Abstract: Disclosed herein are embodiments of a polymer-functionalized particle for using in isolating and extracting solutes, such as rare earth metals, lithium, and the like. The polymer-functionalized particles exhibit strong resistance to agglomeration and degradation even in high ionic strength and/or temperature environments. A post-particle synthesis method for making the polymer-functionalized particle is disclosed, along with a magnetic separation device and that can be used in system embodiments to facilitate use and regeneration of the polymer-functionalized particles in solute extraction.

Abstract: A MOF production system and method of making are detailed for continuous and controlled synthesis of MOFs and MOF composites. The system can provide optimized yields of MOFs and MOF composites greater than or equal to 95%.

Abstract: An apparatus comprising (A) an atmospheric water extraction unit; and (B) a direct air capture unit positioned downstream of and in communication with the atmospheric water extraction unit, wherein the apparatus is capable of reversibly operating in (i) adsorption mode to adsorb water and CO2 from an incoming air stream and (ii) regeneration mode to release adsorbed water and CO2, wherein the atmospheric water extraction unit comprises a first desiccant bed comprising a sorbent that adsorbs water from an incoming air stream during adsorption mode and releases water during regeneration mode, and wherein the direct air capture unit comprises a first CO2 sorbent bed that adsorbs CO2 from an air stream during adsorption mode and releases CO2 during regeneration.

Abstract: An apparatus that includes (A) an atmospheric water extraction unit; and (B) a direct air capture unit positioned downstream of and in communication with the atmospheric water extraction unit, wherein the apparatus is capable of reversibly operating in (i) adsorption mode to adsorb water and CO2 from an incoming air stream and (ii) regeneration mode to release adsorbed water and CO2, wherein the atmospheric water extraction unit comprises a first desiccant bed comprising a sorbent that adsorbs water from an incoming air stream during adsorption mode and releases water during regeneration mode, and wherein the direct air capture unit comprises a first moisture-responsive CO2 sorbent bed comprising a sorbent that adsorbs CO2 from an air stream during adsorption mode and releases CO2 upon contact with water vapor during regeneration mode.

Abstract: Heat exchanger assemblies and methods for providing heat exchange as well as methods providing specific energy to predetermined materials within an assembly as well as gas turbine engines as well as methods of powering same are provided. Heating assemblies are provided that can include: a heat-sinking substrate; and a selective emitter layer in thermal communication with the substrate. These assemblies can be provided as part of heat exchanger assemblies. Methods for providing heat to a fluid are also provided that can include heating a layer upon a substrate to provide photons of a predetermined wavelength to a fluid from the layer. Turbine combustion engines are also provided that can include a turbine having at least a portion of the blades in the hot section of the turbine coated with an emissivity layer in thermal communication with the turbine blade. Methods for powering turbine combustion engines are also provided.

Abstract: A MOF production system and method of making are detailed for continuous and controlled synthesis of MOFs and MOF composites. The system can provide optimized yields of MOFs and MOF composites greater than or equal to 95%.

Abstract: Disclosed herein are embodiments of a polymer-functionalized particle for using in isolating and extracting solutes, such as rare earth metals, lithium, and the like. The polymer-functionalized particles exhibit strong resistance to agglomeration and degradation even in high ionic strength and/or temperature environments. A post-particle synthesis method for making the polymer-functionalized particle is disclosed, along with a magnetic separation device and that can be used in system embodiments to facilitate use and regeneration of the polymer-functionalized particles in solute extraction.

Abstract: A MOF production system and method of making are detailed for continuous and controlled synthesis of MOFs and MOF composites. The system can provide optimized yields of MOFs and MOF composites greater than or equal to 95%.

Abstract: The present invention relates to sorbants such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs), porous aromatic frameworks (PAFs) or porous polymer networks (PPNs) for separations of gases or liquids, gas storage, cooling, and heating applications, including, but not limited to, adsorption chillers.

Abstract: A new power generation thermodynamic cycle is described that eliminates need for bulk liquid condensation and vaporization steps required in conventional ORC power systems. An exemplary harmonic adsorption recuperative power cycle system offers more efficient power generation as compared with conventional ORC systems. A multibed adsorption system is used to provide thermal compression for the cycle. An adsorption compressor contains a sorbent with strong adsorption affinity for the working fluid in the pores while well outside the P-T conditions needed to condense the liquid phase, allowing the adsorption compressor to reduce operating pressure exiting the expander.

Abstract: Metal-organic framework materials can be used as acoustic attenuation materials. A sound attenuation material includes a metal-organic framework material that attenuates audible frequency sound incident thereon. The sound attenuating material can be used in acoustic applications such as building construction materials.

Abstract: A new power generation thermodynamic cycle is described that eliminates need for bulk liquid condensation and vaporization steps required in conventional ORC power systems. An exemplary harmonic adsorption recuperative power cycle system offers more efficient power generation as compared with conventional ORC systems. A multibed adsorption system is used to provide thermal compression for the cycle. An adsorption compressor contains a sorbent with strong adsorption affinity for the working fluid in the pores while well outside the P-T conditions needed to condense the liquid phase, allowing the adsorption compressor to reduce operating pressure exiting the expander.

Abstract: A MOF production system and method of making are detailed for continuous and controlled synthesis of MOFs and MOF composites. The system can provide optimized yields of MOFs and MOF composites greater than or equal to 95%.

Abstract: A system and process are disclosed for production of consolidated magnesium metal products and alloys with selected densities from magnesium-containing salts and feedstocks. The system and process employ a dialkyl magnesium compound that decomposes to produce the Mg metal product. Energy requirements and production costs are lower than for conventional processing.

Abstract: A system and process are disclosed for production of consolidated magnesium metal products and alloys with selected densities from magnesium-containing salts and feedstocks. The system and process employ a dialkyl magnesium compound that decomposes to produce the Mg metal product. Energy requirements and production costs are lower than for conventional processing.

Abstract: Methods for releasing associated guest materials from a metal organic framework are provided. Methods for associating guest materials with a metal organic framework are also provided. Methods are provided for selectively associating or dissociating guest materials with a metal organic framework. Systems for associating or dissociating guest materials within a series of metal organic frameworks are provided. Thermal energy transfer assemblies are provided. Methods for transferring thermal energy are also provided.

Abstract: The present invention relates to sorbants such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs), porous aromatic frameworks (PAFs) or porous polymer networks (PPNs) for separations of gases or liquids, gas storage, cooling, and heating applications, including, but not limited to, adsorption chillers.

Abstract: Methods for releasing associated guest materials from a metal organic framework are provided. Methods for associating guest materials with a metal organic framework are also provided. Methods are provided for selectively associating or dissociating guest materials with a metal organic framework. Systems for associating or dissociating guest materials within a series of metal organic frameworks are provided. Gas separation assemblies are provided.

Abstract: Downhole fluid injection systems are provided that can include a first well extending into a geological formation, and a fluid injector assembly located within the well. The fluid injector assembly can be configured to inject a liquid CO2/H2O-emulsion into the surrounding geological formation. CO2 sequestration methods are provided that can include exposing a geological formation to a liquid CO2/H2O-emulsion to sequester at least a portion of the CO2 from the emulsion within the formation. Hydrocarbon material recovery methods are provided that can include exposing a liquid CO2/H2O-emulsion to a geological formation having the hydrocarbon material therein. The methods can include recovering at least a portion of the hydrocarbon material from the formation.

Abstract: Methods for releasing associated guest materials from a metal organic framework are provided. Methods for associating guest materials with a metal organic framework are also provided. Methods are provided for selectively associating or dissociating guest materials with a metal organic framework. Systems for associating or dissociating guest materials within a series of metal organic frameworks are provided. Thermal energy transfer assemblies are provided. Methods for transferring thermal energy are also provided.