Abstract: A method for improving the increasing the efficiency of an unconventional oil recovery (UOR) process uses biodiesel as a surfactant in water-surfactant emulsions or water-solvent-surfactant emulsions for purposes of water-surfactant emulsions flooding or water-solvent-surfactant emulsions methods. A polymer may be added to the emulsions to increase the emulsion viscosity. Water-surfactant emulsions flooding or water-solvent-surfactant emulsions flooding methods may be implemented in intervals alternating with or sequential to intervals of water-only flooding.

Abstract: In a method for enhancing the efficiency of separation of bitumen from oil sands ore, lipids, lipid by-products, and lipid derivatives are used as process additives for ore-water slurry-based bitumen extraction processes or in situ bitumen recovery processes. These additives act as surfactants reducing surface and interfacial tensions, thus promoting breakdown the oil sands ore structure and resultant liberation of bitumen from the ore. Lipid treatment does not deleteriously affect release water chemistry in bitumen recovery processes, and it does not appreciably affect the fuel value of recovered bitumen. Lipids which may be effectively used as additives include biodiesel, tall oil fatty acids, monoglycerides, vegetable oil, and soap water, and combinations thereof.

Abstract: In a method for enhancing the efficiency of separation of bitumen from oil sands ore, lipids, lipid by-products, and lipid derivatives are used as process additives for ore-water slurry-based bitumen extraction processes or in situ bitumen recovery processes. These additives act as surfactants reducing surface and interfacial tensions, thus promoting breakdown the oil sands ore structure and resultant liberation of bitumen from the ore. Lipid treatment does not deleteriously affect release water chemistry in bitumen recovery processes, and it does not appreciably affect the fuel value of recovered bitumen. Lipids which may be effectively used as additives include biodiesel, tall oil fatty acids, monoglycerides, vegetable oil, and soap water, and combinations thereof.

Abstract: In a process for destabilizing bitumen-water emulsions to facilitate bitumen recovery therefrom, bitumen-water interfacial tension is increased by reducing or eliminating the activity of functional groups acting as surfactants by treating the emulsions with one or more additives of ionic base to increase the hydrophobic characteristics of bitumen droplets in the emulsions and thus increase their attraction to each other and to gas bubbles. Additives effective for this purpose include salts of the Periodic Table's Group II earth alkali metals cations such as magnesium, calcium, strontium, and barium, and Group III metals cations such as aluminum. Mechanical agitation or injection of a gas stream into the destabilized bitumen-eater emulsion may be used to form bitumen-rich froth. The additives used for destabilization of the emulsions also promote flocculation of clay-size particles in the froth and improve the chemistry of the recovered water.

Abstract: In a method for increasing the efficiency of bitumen recovery from oil sands, bitumen asphaltenes naturally present in the oil sands ore are treated with selected chemical agents to produce surfactants which reduce surface and interfacial tensions and promote the production of bitumen-water emulsions, thus facilitating the extraction and recovery of bitumen for use in producing synthetic crude oil. The agents react with the asphaltenes by oxidation, sulfonation, sulfoxidation, or sulfomethylation reactions, or by a combination of such reactions. These reactions may be initiated by adding selected agents into water-based oil sand slurries in process vessels or in pipelines. Alternatively, the agents may be injected directly into subsurface oil sand formations for in situ production of surfactants to enhance the efficiency of in situ thermal bitumen recovery processes.

Abstract: In a method for enhancing the efficiency of bitumen recovery from oil sands ore, CaO lime (or Ca(OH)2) is mixed into an oil sands ore-water slurry prior to or during the operation of slurry-based bitumen extraction processes. The lime is introduced at dosages effective to reduce the electro-chemical attraction between clay particles and bitumen in the slurry, thereby promoting detachment of clay particles from bitumen droplets in the ore-water slurry. This occurs because water-soluble asphaltic acids formed at the bitumen-water interface act as surfactants which reduce or eliminate the activity of Ca2+ and Mg2+ ions binding the clay particles and bitumen together. The detachment of clay particles promotes the attachment of air bubbles to the bitumen droplets, thereby forming a bitumen-rich froth which will float to the surface of the ore-water slurry, thus facilitating bitumen recovery.

Abstract: In a method for enhancing the efficiency of bitumen recovery from oil sands ore, CaO lime (or Ca(OH)2) is mixed into an oil sands ore-water slurry prior to or during the operation of slurry-based bitumen extraction processes. The lime is introduced at dosages effective to reduce the electro-chemical attraction between clay particles and bitumen in the slurry, thereby promoting detachment of clay particles from bitumen droplets in the ore-wafer slurry. This occurs because water-soluble asphaltic acids formed at the bitumen-water interface act as surfactants which reduce or eliminate the activity of Ca2+ and Mg2+ ions binding the clay particles and bitumen together. The detachment of clay particles promotes the attachment of air bubbles to the bitumen droplets, thereby forming a bitumen-rich froth which will float to the surface of the ore-water slurry, thus facilitating bitumen recovery.

Abstract: In a method for increasing the efficiency of bitumen recovery from oil sands, bitumen asphaltenes naturally present in the oil sands ore are treated with selected chemical agents to produce surfactants which reduce surface and interfacial tensions and promote the production of bitumen-water emulsions, thus facilitating the extraction and recovery of bitumen for use in producing synthetic crude oil. The agents react with the asphaltenes by oxidation, sulfonation, sulfoxidation, or sulfomethylation reactions, or by a combination of such reactions. These reactions may be initiated by adding selected agents into water-based oil sand slurries in process vessels or in pipelines. Alternatively, the agents may be injected directly into subsurface oil sand formations for in situ production of surfactants to enhance the efficiency of in situ thermal bitumen recovery processes.

Abstract: In a method for enhancing the efficiency of separation of bitumen from oil sands ore, lipids, lipid by-products, and lipid derivatives are used as process additives for ore-water slurry-based bitumen extraction processes or in situ bitumen recovery processes. The lipids, lipid by-products, and lipid derivatives act as surfactants reducing surface and interfacial tensions, thus promoting breakdown the oil sands ore structure and resultant liberation of bitumen from the ore. Lipid treatment does not deleteriously affect release water chemistry in bitumen recovery processes, and it does not appreciably affect the fuel value of recovered bitumen. Lipids which may be effectively used as additives include biodiesel, tall oil fatty acids, monoglycerides, vegetable oil, and soap water, and combinations thereof.

Abstract: In a method for enhancing the efficiency of bitumen recovery from oil sands ore, CaO lime (or Ca(OH)2) is mixed into an oil sands ore-water slurry prior to or during the operation of slurry-based bitumen extraction processes. The lime is introduced at dosages effective to reduce the electro-chemical attraction between clay particles and bitumen in the slurry, thereby promoting detachment of clay particles from bitumen droplets in the ore-wafer slurry. This occurs because water-soluble asphaltic acids formed at the bitumen-water interface act as surfactants which reduce or eliminate the activity of Ca2+ and Mg2+ ions binding the clay particles and bitumen together. The detachment of clay particles promotes the attachment of air bubbles to the bitumen droplets, thereby forming a bitumen-rich froth which will float to the surface of the ore-water slurry, thus facilitating bitumen recovery.

Abstract: In a hydrocracking process a feed mixture comprising: heavy oil containing asphaltenes and sulfur moieties; an oil-soluble, metal-containing compound additive (such as iron pentacarbonyl or molybdenum 2-ethyl hexanoate), which additive is operative to impede coalescence of coke precursors and which forms hydrocracking catalytic particles in situ; and, optionally, a hydrocarbon diluent which is a solvent for asphaltenes and which will assist with dispersion of the additive; is mixed for a prolonged period at low temperature (e.g., 80.degree. C.-190.degree. C.) in a first vessel or vessels to disperse the additive without significantly decomposing the additive. Preferably, the product mixture is then digested in a second vessel or vessels by mixing it at an elevated temperature (e.g., 250.degree. C.), to decompose the additive. The resulting mixture is then heated to hydrocracking temperature (e.g., 450.degree. C.) and introduced into a reactor.