Abstract: Crosslinked silicone foams are provided that can be substantially free of chemical blowing agents or byproducts thereof. These foams can be prepared from polymerizable silicone compositions that include an MQ-water cluster including a silicate MQ resin and a quantity of water dispersed in the silicate MQ resin and a silicone fluid, wherein the MQ-water cluster and silicone fluid collectively provide a inverted emulsion having a continuous and a discontinuous phase, the continuous phase including the silicone fluid and the discontinuous phase including the MQ-water cluster.

Abstract: It is desired to find a new class of adhesion promoters to adhere the granules to the asphalt. Generally, the application is directed to an article comprising a substrate and a coating on the substrate, wherein the coating comprises a polyolefin. The substrate may be a roofing granule. In certain embodiments, the polyolefin is a chemically modified polyolefin. In some embodiments, the coating comprises a photocatalytic material.