Abstract: Encapsulated water soluble chemicals for use in controlled time release applications, methods of encapsulating the chemicals and methods of using the encapsulated chemicals are provided. The methods of encapsulating the chemicals are basically comprised of forming a first coating of a dry hydrophobic film forming material or a sparingly soluble material which provides a dry shield on the chemical and then forming a second coating of a porous cross-linked hydrophilic polymer on the first coating which prevents the substantial dissolution of the resulting encapsulated chemical for a selected period of time.

Abstract: Cement compositions and methods of cementing within subterranean formations penetrated by well bores wherein the flow properties of one or more dry particulate cementitious materials are improved and wherein the materials can be readily conveyed out of storage tanks and the like. A preferred composition of the present invention comprises a particulate flow enhancing additive dry-blended with one or more dry particulate cementitious materials, said flow enhancing additive being comprised of a particulate solid material carrying a flow inducing polar chemical, and a sufficient amount of water to form a pumpable slurry.

Abstract: Methods of improving the flow properties of one or more dry particulate cementitious materials are provided. The methods are basically comprised of dry-blending a particulate flow enhancing additive comprised of a particulate solid adsorbent material having a flow inducing polar molecule producing chemical adsorbed thereon with said cementitious materials.

Abstract: The present invention provides improved early-enhanced strength cement compositions and methods. The cement compositions can be utilized in surface construction projects as well as in the construction of oil, gas and water wells. The improved cement compositions of this invention are basically comprised of a hydraulic cement, water present in an amount sufficient to form a slurry and hydrophobic silica powder.

Abstract: Encapsulated water soluble chemicals for use in controlled time release applications, methods of encapsulating the chemicals and methods of using the encapsulated chemicals are provided. The methods of encapsulating the chemicals are basically comprised of forming a first coating of a dry hydrophobic film forming material or a sparingly soluble material which provides a dry shield on the chemical and then forming a second coating of a porous cross-linked hydrophilic polymer on the first coating which prevents the substantial dissolution of the resulting encapsulated chemical for a selected period of time.

Abstract: Methods of improving the flow properties of at least one dry particulate cementitious or non-cementitious material are provided. The methods are basically comprised of dry-blending a particulate flow enhancing additive comprised of a particulate solid absorbent material having a flow inducing polar molecule producing chemical absorbed thereon with said cementitious or non-cementitious material.

Abstract: Methods and compositions for forming permeable cement sand screens in well bores are provided. The compositions are basically comprised of a hydraulic cement, an acid soluble particulate solid, a liquid hydrocarbon solvent soluble particulate solid, a particulate cross-linked gel containing an internal breaker which after time causes the gel to break into a liquid, water present in an amount sufficient to form a slurry, a gas present in an amount sufficient to form a foam and a mixture of foaming and foamed stabilizing surfactants.

Abstract: Improved methods of treating water and hydrocarbons producing subterranean formations to reduce the water permeabilities of the formations without substantially reducing the hydrocarbons permeabilities thereof are provided. The methods basically comprise introducing into the formation a chemical which does not resist water flow and attaches to adsorption sites on surfaces within the porosity of the formation but slowly washes off the sites as another fluid flows through the treated formation. Thereafter, a water flow resisting polymer is introduced into the formation so that it flows deeply into the porosity of the formation before the previously introduced chemical washes off and attaches to the adsorption sites as the chemical washes off.

Abstract: Methods and compositions for forming permeable cement sand screens in well bores are provided. The compositions are basically comprised of a hydraulic cement, an acid soluble particulate solid, a liquid hydrocarbon solvent soluble particulate solid, a particulate cross-linked gel containing an internal breaker which after time causes the gel to break into a liquid, water present in an amount sufficient to form a slurry, a gas present in an amount sufficient to form a foam and a mixture of foaming and foamed stabilizing surfactants.

Abstract: The present invention provides improved compositions and methods for sealing pipe in a well bore. The compositions which harden into highly resilient solid masses having high strengths are basically comprised of a hydraulic cement, an aqueous rubber latex, an aqueous rubber latex stabilizing surfactant and silica hydrophobicized with silicon oil.

Abstract: The present invention provides improved methods of cementing casing strings in deep water offshore formations penetrated by well bores. The methods are basically comprised of the steps of preparing a cement composition comprised of hydraulic cement, water, gas, a mixture of foaming and foam stabilizing surfactants, a cement early strength accelerator and a mildly set retarding cement dispersing agent, placing the cement composition in the annulus between the casing string and the well bore and allowing the cement composition to set into a hard impermeable mass.

Abstract: The present invention provides improved compositions and methods for sealing pipe in a well bore. The compositions which harden into highly resilient solid masses having high strengths are basically comprised of a hydraulic cement, an aqueous rubber latex, an aqueous rubber latex stabilizing surfactant, an epoxy resin, an epoxy resin hardening agent and porous precipitated silica hydrophobicized with silicone oil.

Abstract: Metallocene catalyst components having bis-fluorenyl ligands of a staggered conformation and processes for the isotactic propagation of a polymer chain from ethylenically unsaturated monomers. The catalyst components comprise bridged bis-fluorenyl metallocenes characterized by the following formula: X(FlYa)(Fl′Zb)MeQn  (1) wherein, Fl and Fl′ are fluorenyl groups which are interconnected by a structural bridge X to impart stereorigidity to the metallocene ligand, Me is a Group 3, 4, or 5 transition metal each Y is the same or different and is a hydrocarbyl or heterohydrocarbyl substittient at a distal position on the fluorenyl group, each Z is the same or different and is a hydrocarbyl or heterohydrocarbyl substituent at a distal position on the other fluorenyl group Fl′, and a and b are each independently 1 or 2.

Abstract: Methods of improving the flow properties of one or more dry particulate cementitious materials are provided. The methods are basically comprised of dry-blending a particulate flow enhancing additive comprised of a particulate solid adsorbent material having a flow inducing polar molecule producing chemical adsorbed thereon with said cementitious materials.

Abstract: The present invention provides improved methods of cementing casing strings in deep water offshore formations penetrated by well bores. The methods are basically comprised of the steps of preparing a cement composition having a short transition time comprised of hydraulic cement, a water reducing additive, a dispersing additive, a compressive strength enhancing and set retarding additive, a set accelerating additive and water, placing the cement composition in the annulus between the casing string and the well bore and allowing the cement composition to set into a hard impermeable mass.

Abstract: The present invention provides improved compositions and methods for sealing pipe in a well bore. The compositions which harden into highly resilient solid masses having high strengths are basically comprised of a hydraulic cement, an aqueous rubber latex, an aqueous rubber latex stabilizing surfactant and silica hydrophobicized with silicon oil.

Abstract: Methods of improving the flow properties of one or more dry particulate cementitious materials are provided. The methods are basically comprised of dry-blending a particulate flow enhancing additive comprised of a particulate solid adsorbent material having a flow inducing polar molecule producing chemical adsorbed thereon with said cementitious materials.

Abstract: Methods of improving the flow properties of one or more dry particulate cementitious materials are provided. The methods are basically comprised of dry-blending a particulate flow enhancing additive comprised of a particulate solid adsorbent material having a flow inducing polar molecule producing chemical adsorbed thereon with said cementitious materials.

Abstract: The present invention provides improved compositions and methods for sealing pipe in a well bore. The compositions which harden into highly resilient solid masses having high strengths are basically comprised of a hydraulic cement, an aqueous rubber latex, an aqueous rubber latex stabilizing surfactant and silica hydrophobicized with silicon oil.

Abstract: The present invention provides improved foamed well cement compositions and methods. The foamed cement compositions have improved properties and are basically comprised of hydraulic cement, amorphous silica surface treated with a mixture of organosilane coupling agents, sufficient water to form a slurry, sufficient gas to foam the slurry and a mixture of foaming and foam stabilizing surfactants present in an amount sufficient to facilitate the formation of the foam and stabilize the foamed composition.