, and on an elastomer matrix comprising a content of a modified diene elastomer of greater than or equal to 75 phr is provided. The modified diene elastomer comprises macromolecules comprising, within their structure, an n-functional branching unit, n having a value of at least 1 and of at most 9, preferably of at most 6, consisting of a group comprising at least two silicon atoms which are substituted by elastomer branches and connected together via a group comprising at least one nitrogen atom, the bonds between silicon and nitrogen atoms being produced via a spacer group.Type: ApplicationFiled: November 7, 2019Publication date: December 30, 2021Applicant: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Benoît DE-GAUDEMARIS, Julien CHATARD, Charlotte DIRE, Kevin ROOS, Benoît GADENNE
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Patent number: 11203680Abstract: A rubber composition based on at least: from 50 to 100 phr of one or more diene elastomers, referred to as very low glass transition temperature (Tg) diene elastomers, having a Tg within a range of from ?110° C. to ?70° C., selected from butadiene homopolymers, copolymers of butadiene and of a vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight, and mixtures thereof a reinforcing filler a crosslinking system; and from 50 to 150 phr of at least one hydrocarbon resin predominantly composed of units derived from terpene and phenol monomers, the resin having a content of aromatic protons of greater than 15%.Type: GrantFiled: December 5, 2017Date of Patent: December 21, 2021Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Benoit De Gaudemaris, Alain Hut
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Patent number: 11124634Abstract: A rubber composition based on at least a reinforcing filler, a crosslinking system, a plasticizing system and an elastomer matrix is provided. The elastomer matrix includes at least one modified diene elastomer comprising within its structure at least one alkoxysilane group, which is optionally partially or totally hydrolysed to silanol, bonded to the elastomer by the silicon atom. The alkoxysilane group optionally bears another function bonded to the silicon atom directly or by means of a spacer group. The modified diene elastomer is such that, before modification, the diene elastomer has a polydispersity index of at least 1.1 and at most 1.6, and has a Mooney viscosity ranging from 50 to 80 and a glass transition temperature (Tg) of strictly less than ?50° C., preferably less than or equal to ?60° C., and greater than or equal to ?110° C.Type: GrantFiled: December 19, 2017Date of Patent: September 21, 2021Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Marie-Laure Francois, Bênoit De-Gaudemaris
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Patent number: 10889147Abstract: A rubber composition is based on at least one diene elastomer, a reinforcing filler, a crosslinking system and a hydrocarbon-based resin. The hydrocarbon-based resin has a number-average molecular weight (Mn) of between 700 and 1000 g/mol, an average molecular weight Mz of greater than 6000 g/mol and a polydispersity index (PI) of greater than 2.4.Type: GrantFiled: December 18, 2015Date of Patent: January 12, 2021Assignee: Compagnie Generale Des Etablissements MichelinInventors: Julien Chatard, Benoit De Gaudemaris, Alain Hut, Fabien Hellot, Francois Dimier
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Publication number: 20200392314Abstract: The tread of a civil engineering vehicle tire comprises a rubber composition based on at least one elastomer matrix comprising from 50 to 100 phr of a styrene-butadiene copolymer and from 0 to 50 phr of isoprene elastomer; a reinforcing filler comprising predominantly carbon black with CTAB specific surface area greater than or equal to 90 m2/g; from 1 to 30 phr of at least one hydrocarbon resin predominantly consisting of units derived from aromatic and cycloaliphatic monomers, having an aromatic proton content between 0 and 12%, an ethylenic proton content greater than 3%, a number-average molecular weight above 500 g/mol and a polydispersity index greater than 2; and a crosslinking system.Type: ApplicationFiled: December 13, 2018Publication date: December 17, 2020Inventors: BENOIT DE GAUDEMARIS, ALAIN HUT, LAURENT PETITJEAN
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Publication number: 20200385550Abstract: The tread of an aircraft tire comprises a composition based on at least one elastomeric matrix comprising from 20 to 100 phr of isoprene elastomer and from 0 to 80 phr of a copolymer of butadiene and styrene; a reinforcing filler predominantly comprising carbon black; from 1 to 30 phr of at least one hydrocarbon resin predominantly composed of units derived from aromatic and cycloaliphatic monomers, said resin having a content of aromatic protons of between 0% and 12%, a content of ethylenic protons of greater than 3%, a number-average molecular mass of greater than 500 g/mol and a polydispersity index of greater than 2; and a crosslinking system.Type: ApplicationFiled: December 13, 2018Publication date: December 10, 2020Inventors: JEAN-LUC CABIOCH, BENOIT DE GAUDEMARIS
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Publication number: 20200190292Abstract: A rubber composition based on at least: from 50 to 100 phr of one or more diene elastomers, referred to as very low glass transition temperature (Tg) diene elastomers, having a Tg within a range of from ?110° C. to ?70° C., selected from butadiene homopolymers, copolymers of butadiene and of a vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight, and mixtures thereof a reinforcing filler a crosslinking system; and from 40 to 150 phr of at least one hydrogenated hydrocarbon resin predominantly composed of units derived from C9 monomers, the resin having a content of aromatic protons of less than 25% and a content of ethylenic protons of less than 1%.Type: ApplicationFiled: December 5, 2017Publication date: June 18, 2020Inventors: BENOIT DE GAUDEMARIS, PHILIPPE LABRUNIE